Assemblies comprising multi-layer optical film comprising optical layers reflecting incident UV and blue light over specified wavelength ranges. Embodiments of the multi-layer optical films are useful, for example, as a UV protective covering. An exemplary UV stable assembly comprises a multi-layer optical film comprising at least a first plurality of first and second optical layers reflecting at least 50 percent of incident UV light over at least a 30 nanometer wavelength range in a wavelength range from at least 300 nanometers to 400 nanometers, and a second plurality of first and second optical layers reflecting at least 50 percent of incident light over at least 30 nanometer wavelength in a wavelength range from at least 430 nanometers to 500 nanometers.