An electrical-energy harvesting system envisages a transducer for converting energy from an environmental energy source into a transduced signal, an electrical energy harvesting interface for receiving the transduced signal and for supplying a harvesting signal, and an energy storage element coupled to the electrical energy harvesting interface for receiving the harvesting signal. The electrical-energy harvesting system also includes a voltage converter connected to the electrical energy harvesting interface for generating a regulated voltage. The harvesting interface samples an open-circuit voltage value of the transduced signal, generates an optimized voltage value starting from the open-circuit voltage value, and generates an upper threshold voltage and a lower threshold voltage on the basis of the optimized voltage value. The harvesting interface controls the voltage converter in switching mode so that the harvesting signal has a value between the upper and lower threshold voltages in at least one operating condition.