公开(公告)号：US11286359B2

公开(公告)日：2022-03-29

申请号：US16533517

申请日：2019-08-06

申请人： TORAY INDUSTRIES, INC.

发明人： Nobuyuki Arai ,  Tomoko Ichikawa ,  Hiroshi Taiko ,  Makoto Endo ,  Masanobu Kobayashi ,  Jun Misumi

IPC分类号： C08J5/24 ,  C08G59/38 ,  D06M13/11 ,  C08L63/00 ,  D06M15/55 ,  C08J5/04 ,  C08J5/06 ,  B29C70/46 ,  C08K5/1515 ,  C09D163/00 ,  D06M101/40 ,  B29K63/00 ,  B29K105/08 ,  B29K307/04

摘要： A prepreg includes; sizing agent-coated carbon fibers coated with a sizing agent; and a thermosetting resin composition impregnated into the sizing agent-coated carbon fibers. The sizing agent includes an aliphatic epoxy compound (A) and an aromatic compound (B) at least containing an aromatic epoxy compound (B1). The thermosetting resin composition includes a thermosetting resin (D) and a latent hardener (E), and optionally includes an additive (F) other than the thermosetting resin (D) and the latent hardener (E). The (a)/(b) ratio is within a predetermined range where (a) is the height of a component at a binding energy assigned to CHx, C—C, and C═C and (b) is the height of a component at a binding energy assigned to C—O in a C1s core spectrum of the surfaces of the sizing agent-coated carbon fibers analyzed by X-ray photoelectron spectroscopy.

公开(公告)号：US11225754B2

公开(公告)日：2022-01-18

申请号：US16604595

申请日：2018-04-11

申请人： Dow Global Technologies LLC

发明人： Michael A. Lowe ,  Richard Baumer

IPC分类号： D06M13/328 ,  C08J5/06 ,  D06M10/08 ,  D06M15/643 ,  D06M101/40

摘要： The surface of a carbon fiber is electrochemically treated by a method to form nitrogen containing groups on the surface of the carbon fiber. The method comprises contacting a carbon fiber surface with an aqueous solution comprised of a non-cyclic aliphatic amine and water soluble inorganic hydroxide with said aqueous solution having a pH of at least 9. A positive electrical bias is then applied to the carbon fibers in the aqueous solution relative to another electrode in contact with the aqueous solution, wherein the positive electrical bias is at a voltage above the oxidation potential of water. The treated carbon fibers are useful for making epoxy reinforced carbon fiber composites.

公开(公告)号：US11168187B2

公开(公告)日：2021-11-09

申请号：US16612104

申请日：2018-05-08

申请人： DIC Corporation

发明人： Kenji Nagao

IPC分类号： C08J5/06 ,  C08J5/04 ,  C08J5/24 ,  D06M15/263 ,  D06M15/564 ,  D06M101/40

摘要： A fiber sizing agent includes: a vinyl ester resin (A) having an alkoxy polyoxyalkylene structure and a urethane bond; and an aqueous medium. The fiber sizing agent has excellent fiber sizing properties for various fibers such as glass fibers and carbon fibers. A molded article obtained from a molding material including the fiber sizing agent is excellent in various physical properties such as bending strength, compressive strength, and interlaminar shear strength, and thus can be used, for example, for an automobile member, an aircraft member, a windmill member, and an industrial member.

公开(公告)号：US11001950B2

公开(公告)日：2021-05-11

申请号：US16364955

申请日：2019-03-26

申请人： Lintec of America, Inc.

发明人： Marcio D. Lima

IPC分类号： B32B5/10 ,  B32B5/26 ,  B32B5/28 ,  B29C70/34 ,  B32B38/08 ,  D04H1/64 ,  D04H5/04 ,  D04H1/74 ,  D06M10/10 ,  D04H1/4242 ,  D04H5/08 ,  B32B5/02 ,  B32B37/12 ,  B32B37/24 ,  B32B27/12 ,  D06M15/19 ,  D06M101/40

摘要： One or more nanofiber yarns can be placed in contact with one or more nanofiber sheets. The nanofiber yarns, which include single-ply and multi-ply nanofiber yarns, provide added mechanical stability to a nanofiber sheet that decreases the likelihood of a nanofiber sheet wrinkling, folding, or otherwise becoming stuck to itself. Furthermore, the nanofiber yarns integrated with the nanofiber sheet can also act as a mechanism to prevent the propagation of tears through the nanofiber sheet. In some cases, an infiltrating material can be infiltrated into interstitial spaces defined by the nanofibers within both the nanofiber yarns and the nanofiber sheets. The infiltrating material can then form a continuous network throughout the nanofiber yarns and the nanofiber sheet.

