Invention Grant
- Patent Title: Process for continuous polymerization of olefin monomers in a reactor
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Application No.: US15100491Application Date: 2014-11-24
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Publication No.: US09637572B2Publication Date: 2017-05-02
- Inventor: Yahya Banat , Jose Fernando Cevallos-Candau
- Applicant: SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V.
- Applicant Address: NL Bergen op Zoom SA Riyadh
- Assignee: SABIC GLOBAL TECHNOLOGIES B.V.,SAUDI BASIC INDUSTRIES CORPORATION
- Current Assignee: SABIC GLOBAL TECHNOLOGIES B.V.,SAUDI BASIC INDUSTRIES CORPORATION
- Current Assignee Address: NL Bergen op Zoom SA Riyadh
- Agency: Cantor Colburn LLP
- Priority: EP13195140 20131129
- International Application: PCT/EP2014/075411 WO 20141124
- International Announcement: WO2015/078815 WO 20150604
- Main IPC: C08F2/00
- IPC: C08F2/00 ; C08F210/00 ; B01J8/18 ; C08F10/06 ; C08F2/34 ; C08F10/02

Abstract:
The invention relates to a process for the continuous polymerization of one or more a-olefin monomers of which at least one is ethylene or propylene comprising the steps of: (1) feeding the one or more a-olefins to a vertically extended reactor suitable for the continuous fluidized bed polymerization of one or more a-olefin monomers of which at least one is ethylene or propylene, which reactor is operable in condensed mode, wherein the reactor comprises a distribution plate and an integral gas/liquid separator located below the distribution plate, (2) withdrawing the polyolefin from the reactor (3) withdrawing fluids from the top of the reactor, (4) cooling the fluids to below their dew point, resulting in a bottom recycle stream, (5) introducing the bottom recycle stream under the distribution plate, (6) separating at least part of the liquid from the bottom recycle stream using the integral separator to form a liquid phase and a gas/liquid phase, (7) feeding the liquid phase to an external pipe, (8) adding a solid polymerization catalyst to the liquid phase in the external pipe resulting in the formation of a slurry stream comprising prepolymer and/or polymer and (9) feeding the slurry stream comprising the prepolymer and/or polymer into the reactor above the distribution plate, wherein the prepolymer and/or polymer are present in the slurry stream in an amount of from 0.01 to 99 wt % based on the total slurry stream upon introduction of the slurry stream into the reactor.
Public/Granted literature
- US20160297899A1 PROCESS FOR CONTINUOUS POLYMERIZATION OF OLEFIN MONOMERS IN A REACTOR Public/Granted day:2016-10-13
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