An organic light-emitting diode (OLED) panel, a manufacturing method thereof and a display device are provided. The OLED panel comprises: a base substrate, a plurality of OLED units formed on the base substrate, and a reflective structure formed on the base substrate, disposed along the periphery of the OLED units and configured to partially or completely encircle the OLED units. The OLED unit includes an anode layer, an organic emission layer and a cathode layer. The reflective structure is provided with a reflective surface which is configured to reflect light emitted from a side terminal of the organic emission layer to the outside of the OLED panel. The OLED panel can improve the utilization rate of light emitted by the OLED units and hence improve the display quality of the OLED panel.