Invention Grant
- Patent Title: Catalyst system and use in heavy aromatics conversion processes
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Application No.: US15004662Application Date: 2016-01-22
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Publication No.: US09802181B2Publication Date: 2017-10-31
- Inventor: Christine N. Elia , Shifang L. Luo , Hari Nair , Wenyih F. Lai , Robert G. Tinger
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- Main IPC: C07C6/12
- IPC: C07C6/12 ; C07C4/18 ; B01J29/80 ; B01J35/10 ; B01J29/22 ; B01J29/24 ; B01J29/44 ; B01J29/46 ; B01J8/04 ; B01J37/18 ; B01J29/67 ; B01J29/68 ; B01J29/74 ; B01J29/76 ; B01J35/00 ; B01J35/02 ; C01B39/26

Abstract:
Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
Public/Granted literature
- US20160221896A1 Catalyst System and Use in Heavy Aromatics Conversion Processes Public/Granted day:2016-08-04
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