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1.发明公开
公开(公告)号：EP4321181A1
公开(公告)日：2024-02-14
申请号：EP22306206.8
申请日：2022-08-10
申请人： Centre national de la recherche scientifique , École Normale Supérieure , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Instituto Superior Técnico , Faculdade De Ciências da Universidade de Lisboa
发明人： SERRE, Christian , TISSOT, Antoine , CAO, Chenchen , LUZIA GONCALVES PINTO, Moisés , SILVA, João , ANTUNES, Fernando , PINTO, Rosana
摘要： The present invention belongs to the field of nanoporous materials, in particular metal organic frameworks (MOFs) and Lewis-based gas delivery and/or slow release, or the detection of Lewis-based gas(es) in gases or liquid streams.
The present invention relates, inter alia, to a new ultra-microporous crystalline metal organic framework solid ( comprising bisphosphonic acid ligands (also refered to as Phosphonate MOF), such as MIP-210(M) and uses thereof as a carrier in Lewis-based gas (such as NO) delivery. The invention also relates to controlled release of the Lewis-based gas in wounds, for example by topical application. The invention also encompasses a synthetic method for producing the new ultra-microporous crystalline metal organic framework solid of the invention.
The MOFs of the present invention can be used in various applications such as gas carrier and/or for the controlled release of gas. The MOFs of the present invention thus are very versatile and have therapeutic and non therapeutic applications.-
公开(公告)号：EP4444461A1
公开(公告)日：2024-10-16
申请号：EP22814466.3
申请日：2022-12-02
申请人： Centre National de la Recherche Scientifique , École Normale Supérieure , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Instituto Superior Técnico
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3.发明公开
公开(公告)号：EP4194084A1
公开(公告)日：2023-06-14
申请号：EP21306747.3
申请日：2021-12-10
申请人： Centre National de la Recherche Scientifique , École Normale Supérieure , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Instituto Superior Técnico
发明人： SEVERINO NEVES, Maria Inès , SERRE, Christian , NOUAR, Farid , PINTO, Moisès , AL MOTHAR, Abeer , FREITAS, Catia
摘要： The present invention relates, inter alia, to the use of porous crystalline solids constituted of a metal-organic framework (MOF) for the selective capture of volatile organic compounds (VOCs) comprising carboxylic acid functional group(s).
The MOF solids of the present invention can be used for the purification of air, for example for the selective capture of VOCs comprising carboxylic acid functional group(s) from outdoor air. It may be used for art preservation, such as the conservation of cellulose derivate films, for indoor air purification systems such as HEPA air filters, adsorbent purifiers, kettle filters, fette filters, honeycomb filters or air conditioning filters, for outdoor air purification systems such as gas mask, nose filter, adsorption columns or chimney filters, and in cosmetic applications such as deodorants, anti-odor shampoo, hygienic protection products, wipes or diapers.-
公开(公告)号：EP4054739A1
公开(公告)日：2022-09-14
申请号：EP20800150.3
申请日：2020-11-04
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5.发明公开
公开(公告)号：EP4373802A1
公开(公告)日：2024-05-29
申请号：EP22754135.6
申请日：2022-07-22
申请人： Centre National de la Recherche Scientifique , École Normale Supérieure , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris
CPC分类号： C07F5/069 , C07C51/418 , B01J20/226 , B01J31/1691 , B01J20/3085 , B01D53/02 , B01D2253/20420130101
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公开(公告)号：EP3453450A1
公开(公告)日：2019-03-13
申请号：EP17306170.6
申请日：2017-09-12
申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , Ecole Normale Supérieure de Paris , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Université de Versailles Saint-Quentin-en-Yvelines , Instituto Superior Técnico
发明人： SERRE, Christian , PINTO, Moisès L.