公开(公告)号：US10954313B2

公开(公告)日：2021-03-23

申请号：US16073789

申请日：2017-01-29

申请人： SP NANO LTD

发明人： Asa Eitan ,  Yana Tesler ,  Jeanie Tamir ,  Nurit Shalev ,  Leonid Melekhov ,  Oshrit Poliker ,  Amnon Wolf ,  Konstantin Press

IPC分类号： C07K17/14 ,  C07K14/415 ,  C09C1/56 ,  C09C1/48 ,  C09D7/62 ,  B60C1/00 ,  C09D107/02 ,  C09D109/04 ,  C09D109/08 ,  C09D111/02 ,  C09D115/00 ,  C09D123/16 ,  C09D161/12 ,  C09D179/02 ,  C09D189/00 ,  D06M11/74 ,  D06M15/15 ,  D06M15/61 ,  D06M15/693 ,  D06M101/32 ,  D06M101/36 ,  D06M101/40

摘要： The present invention, relates to composition of matter comprising sequence variants of Stable Protein 1 (SP1) and carbon nanotubes or carbon black, and optionally comprising latex. This invention also relates to surfaces (e.g. metal wires, cords, and polymeric and non polymeric fibers, yarns, films or fabrics, wood and nano, micro and macro particles) comprising this composition of matter, to methods for producing them, and to uses thereof in the preparation and formation of improved composite materials, including rubber, and rubber compound composites.

公开(公告)号：US10920368B2

公开(公告)日：2021-02-16

申请号：US15440213

申请日：2017-02-23

申请人： Nanocomp Technologies, Inc.

发明人： Peter L. Antoinette ,  Mark A. Banash ,  Ashley Hart

IPC分类号： B05D1/04 ,  D06M15/19 ,  B05D1/00 ,  B05D1/22 ,  B05D1/28 ,  B05D3/06 ,  B05D3/10 ,  D06M101/40

摘要： A method for coloring a carbon nanotube (CNT) product is provided, including placing a CNT product in an electric circuit to ground the product, charging a plurality of pigment molecules with an opposite charge from the CNT product, applying a coating of the charged pigment molecules to a surface of the CNT product, and exposing the coating to a temperature sufficient to cure the coating, while allowing the coating to form a substantially conformal film on the surface of the CNT product.

公开(公告)号：US10828663B2

公开(公告)日：2020-11-10

申请号：US15886139

申请日：2018-02-01

申请人： Florida State University Research Foundation, Inc.

发明人： Shaokai Wang ,  Zhiyong (Richard) Liang

IPC分类号： B05D1/12 ,  D06M11/83 ,  H01B1/22 ,  D06M23/08 ,  B32B5/26 ,  B32B5/02 ,  C08J5/10 ,  C08J5/06 ,  B32B1/00 ,  C08J5/04 ,  D06M101/40

摘要： Composite materials are provided that include a host material, nanoscale high conductive particles, and microscale high conductive particles. The nanoscale high conductive particles and the microscale high conductive particles may increase the through thickness thermal conductivity of the composite material by at least 4.0 W/(m·K), as compared to the same composite material without the nanoscale high conductive particles and microscale high conductive particles. Methods for making the composite materials herein also are provided.

公开(公告)号：US10533266B2

公开(公告)日：2020-01-14

申请号：US15978011

申请日：2018-05-11

申请人： The Boeing Company

发明人： Keith Daniel Humfeld ,  Scott Hartshorn

IPC分类号： D01F8/18 ,  C01B32/168 ,  C01B32/205 ,  D01F9/12 ,  D06M10/10 ,  D06M15/31 ,  D06M15/71 ,  D06B3/04 ,  D06M101/40

摘要： A carbon nanotube yarn is coated with polyacrylonitrile to form a coated carbon nanotube yarn. The polyacrylonitrile is converted to crystalline carbon to form a layered carbon fiber with a sheath of the crystalline carbon and a core of the carbon nanotube yarn.

公开(公告)号：US10458061B2

公开(公告)日：2019-10-29

申请号：US14786722

申请日：2014-04-23

申请人： Nitta Corporation

发明人： Maki Onizuka ,  Takuji Komukai

IPC分类号： D06M11/74 ,  B82Y30/00 ,  C08J5/04 ,  C08J5/00 ,  D06M101/40

摘要： Provided are: a composite material capable of exhibiting the original functions of a base material thereof and also capable of exhibiting functions derived from CNTs, such as electrical conductivity, heat conductivity, and mechanical strength; and a molded article therefrom. A composite material comprising a base material and a structure formed on the surface of the base material, the structure including a plurality of carbon nanotubes, wherein the plurality of carbon nanotubes form a network structure, in which the carbon nanotubes are directly connected with one another and also directly adhere to the surface of the base material.

公开(公告)号：US10422074B2

公开(公告)日：2019-09-24

申请号：US15554367

申请日：2016-03-07

申请人： Evonik Degussa GmbH

发明人： Stephan Sprenger ,  Matthias Naumann

IPC分类号： C08K7/06 ,  D06M11/79 ,  C08J5/06 ,  H01B1/04 ,  H01B1/24 ,  D06M15/55 ,  D06M23/08 ,  C08J5/24 ,  C01B32/00 ,  C01B32/05 ,  D01F9/12 ,  D06M101/40

摘要： A carbon fiber material is coated with nanoparticles, where the coating contains from 0.01 to less than 10% by weight of nanoparticles, based on the dry weight of the coated fiber material, and the coating may optionally be involved in further reactions.