公开(公告)号：US20190353616A1

公开(公告)日：2019-11-21

申请号：US16340883

申请日：2018-03-27

Applicant: JAPAN PETROLEUM ENERGY CENTER ,  JXTG NIPPON OIL & ENERGY CORPORATION ,  IDEMITSU KOSAN CO., LTD. ,  COSMO OIL CO., LTD.

Inventor： Teruo SUZUKI ,  Keita KATANO ,  Ryuzo TANAKA ,  Shogo TERATANI

IPC: G01N27/62 ,  G01N33/28 ,  G16C20/40 ,  H01J49/00

Abstract: A method identifies the molecular structure of each component in a multicomponent mixture. The method includes (1) subjecting the multicomponent mixture to mass spectrometry to identify the formula of a molecule attributed to each obtained peak, and to identify abundance of the molecule; (2) subjecting the multicomponent mixture to collision induced dissociation; (3) performing mass spectrometry on each fragment ion generated via the collision induced dissociation in (2) to identify the core structure forming each fragment ion and abundance thereof; (4) dividing the molecules attributed to each peak in (1) into “classes” based on “a type and number of heteroatoms, and a DBE value”, and on all the molecules belonging to each “class”, estimating the existence state and abundance thereof; and (5) determining the core structure forming each molecule, for which the existence state is estimated in (4), and determining and assigning a side chain and a cross-link thereto.

公开(公告)号：US09688917B2

公开(公告)日：2017-06-27

申请号：US14779917

申请日：2014-03-19

Applicant: Japan Oil, Gas and Metals National Corporation ,  Inpex Corporation ,  JX Nippon Oil & Energy Corporation ,  Japan Petroleum Exploration Co., Ltd. ,  Cosmo Oil Co., Ltd. ,  Nippon Steel & Sumikin Engineering Co., Ltd.

Inventor： Yukifumi Ishito ,  Junichi Inoue ,  Masaki Shingu ,  Haruki Nagano ,  Kazuhiko Tasaka

IPC: C10G2/00 ,  B01J8/22

CPC classification number: C10G2/342 ,  B01J8/22 ,  C10G2/32

Abstract: In the hydrocarbon-producing apparatus, a vapor-liquid separation tank of a second vapor-liquid separation unit is provided with a filling material layer. A vapor-liquid separation tank of the first vapor-liquid separation unit has a first return line. The vapor-liquid separation tank of the second vapor-liquid separation unit has a second return line. A light component of light oil discharged from a bottom of the vapor-liquid separation tank is returned to a portion between a top side above a return-location from the second return line within the vapor-liquid separation tank of the second vapor-liquid separation unit, and a line directly connected with a cooler installed on the first vapor-liquid separation unit through the first return line. A heavy component of light oil discharged from a bottom of the vapor-liquid separation tank of the second vapor-liquid separation unit is returned to the filling material layer through the second return line.

公开(公告)号：US20160220985A1

公开(公告)日：2016-08-04

申请号：US15022463

申请日：2014-09-25

Applicant: COSMO OIL CO., LTD

Inventor： Takayuki OSAKI ,  Nobumasa NAKAJIMA

IPC: B01J23/887 ,  B01J35/02 ,  B01J35/10 ,  C10G45/08

CPC classification number: B01J23/8873 ,  B01J21/04 ,  B01J23/06 ,  B01J23/883 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/033 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J2523/00 ,  C10G45/04 ,  C10G45/08 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/847

Abstract: The hydrogenation catalyst for heavy hydrocarbon oil includes: at least one of metals in Group 6 of the periodic table being held by a zinc-containing alumina carrier containing 1% by mass to 15% by mass of zinc oxide particles having an average particle diameter of 2 μm to 12 μm based on the carrier; the average pore diameter being 18 nm to 35 nm, and the specific surface area being 70 m2/g to 150 m2/g. Also, the hydrogenation method for heavy hydrocarbon oil, includes, a catalytic reaction of heavy hydrocarbon oil in the presence of the hydrogenation catalyst, under the conditions of a temperature of 300° C. to 420° C., a pressure of 3 MPa to 20 MPa, a hydrogen/oil ratio of 400 m3/m3 to 3,000 m3/m3, and a liquid space velocity of 0.1 h−1 to 3 h−1.

Abstract translation: 重质烃油的氢化催化剂包括：周期表第6族金属中的至少一种由含有氧化锌载体的含锌氧化铝载体保持，该载体含有1质量％至15质量％的平均粒径为 基于载体2μm至12μm; 平均孔径为18nm〜35nm，比表面积为70m 2 / g〜150m 2 / g。 此外，重质烃油的氢化方法包括在加氢催化剂存在下，在温度为300〜420℃，压力为3MPa〜 20MPa，氢/油比为400m3 / m3至3,000m3 / m3，液体空间速度为0.1h-1至3h-1。

公开(公告)号：US20160007599A1

公开(公告)日：2016-01-14

申请号：US14773074

申请日：2014-03-06

Applicant: COSMO OIL CO., LTD.

