Inorganic multilayer lamination transfer films, methods of forming these lamination transfer films, and methods of using these lamination transfer films. These inorganic multilayer lamination transfer films can have alternating layers including inorganic nanoparticles, sacrificial materials, and optionally inorganic precursors that can be densified to form an inorganic optical stack. Receptor substrates, such as glass or metal, are laminated to the multilayer lamination transfer films.