An oxynitride orange-red fluorescent substance and a light-emitting film or sheet and a light-emitting device comprising the same are disclosed. The chemical formula of the oxynitride orange-red fluorescent substance is MmAaSixNyOz:dR in which the element M is one or more of the elements selected from Ca, Sr and Ba, the element A is Al or a mixture of Al with one or more of the elements selected from Ga, La, Sc and Y, the element R is one or more of the elements selected from Ce, Eu and Mn, 0.8≦m≦1.2, 1