公开(公告)号：EP3325122B1

公开(公告)日：2020-02-05

申请号：EP16736068.4

申请日：2016-07-05

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas

IPC分类号： B01D3/32 ,  C07C51/44 ,  B08B9/093

公开(公告)号：EP3177379A1

公开(公告)日：2017-06-14

申请号：EP15747794.4

申请日：2015-08-04

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas

IPC分类号： B01D3/22 ,  B01D3/32

CPC分类号： F25J3/0271 ,  B01D3/20 ,  B01D3/22 ,  B01D3/32 ,  B01D3/4261 ,  C07C45/783 ,  C07C45/80 ,  C07C45/82 ,  C07C51/44 ,  C07C51/48 ,  C07C67/54 ,  C07C47/22 ,  C07C57/04 ,  C07C69/54

摘要： The invention relates to a column (1) for the thermal treatment of a fluid, comprising: a cylindrical, vertically oriented column body (2) forming a column hollow chamber (3); and a material exchange base (4) arranged in the column hollow chamber (3), forming a collecting surface (5). The column (1) according to the invention is characterised by a circulation device (9) comprising: at least one outlet opening (10) formed in the column body (2) above the collecting surface (5); a circulation line (11) in fluid connection with the outlet opening (10); and at least one recirculation opening (14; 14-1 to 14-3) which is in fluid connection with the circulation line (11), and which is formed in the column body (2) above the collection surface (5). The invention also relates to a thermal separation method, wherein a column (1) of this type is used. With this separation method, a gas rises in the column and a liquid falls in the column, wherein the gas and/or the liquid contains in particular (meth)acrylmonomers.

摘要翻译： 本发明涉及一种用于流体热处理的塔（1），该塔具有形成柱空腔（3）的圆柱形垂直柱体（2）和设置在该柱中的传质塔盘（4） 空腔（3）并形成收集区域（5）。 本发明的塔（1）的特征在于循环装置（9），其具有在收集区域（5）上方的柱体（2）中形成的至少一个排放孔口（10），循环管线（11） 排放孔（10）和至少一个循环孔（14; 14-1至14-3），所述循环孔与循环管线（11）流体连通并形成在塔体（2）中的收集区域上方 5）。 本发明还涉及一种使用这种塔（1）的热分离方法。 在该分离过程中，气体在塔内上升并且液体在塔内下降，所述气体和/或液体尤其包含（甲基）丙烯酸单体。

公开(公告)号：EP2827961A1

公开(公告)日：2015-01-28

申请号：EP13707397.9

申请日：2013-03-05

申请人： BASF SE

发明人： MÜLLER-ENGEL, Klaus Joachim ,  WALTER, Thomas ,  HÜTTEN, Frank ,  OTTENBACHER, Markus ,  HAMMON, Ulrich

IPC分类号： B01D3/16

CPC分类号： B01J19/32 ,  B01D3/16 ,  B01D3/225 ,  B01F3/0446 ,  B01J2219/322 ,  B01J2219/3327 ,  C07C51/42 ,  C07C67/48 ,  C07C57/04 ,  C07C69/54

摘要： A thermal separating method between a gas rising in a separation column and a liquid, containing (meth)acrylic monomers, descending in the separation column, wherein the separation column contains a sequence of cross-current material exchange trays, the cross-current material exchange trays of which have passage openings for the rising gas both upstream and downstream, in the direction of the cross current, of an outlet shaft for the descending liquid, as well as such cross-current material exchange trays, and a sequence of cross-current material exchange trays contained in a separation column.

公开(公告)号：EP3201167B1

公开(公告)日：2020-08-05

申请号：EP15775409.4

申请日：2015-09-23

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas ,  OTTENBACHER, Markus ,  HÜTTEN, Frank

IPC分类号： B01D3/34 ,  C07C51/48 ,  C07C51/44 ,  C07C51/42 ,  C07C57/04

公开(公告)号：EP3325122A1

公开(公告)日：2018-05-30

申请号：EP16736068.4

申请日：2016-07-05

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas

IPC分类号： B01D3/32 ,  C07C51/44 ,  B08B9/093

CPC分类号： B01D3/32 ,  B01D3/008 ,  B01D3/26 ,  B01D3/324 ,  B08B3/02 ,  B08B9/00 ,  B08B9/093 ,  C07C51/44 ,  C07C57/04

摘要： The invention relates to a column (1) for thermally treating fluid mixtures, comprising a cylindrical, vertically-aligned column body (2) that forms a column cavity (3), a plurality of trays (8) which are mounted in the column cavity (3) and vertically spaced apart from one another, at least one neck (11) arranged in the column body (2) and extending away from said column body (2), and a closeable inspection opening (9) formed at the neck (11). The claimed column is characterised in that a spray device (20) is arranged in the column body (2) and can spray liquid (22) at least against the neck (11) surface (15) directed into the column cavity (3).

