- 专利标题: Hydrogenation treatment catalyst for heavy hydrocarbon oil, and method for hydrogenation treatment of heavy hydrocarbon oil
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申请号: US15022961申请日: 2014-09-25
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公开(公告)号: US09908107B2公开(公告)日: 2018-03-06
- 发明人: Takayuki Osaki , Nobumasa Nakajima
- 申请人: Cosmo Oil Co., Ltd.
- 申请人地址: JP Tokyo
- 专利权人: COSMO OIL CO., LTD.
- 当前专利权人: COSMO OIL CO., LTD.
- 当前专利权人地址: JP Tokyo
- 代理机构: Panitch Schwarze Belisario & Nadel LLP
- 优先权: JP2013-201801 20130927
- 国际申请: PCT/JP2014/075417 WO 20140925
- 国际公布: WO2015/046323 WO 20150402
- 主分类号: C10G65/04
- IPC分类号: C10G65/04 ; B01J27/19 ; C10G45/08 ; B01J35/10 ; B01J35/00 ; B01J23/887 ; B01J21/12 ; B01J35/02
摘要:
A hydrogenation treatment catalyst is provided for heavy hydrocarbon oil, in which a hydrogenation-active component is supported on a silica-containing porous alumina carrier containing 0.1% to 1.5% by mass of silica based on the carrier. The total pore volume is 0.55 to 0.75 mL/g. Of the total volume of pores having a pore diameter of 3 to 30 nm (1) 30% to 45% have a pore diameter of 5 to 10 nm, (2) 50% to 65% have a pore diameter of 10 to 15 nm, and (3) the total volume of pores having a pore diameter in a range of ±1 nm from the average pore diameter is 25% or more. The total volume of pores having a pore diameter of 30 nm or more is 3% or less. The average pore diameter of pores having a pore diameter of 10 to 30 nm is 10.5 to 13 nm.
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