The present invention is to provide: a liquid electrolyte for batteries, which has excellent stability to lithium metals; a method for producing the liquid electrolyte; and a lithium battery comprising the liquid electrolyte. Presented is a liquid electrolyte for lithium batteries, wherein the liquid electrolyte comprises a mesoionic compound represented by the following general formula (1): wherein R1 is an aliphatic hydrocarbon group having 1 to 3 carbon atoms, and R2 is a group represented by any one of the following general formulae (2), (3) and (4): General Formula (2): —ClH2l—(OCH2)m—CnH2n+1; General Formula (3): —CxH2x—(CH2OCH2)y—CzH2z+1; and General Formula (4): —CpH2p—(C2H4OCH2)q—CrH2r+1.