Inventor： Jun LI ,  Yasunobu UEDA ,  Shigeyuki WATANABE ,  Yasutomo TAKEUCHI

IPC: A01N37/44

CPC classification number: A01N37/44 ,  A01G7/00

Abstract: Plant growth accelerator comprising, as an active ingredient, 5-amino-4-hydroxypentanoic acid of formula (1) H2NCH2CH(OH)CH2CH2COOR1   (1) wherein R1 represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, a derivative thereof or a salt thereof.

Abstract translation: 植物生长促进剂，其包含作为活性成分的式（1）的5-氨基-4-羟基戊酸H 2 NCH 2 CH（OH）CH 2 CH 2 COOR 1（1）其中R 1表示氢原子或具有1至10个碳原子的烃基，衍生物 或其盐。

公开(公告)号：US20140377142A1

公开(公告)日：2014-12-25

申请号：US14478433

申请日：2014-09-05

Applicant: JAPAN OIL, GAS AND METALS NATIONAL CORPORATION ,  INPEX CORPORATION ,  JX NIPPON OIL & ENERGY CORPORATION ,  JAPAN PETROLEUM EXPLORATION CO., LTD. ,  COSMO OIL CO., LTD. ,  NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD.

Inventor： Marie IWAMA ,  Kazuhiko TASAKA ,  Yuichi TANAKA

IPC: B01D3/00

CPC classification number: B01D3/009 ,  B01J8/007 ,  B01J8/22 ,  C07C1/04 ,  C10G2/00 ,  C10G2/342 ,  C10G31/00 ,  C10G47/00 ,  C10G2300/208

Abstract: Hydrocarbon oil obtained by Fischer-Tropsch synthesis reaction using a slurry bed reactor holding a slurry of a liquid hydrocarbon in which a catalyst is suspended; the hydrocarbon oil is fractionated into a distilled oil and a column bottom oil containing the catalyst fine powder by a rectifying column; at least part of the column bottom oil is transferred to a storage tank, and the catalyst fine powder is sedimented to the bottom of the storage tank to capture the catalyst fine powder; a residue of the column bottom oil is transferred from the rectifying column to a hydrocracker, and/or the supernatant of the column bottom oil from which the catalyst fine powder is captured by the storage tank is transferred from the storage tank to the hydrocracker; and using the hydrocracker, the residue of the column bottom oil and/or the supernatant of the column bottom oil is hydrocracked.

Abstract translation: 通过费托合成反应获得的烃油，其使用保持催化剂悬浮的液态烃的淤浆的淤浆床反应器; 将烃油通过精馏塔分馏成蒸馏油和含有催化剂细粉末的塔底油; 将塔底油的至少一部分转移到储罐中，并将催化剂细粉沉淀到储罐的底部以捕获催化剂细粉; 柱底油的残渣从精馏塔转移到加氢裂化器中，和/或由储罐捕获催化剂细粉末的塔底油的上清液从储罐转移到加氢裂化器; 并使用加氢裂化器，将柱底油的残余物和/或塔底油的上清液加氢裂化。

公开(公告)号：US20230295522A1

公开(公告)日：2023-09-21

申请号：US18013867

申请日：2021-06-30

Applicant: Cosmo Oil Co., Ltd.

Inventor： Shinya SUZUKI ,  Takamaro KAWAI ,  Hikaru YAMADA

IPC: C10G45/08 ,  B01J35/00 ,  B01J21/06 ,  B01J21/04 ,  B01J23/06 ,  B01J37/02 ,  B01J37/08

CPC classification number: C10G45/08 ,  B01J35/0013 ,  B01J35/006 ,  B01J21/063 ,  B01J21/04 ,  B01J23/06 ,  B01J37/0203 ,  B01J37/08 ,  B01J37/0213 ,  C10G2300/703 ,  C10G2300/1044

Abstract: A hydrotreating catalyst for a hydrocarbon oil is provided in which at least one metal selected from Group 6 metals in the periodic table and at least one metal selected from Group 9 and Group 10 metals in the periodic table are supported on a zinc/titanium-containing alumina carrier containing zinc and titanium.

公开(公告)号：US09513051B2

公开(公告)日：2016-12-06

申请号：US14251816

申请日：2014-04-14

Applicant: Japan Oil, Gas and Metals National Corporation ,  INPEX Corporation ,  JX Nippon Oil & Energy Corporation ,  Japan Petroleum Exploration Co., Ltd. ,  Cosmo Oil Co., Ltd. ,  Nippon Steel & Sumikin Engineering Co., Ltd.

Inventor： Kazuhiko Tasaka

IPC: F25J3/08 ,  C10G2/00 ,  C10G31/06

CPC classification number: F25J3/08 ,  C10G2/30 ,  C10G31/06 ,  C10G2300/1022 ,  C10G2300/4081

Abstract: There is provided a method for recovering hydrocarbon compounds from a gaseous by-products generated in the Fisher-Tropsch synthesis reaction, the method comprising a pressurizing step in which the gaseous by-products are pressurized, a cooling step in which the pressurized gaseous by-products are pressurized to liquefy hydrocarbon compounds in the gaseous by-products, and a separating step in which the hydrocarbon compounds liquefied in the cooling step are separated from the remaining gaseous by-products.

