A release film is provided for supporting an ultrathin ceramic green sheet having a thickness of 0.5 to 1.0 μm, and the release film due to containing modified organic particles and an antistatic agent has a slippery releasing surface with a low friction coefficient and hence excellent coatability and releasing properties; resulted in that when the release film is rolled up, the rolled surfaces do not adhere to each other, and when the ultrathin ceramic green sheet is peeled off from the release film, the ultrathin ceramic green sheet due to a relatively small electrostatic force being generated is without breaking; so that the release film contributes to increasing the yield of ultrathin ceramic green sheet.