公开(公告)号：EP3177380A1

公开(公告)日：2017-06-14

申请号：EP15747792.8

申请日：2015-08-04

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas

IPC分类号： B01D3/32

摘要： The invention relates to a column (1) for thermally treating fluid mixtures, comprising a vertically aligned cylindrical column body (2) which forms a hollow column space (3), multiple bases (8) which are mounted in the hollow column space (3) in a mutually vertically spaced manner, and a support structure (9) which supports at least one of the bases (8) in the vertical direction. The column (1) according to the invention is characterized in that the support structure (9) has multiple openings (12) which allow a horizontal exchange of materials by means of the support structure (9). The invention further relates to a base device for such a column and to a thermal separating method between at least one gas which is ascending in such a column (1) and at least one liquid which is descending in the column (1).

摘要翻译： 本发明涉及一种用于流体混合物的热处理的塔（1），具有圆柱形，垂直柱主体（2）形成的柱腔（3），托盘的多个（8），安装有垂直间距在列 腔（3）和支撑结构（9），它支持在垂直方向上的托盘（8）中的至少一个。 它是本发明的柱的特性特征（1）那样的支撑结构（9）具有孔的多个（12），其允许通过支撑结构的水平传质（9）。 本发明进一步涉及一个盘装置为寻求一个柱和一个搜索塔（1）内的至少一个气体上升和至少一种液体的塔（1）内降之间的热分离过程。

公开(公告)号：EP3154672A1

公开(公告)日：2017-04-19

申请号：EP15728831.7

申请日：2015-06-09

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas

IPC分类号： B01J8/06 ,  C07C51/25

CPC分类号： B01J8/0278 ,  B01J8/065 ,  B01J8/067 ,  B01J2208/00017 ,  B01J2208/00176 ,  B01J2208/0053 ,  B01J2208/00893 ,  C07C45/28 ,  C07C45/35 ,  C07C51/16 ,  C07C51/252 ,  Y02P20/582 ,  C07C57/04 ,  C07C47/22

摘要： The invention relates to a system (1) for carrying out heterogeneous catalytic gas-phase reactions, comprising: a reactor (3); at least one line (11), leading into the reactor (3), for introducing reagents into the reactor (3); at least one first feed (5), leading into the line (11), for providing at least one first reagent A; at least one second feed (7), leading into the line (11), for providing at least one second reagent B; at least one third feed (9), leading into the line (11), for providing a circuit gas G; a temperature-control unit (13), arranged upstream from the reactor (3) in the line (11), for controlling the temperature of the first reagent A and/or second reagent B and/or the circuit gas G before entering into the reactor (3); and at least one outlet (15) for products, by-products and/or unreacted reagents of the gas-phase reaction. The invention also relates to a method for carrying out heterogeneous catalytic gas-phase reactions.

摘要翻译： 本发明涉及一种用于非均相催化气相反应的性能的设备（1），包括一个反应器（3），至少一个线路（11）导入所述反应器（3）用于引入反应物到反应器中（3） 中，至少一个第一进料（5），用于提供至少一个第一反应物A，这导致进入管线（11），至少一个第二进料（7），用于提供至少一个第二反应物B，这导致进线（ 11）中，至少一个第三进料（9），用于在反应器上游提供一个循环气体G，这导致进入管线（11），其在管线（11设置在温度控制单元（13）所有的）（3） 并且是用于之前进入反应器（3）和至少一个出口（15），用于产品控制所述第一反应物A和/或第二反应物B和/或循环气体G的温度，副产物和/或未反应的 从气相反应的反应物。 本发明还涉及一种用于执行非均相催化气相反应。

