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    VERFAHREN ZUR HERSTELLUNG VON POLYETHERALKOHOLEN
    2.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON POLYETHERALKOHOLEN 审中-公开

    公开(公告)号：EP1233996A1

    公开(公告)日：2002-08-28

    申请号：EP00966099.4

    申请日：2000-10-02

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： BAUM, Eva ,  GROSCH, Georg, Heinrich ,  HARRE, Kathrin ,  WINKLER, Jürgen ,  OSTROWSKI, Thomas ,  HOEPPNER, Gerd ,  PAREDIS, Els

    IPC分类号： C08G65/26 ,  C07D301/32

    CPC分类号： C08G65/2663

    摘要： The invention relates to a method for producing polyether alcohols by the catalytic reaction of H functional compounds with alkylene oxides, whereby at least one multi-metal cyanide compound is used as the catalyst. The method is characterised in that the total content of alkaline and acidic impurities contained in the starting material and the alkylene oxides, which reduce the activity of the catalyst, is less than 100 ppm.

    摘要翻译： 本发明涉及一种通过H官能化合物与烯化氧的催化反应生产聚醚醇的方法，其中至少一种多金属氰化物化合物用作催化剂。 该方法的特征在于，降低催化剂活性的原料和烯化氧中所含的碱性和酸性杂质的总含量小于100ppm。

    VERFAHREN ZUR HERSTELLUNG VON POLYURETHANEN
    3.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON POLYURETHANEN 有权

    公开(公告)号：EP1175454A1

    公开(公告)日：2002-01-30

    申请号：EP00926868.1

    申请日：2000-04-11

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： LORENZ, Reinhard ,  BAUER, Stephan ,  JUNGE, Dieter ,  BAUM, Eva ,  HARRE, Kathrin ,  ERBES, Jörg ,  OSTROWSKI, Thomas ,  GROSCH, Georg, Heinrich

    IPC分类号： C08G18/48 ,  C08K3/00 ,  C08G18/24

    CPC分类号： C08G18/4866 ,  C08G18/225 ,  C08G65/2663 ,  C08G2101/0008 ,  C08G2101/0083

    摘要： The invention relates to a method for producing polyurethanes by reacting at least one polyisocyanate with at least one compound having at least two hydrogen atoms that are reactive with isocyanate groups. The method is characterised in that at least one polyether alcohol is used for the connection to at least two active hydrogen atoms. Said polyether alcohol is produced by adding alkylene oxides to H-functional initiator substances by means of multi-metal cyanide catalysis. The reaction is carried out in the presence of at least one metallic salt.

    摘要翻译： 本发明涉及通过使至少一种多异氰酸酯与至少一种具有至少两个与异氰酸酯基团反应的氢原子的化合物反应来生产聚氨酯的方法。 该方法的特征在于至少一种聚醚醇用于连接至少两个活性氢原子。 所述聚醚醇通过用多金属氰化物催化剂将烯化氧加入到H-官能引发剂物质中而制得。 该反应在至少一种金属盐的存在下进行。

    VERFAHREN ZUR HERSTELLUNG VON POLYETHERALKOHOLEN
    5.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON POLYETHERALKOHOLEN 有权
    用于生产聚醚醇

    公开(公告)号：EP1685179A1

    公开(公告)日：2006-08-02

    申请号：EP04797695.6

    申请日：2004-11-06

    申请人： BASF Aktiengesellschaft

    发明人： OSTROWSKI, Thomas ,  RUPPEL, Raimund ,  BAUM, Eva ,  HARRE, Kathrin

    IPC分类号： C08G65/00 ,  C08G65/10 ,  C08G65/12 ,  C08G65/26

    CPC分类号： C08G65/2663 ,  C08G18/4866 ,  C08G65/2696

    摘要： The invention relates to a method for the continuous production of polyether alcohols by reacting alkene oxides with H-functional initiation substances in the presence of DMC catalysts. According to said method: a) a preliminary product and a DMC catalyst are first provided in a reactor, b) alkene oxide is added in such a way that the dosing speed, which is maintained for the continuous operation of the reactor, is reached within 100 to 3000 seconds, c) during or after step b) the initiation substance is added in such a way that the dosing speed, which is maintained for the continuous operation of the reactor, is reached within 5 to 500 seconds, d) once the contents of the reactor have reached the desired level for the continuous operation of said reactor, the product is continuously removed. The initiation substance and alkene oxide are added simultaneously in quantities that enable the level of the contents in the reactor to remain constant and the DMC catalyst is added in such a way that the catalyst concentration required for the continuous operation of the reactor is maintained.