摘要： The present invention relates, inter alia, to the use of porous crystalline solids constituted of a metal-organic framework (MOF) for the capture of polar volatile organic compounds (VOCs). In particular, the MOF of interest are material comprising an average pores sizes of 0.4 to 0.6 nm and an hydrophobic core formed by a metal oxide and/or hydroxide network connected by linkers, said linkers being selected from the group comprising (i) C 6 -C 24 aromatic polycarboxylate linkers, such as benzyl or naphtyl di-, tri- or tetracarboxylate, and (ii) C 6 -C 16 polycarboxylate aliphatic linkers; the linkers bearing or not apolar fluorinated groups, e.g. -(CF 2 ) n -CF 3 groups, n being a integer from 0 to 5, preferably 0 ou 3, and/or apolar C 1 -C 20 preferably C 1 -C 4 alkyl groups, e.g. -CH 3 or -CH 2 -CH 3 , grafted directly to the linkers and pointing within the pores of the MOF. The MOF solids used in the present invention can be used for the purification of air, for example for the capture of polar VOCs like acetic acid and aldehydes from indoor air in cars, museums and archives, much more efficiently than common adsorbents, particularly in presence of humidity. They can in particular be used for the preservation of cultural heritage.
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公开(公告)号：EP3681627A1
公开(公告)日：2020-07-22
申请号：EP18765456.1
申请日：2018-09-12
申请人： Centre National de la Recherche Scientifique , Ecole Normale Supérieure de Paris , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Université de Versailles Saint-Quentin-en-Yvelines , Instituto Superior Técnico
发明人： SERRE, Christian , PINTO, Moisés L.
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8.发明公开
公开(公告)号：EP3498368A1
公开(公告)日：2019-06-19
申请号：EP17306798.4
申请日：2017-12-18
申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , Ecole Normale Supérieure de Paris , Ecole Nationale Supérieure de Chimie de Montpellier , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Université de Montpellier , Université de Versailles Saint-Quentin-en-Yvelines
发明人： SERRE, Christian , WANG, Sujing , MAURIN, Guillaume , WAHIDUZZAMAN, Mohammad , DEVAUTOUR-VINOT, Sabine
摘要： The present invention relates to crystalline Zr-, Hf-, Ln-based MOFs having aliphatic or heteroaliphatic, preferably aliphatic, linkers; a process of preparing same and uses thereof, particularly as separation/purification material, or as proton conductive material (fuel cells), or as water sorption material, or as catalyst; for example for gas separation, small molecule separation, for CO 2 /N 2 separation, separation of chiral molecules, size/shape-based molecule separation, or separation/extraction of metallic ions, as water sorption material, in adsorption-type cooling/heating systems, as catalyst, in biomass conversion systems/reactions.
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公开(公告)号：EP3978113A1
公开(公告)日：2022-04-06
申请号：EP20382882.7
申请日：2020-10-05
申请人： Consejo Superior de Investigaciones Científicas (CSIC) , Universitat Politècnica de València , Paris Sciences et Lettres , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Centre national de la recherche scientifique , Ecole Normale Supérieure
发明人： NAVALÓN OLTRA, Sergio , VALLÉS GARCÍA, Cristina , CABRERO ANTONINO, María , GARCÍA GÓMEZ, Hermenegildo , SERRE, Christian , MOUCHAHAM, Georges , ZHOU, Lin
摘要： The present invention relates to metal-organic frameworks (MOFs) which contain trimetallic centres with pyrazole as a ligand in the structure thereof. Particularly, it relates to MOFs which contain units of formula (I). The present invention also relates to a photocatalytic method for generating H 2 starting from liquid water or vapour using said materials.
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10.发明公开
公开(公告)号：EP3680311A1
公开(公告)日：2020-07-15
申请号：EP19305025.9
申请日：2019-01-08
申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , Instituto Politécnico De Bragança , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Ecole Normale Supérieure de Paris , Universidade Do Porto
摘要： The present invention relates to the use of 2,5-furanedicarboxylate-based MOFs, such as, MIL-160(AI) metal-organic framework, for separating C6 alkane isomers into linear, mono-branched and di-branched isomers. The present invention also relates to the use of 2,5-furanedicarboxylate-based MOFs, such as, MIL-160(AI) metal-organic framework, preferably in combination with Zeolite 5A for producing higher research octane number gasoline blends. Also within the scope of the invention is a system for separating C6 and C5 alkane isomer mixtures into linear, mono-branched and di-branched fractions.
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