公开(公告)号：EP3389809A1

公开(公告)日：2018-10-24

申请号：EP16819873.7

申请日：2016-12-16

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas

IPC分类号： B01D3/20 ,  B01D3/22

CPC分类号： B01D3/324 ,  B01D3/20 ,  B01D3/205 ,  B01D3/225 ,  B01D3/26 ,  B01D3/32 ,  B01D53/18 ,  C07C51/42 ,  C07C51/44 ,  C07C67/52 ,  C07C57/04

摘要： The invention relates to a column (1) for thermally treating fluid mixtures, comprising a vertically aligned cylindrical column body (2) which forms a column cavity (3), a sequence of vertically spaced dual-flow material exchange bases (8) which are mounted in the column cavity (3) and which have openings for the passage of liquid and gas in counter-flow, and at least one gas inlet opening (5) which is arranged below the lowermost base of the sequence of dual-flow material exchange bases (8). The column according to the invention is characterized in that a gas distribution base (9) is arranged between the lowermost base of the sequence of dual-flow material exchange bases (8) and the gas inlet opening (5), said gas distribution base having openings (32) for the vertical passage of gas which can be introduced into the column cavity (3) via the gas inlet opening (5). The openings (32) are designed to cause a uniform distribution of gas over the column cross-section. The invention further relates to a method for thermally treating fluid mixtures in such a column (1).

公开(公告)号：EP3325121A1

公开(公告)日：2018-05-30

申请号：EP16736065.0

申请日：2016-07-05

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas

IPC分类号： B01D3/32

CPC分类号： B01D3/32 ,  B01D3/26 ,  B01D3/324 ,  C07C45/80 ,  C07C51/44 ,  C07C51/48 ,  C07C57/04

摘要： The invention relates to a column (1) for thermally treating fluid mixtures, comprising a cylindrical, vertically-aligned column body (2) that forms a column cavity (3) and a vertical inner surface (16), a plurality of trays (8) which are mounted in said column cavity (3) and vertically spaced apart from one another, at least one neck (11) arranged in the column body (2) and extending away from said column body (2), and a closeable inspection opening (9) formed at the neck (11). The claimed column is characterised in that, in a vertical cross-section of the column (1), the surface (15) of the lower intersection line of the neck (11), directed into the column cavity (3), or a tangent to the surface (15) of said lower intersection line of the neck (11), forms, together with the vertical inner surface (16) of the column body (2) which extends downwards from said neck (11), an angle in the range of 210° to 267°, at least in some sections.

公开(公告)号：EP3201167A1

公开(公告)日：2017-08-09

申请号：EP15775409.4

申请日：2015-09-23

申请人： BASF SE

发明人： HAMMON, Ulrich ,  WALTER, Thomas ,  OTTENBACHER, Markus ,  HÜTTEN, Frank

IPC分类号： C07C51/42 ,  C07C51/44 ,  C07C57/04

摘要： The invention relates to a method for recovering acrylic acid, having the following steps a) separating a temperature-controlled mother acid stream from a crystallization device in the direction of an absorption column (201) and in the direction of a splitting column (205), b) supplying the first temperature-controlled mother acid sub-stream as a return flow to the top plate of the splitting column (205), c) supplying at least one strip gas stream below the bottom plate of the splitting column (205), d) supplying an auxiliary component stream, which comprises an oligomeric acrylic acid, from the condensation column (201) to a central base of the splitting column (205), e) splitting at least one part of the oligomeric acrylic acid from the auxiliary component stream in the splitting column (205), thereby obtaining monomeric acrylic acid, f) separating the auxiliary components contained in the auxiliary component stream by means of a counter-current rectification process in the splitting column (205), g) discharging the monomeric acrylic acid without condensation as a gas mixture together with the supplied strip circuit gas stream at the head of the splitting column (205), and h) supplying the gas mixture below the bottom plate of the condensation column (201). The invention further relates to a system (1) for recovering acrylic acid.

摘要翻译： 一种回收丙烯酸的方法，包括：a）在吸收方向上将加热的母酸物流分成冷凝塔和分离塔; b）将经加热的母酸分子流作为回流供给到解离柱; c）将至少一个汽提气流输入到解离塔中; d）将包含低聚丙烯酸的次要组分料流从吸收塔加入到解离塔中; e）在解离塔中解离部分低聚丙烯酸以产生单体丙烯酸; f）去除包含在解离塔中的次要组分流中的次要组分; g）将单体丙烯酸作为气体混合物与来自解离塔的引入循环汽提气流一起排出; 和h）将气体混合物输入吸收塔。