    VERFAHREN ZUR HERSTELLUNG VON POLYETHEROLEN
    7.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON POLYETHEROLEN 审中-公开

    公开(公告)号：EP1539855A1

    公开(公告)日：2005-06-15

    申请号：EP03748004.3

    申请日：2003-09-11

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： BOHRES, Edward ,  HIBST, Hartmut ,  STÖSSER, Michael ,  RUPPEL, Raimund ,  BAUM, Eva

    IPC分类号： C08G65/26

    CPC分类号： C08G65/2645 ,  C08G65/266

    摘要： The invention relates to a method for the production of a polyetherol, wherein at least one alkylene oxide is reacted with at least one starter compound in the presence of one catalyst of general formula (I): M1p[M2qOn(OH)2(3-n)]x, The invention also relates to polyetherols produced according one inventive method and the use thereof for polyurethane synthesis, as a fuel additive or as a surfactant.

    摘要翻译： 本发明涉及一种生产聚醚醇的方法，其中至少一种烯化氧在至少一种通式（I）的催化剂存在下与至少一种起始化合物反应：M1p [M2qOn（OH）2（3- 本发明还涉及根据一种发明方法生产的聚醚醇及其在聚氨酯合成中的用途，作为燃料添加剂或作为表面活性剂。

    MULTIMETALLCYANID-KATALYSATOREN
    9.
    发明公开
    MULTIMETALLCYANID-KATALYSATOREN 有权
    用于生产聚醚多元醇使用结晶多金属氰化物催化剂

    公开(公告)号：EP1185367A1

    公开(公告)日：2002-03-13

    申请号：EP00935078.6

    申请日：2000-05-19

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： GROSCH, Georg, Heinrich ,  HARRE, Kathrin ,  ERBES, Jörg ,  LORENZ, Reinhard ,  BAUER, Stephan ,  OSTROWSKI, Thomas ,  BAUM, Eva ,  JUNGE, Dieter

    IPC分类号： B01J27/26 ,  C08G65/10

    CPC分类号： C08G65/2663 ,  B01J27/26

    摘要： The invention relates to multi-metal cyanide compounds of the general formula (I). In said formula: M1 represents at least one metal ion, selected from the group containing Zn?2+, Fe2+, Co3+, Ni2+, Mn2+, Pb2+, Fe3+, Mo4+, Mo6+, Al3+, V5+, Sr2+, W4+, W6+, Cu2+, Cr2+, Cr3+, Cd2+, Hg2+, Pd2+, Pt2+, V2+, Mg2+, Ca2+, Ba2+; M2¿ represents at least one metal ion, selected from the group containing Fe?2+, Fe3+, Co3+, Cr3+, Mn2+, Mn3+, Rh3+, Ru2+, Ru3+, V4+, V5+, Co2+, Ir3+ and Cr2+ and M2¿ is different from M1; X represents at least one anion, selected from the group containing halide, hydroxide, sulphate, carbonate, cyanide, thiocyanate, isocyanate, carboxylate, in particular, formiate, acetate, propionate, oxalate, nitrate; A represents at least one anion, selected from the group containing halide, hydroxide, sulphate, carbonate, cyanate, thiocyanate, isocyanate, carboxylate or nitrate, in particular, cyanide; a, b, c and d are whole or fractional numbers which are selected in such a way, that the electroneutrality of the cyanide compound is guaranteed, whereby a, b and d are greater than zero and c is greater than or equal to zero; e is a whole or fractional number greater than zero and h is a whole or fractional number greater than or equal to zero; and f and g are whole or fractional numbers which are selected in such a way that the electroneutrality of M1fXg is guaranteed.

    PROCESS FOR PREPARING REACTIVE POLYETHER POLYOLS HAVING AN ETHYLENE OXIDE END BLOCK
    10.
    发明授权
    PROCESS FOR PREPARING REACTIVE POLYETHER POLYOLS HAVING AN ETHYLENE OXIDE END BLOCK 有权
    用于生产环氧乙烷末端块活性聚醚多元醇

    公开(公告)号：EP1753802B1

    公开(公告)日：2008-01-23

    申请号：EP05744275.8

    申请日：2005-04-21

    申请人： BASF Aktiengesellschaft

    发明人： OSTROWSKI, Thomas ,  RUPPEL, Raimund ,  HÖPPNER, Gerd ,  BERGMANN, Sascha ,  VANDEWALLE, Koen ,  BAUM, Eva

    IPC分类号： C08G65/26 ,  C08G18/48

    CPC分类号： C08G65/2696 ,  C08G18/4841 ,  C08G18/4866 ,  C08G65/2663

    摘要： Process for preparing polyether polyols having an end block of ethylene oxide by addition of alkylene oxides onto H-functional starter substances, in which A) a polyether polyol precursor is prepared by means of double metal cyanide (DMC) catalysis in a semicontinuous mode of operation in which previously prepared polyether polyol together with the DMC catalyst are placed in a reactor and H-functional starter substance and propylene oxide are added continuously; B) the polyether polyol precursor from stage A) is reacted with propylene oxide or an ethylene oxide/propylene oxide mixture in the presence of the DMC catalyst in a continuously operating reactor to give a polyether polyol intermediate; C) the intermediate from stage B) is mixed with an alkali metal hydroxide as catalyst and D) reacted with ethylene oxide in a continuously operating reactor to give the final product; E) the catalyst is separated off from the final product obtained in stage D).