- 专利标题: Carbon fiber sizing agent, aqueous dispersion thereof, carbon fiber bundle applied with sizing agent, sheet-like article comprising carbon fiber bundle, and carbon fiber reinforced composite material
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申请号: US14240161申请日: 2012-08-21
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公开(公告)号: US09862824B2公开(公告)日: 2018-01-09
- 发明人: Kouki Wakabayashi , Naoki Sugiura , Masahiro Hata , Shigekazu Takeda , Keigo Yoshida , Shuuichi Nakamura
- 申请人: Kouki Wakabayashi , Naoki Sugiura , Masahiro Hata , Shigekazu Takeda , Keigo Yoshida , Shuuichi Nakamura
- 申请人地址: JP Tokyo
- 专利权人: Mitsubishi Chemical Corporation
- 当前专利权人: Mitsubishi Chemical Corporation
- 当前专利权人地址: JP Tokyo
- 代理机构: Morgan, Lewis & Bockius LLP
- 优先权: JP2011-180696 20110822
- 国际申请: PCT/JP2012/071018 WO 20120821
- 国际公布: WO2013/027708 WO 20130228
- 主分类号: C08L75/04
- IPC分类号: C08L75/04 ; D06M15/55 ; D06M15/564 ; C08L63/00 ; C08J5/06 ; C08J5/24 ; D06M101/40 ; C08L67/02 ; D06M15/507 ; D06M13/11 ; D06M13/224 ; C08J5/04 ; C09D163/10
摘要:
The present invention provides: a carbon fiber sizing agent that can obtain a carbon fiber bundle having a superior effect of improving mechanical properties when composited using a resin; an aqueous dispersion thereof; a carbon fiber bundle; a sheet-shaped article having a carbon fiber bundle; and a composite material. The carbon fiber sizing agent contains: a compound (A) that is an ester of an unsaturated monobasic acid and an epoxy compound having a plurality of epoxy groups in the molecule, and that has at least one epoxy group in the molecule; a urethane acrylate oligomer (B) that is bifunctional and that has a tensile elongation rate of the cured product of at least 40%; and a polyurethane resin (C) having a tensile elongation rate of a dried coating film of 350-900% inclusive. The amounts of A-C contained satisfy the conditions described in the description. The aqueous dispersion disperses the sizing agent. The carbon fiber bundle contains 0.6-3.0 mass % inclusive of the sizing agent. The sheet-shaped article and a pultruded composite material contain the carbon fiber bundle. The composite material contains the sheet-shaped article.