Abstract translation: 提供了一种从费 - 托合成反应产生的气态副产物中回收烃化合物的方法，该方法包括加压步骤，其中气态副产物被加压，冷却步骤， 将产物加压至气态副产物中的液化烃化合物，并且将在冷却步骤中液化的烃化合物与剩余气态副产物分离的分离步骤。

公开(公告)号：US20160230102A1

公开(公告)日：2016-08-11

申请号：US15021960

申请日：2014-09-25

Applicant: COSMO OIL CO., LTD

Inventor： Takayuki OSAKI ,  Nobumasa NAKAJIMA

IPC: C10G65/04 ,  B01J37/00 ,  B01J37/02 ,  B01J27/19

CPC classification number: C10G65/04 ,  B01J23/883 ,  B01J27/19 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/28 ,  C10G45/08

Abstract: The hydroprocessing catalyst for a heavy hydrocarbon oil, includes, as a carrier, a phosphorus-silica-containing alumina carrier containing 0.1% by mass to 4% by mass of phosphorus in terms of oxide based on the carrier, and 0.1% by mass to 1.5% by mass of silica based on the carrier, the carrier supporting 8% by mass to 20% by mass of at least one selected from metals in Group 6 of the periodic table in terms of oxide based on the catalyst and 2% by mass to 6% by mass of at least one selected from metals in Groups 8 to 10 of the periodic table in terms of oxide based on the catalyst.

Abstract translation: 重质烃油用加氢催化剂以载体为基础的氧化物含有0.1质量％〜4质量％的磷作为载体的含磷二氧化硅的氧化铝载体，以载体为0.1质量％〜0.1质量％ 基于载体的二氧化硅为1.5质量％，载体为8质量％〜20质量％的选自元素周期表第6族金属中的至少一种，以氧化物计，基于催化剂和2质量％ 至6质量％的选自元素周期表第8至10族的金属中的至少一种，基于催化剂的氧化物。

公开(公告)号：US20160046969A1

公开(公告)日：2016-02-18

申请号：US14778916

申请日：2014-03-19

Applicant: COSMO OIL CO., LTD.

Inventor： Masaru SAITO ,  Taishi YAMAMOTO ,  Haruki KAWANO

IPC: C12P13/00

CPC classification number: C12P13/005 ,  C12N1/00

Abstract: Provided is a method for producing 5-aminolevulinic acid or a salt thereof at a high yield using 5-aminolevulinic acid-producing microorganisms. The method for producing 5-aminolevulinic acid or a salt thereof comprises culturing 5-aminolevulinic acid-producing microorganisms in a medium comprising one or more components selected from the group consisting of L-arginine, glutamic acid, and a salt thereof. The content of glutamic acid or the salt thereof is from 42 to 100 mM in the medium as the glutamic acid.

Abstract translation: 提供了使用5-氨基乙酰丙酸生产微生物以高产率生产5-氨基乙酰丙酸或其盐的方法。 生产5-氨基乙酰丙酸或其盐的方法包括在包含一种或多种选自L-精氨酸，谷氨酸及其盐的组分的培养基中培养5-氨基乙酰丙酸生产微生物。 在作为谷氨酸的培养基中，谷氨酸或其盐的含量为42〜100mM。

公开(公告)号：US20150166900A1

公开(公告)日：2015-06-18

申请号：US14628777

申请日：2015-02-23

Applicant: JAPAN OIL, GAS AND METALS NATIONAL CORPORATION ,  INPEX CORPORATION ,  JX NIPPON OIL & ENERGY CORPORATION ,  JAPAN PETROLEUM EXPLORATION CO., LTD. ,  COSMO OIL CO., LTD. ,  NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD.

Inventor： Yuichi TANAKA

IPC: C10G2/00 ,  B01J8/18 ,  B01J8/22

CPC classification number: C10G2/34 ,  B01D37/048 ,  B01D43/00 ,  B01J8/006 ,  B01J8/1809 ,  B01J8/22 ,  B01J2208/00017 ,  B01J2219/00083 ,  C10G2/342 ,  C10G3/60 ,  C10G2300/4006 ,  Y02P30/20

Abstract: The present invention provides a process for producing a hydrocarbon oil by performing a Fischer-Tropsch synthesis reaction using a reactor for a Fischer-Tropsch synthesis including a reaction apparatus having a slurry containing catalyst particles and a gaseous phase located above the slurry to obtain a hydrocarbon oil, wherein the Fischer-Tropsch reaction is performed while controlling a temperature of the slurry so that a difference T2−T1 between the average temperature T1 of the slurry and a temperature T2 at the liquid level of the slurry in contact with the gaseous phase is 5 to 30° C.

Abstract translation: 本发明提供一种通过使用费 - 托合成反应器进行费 - 托合成反应的方法，包括具有含有催化剂颗粒的淤浆和位于浆料上方的气相的反应装置，以获得烃 油，其中在控制浆料的温度的同时进行费 - 托反应，使得浆料的平均温度T1与在与气相接触的浆料的液面处的温度T2之间的差T2-T1为 5〜30℃