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12 条记录 (耗时 0.017 秒)

    KATALYSATOREN FÜR DIE HERSTELLUNG VON ISOCYANURATEN AUS ISOCYANATEN
    2.
    发明公开
    KATALYSATOREN FÜR DIE HERSTELLUNG VON ISOCYANURATEN AUS ISOCYANATEN 审中-公开
    KATALYSATORENFÜRDIE HERSTELLUNG VON ISOCYANURATEN AUS ISOCYANATEN

    公开(公告)号：EP3230333A1

    公开(公告)日：2017-10-18

    申请号：EP15807926.9

    申请日：2015-12-10

    申请人： Covestro Deutschland AG

    发明人： MÜLLER, Thomas Ernst ,  HAGEN, Torsten ,  RAFFEL, Bolko ,  GÜRTLER, Christoph ,  VOGT, Henning ,  AL NABULSI, Abdulghani ,  KÖHLER, Burkhard ,  LEITNER, Walter

    IPC分类号： C08G18/48 ,  C08G18/79 ,  C08G18/02 ,  C08G18/09 ,  C08G18/16 ,  C08G18/22 ,  C08G18/42

    CPC分类号： B01J31/0229 ,  B01J2231/14 ,  C07D251/30 ,  C08G18/022 ,  C08G18/092 ,  C08G18/10 ,  C08G18/14 ,  C08G18/168 ,  C08G18/225 ,  C08G18/4018 ,  C08G18/4238 ,  C08G18/4833 ,  C08G18/7671 ,  C08G18/791 ,  C08G2101/0025 ,  C08G2105/02 ,  C08G2330/00 ,  C08J9/141 ,  C08J2203/14 ,  C08J2205/10 ,  C08J2375/06

    摘要： The invention relates to a method for producing isocyanurates and isocyanurate-containing polyurethanes, comprising the step of reacting an isocyanate in the presence of a catalyst. Said method is characterized in that the catalyst comprises the product of the reaction of a carboxylic acid containing thiol groups with an alkali-metal, alkaline-earth-metal, scandium-group, or lanthanoid base, wherein the reaction is performed in the absence of compounds containing tin and/or lead, wherein the degree of deprotonation of the catalyst is > 50% to ≤ 100% and the H atoms present in carboxyl groups, the carboxylate groups, the H atoms present in thiol groups, and the thiolate groups are also taken into account in the calculation of the degree of deprotonation. The catalyst is preferably a dipotassium salt of 2-mercaptoacetic acid, 3-mercaptopropionic acid, 4-mercaptobutyric acid, and/or thiosalicylic acid. Even at low temperatures, isocyanurates and/or isocyanurate units and in particular mixtures of isocyanurates and/or isocyanurate units and carbamates and/or urethane units, which are present in isocyanurate-containing polyurethanes (PUR/PIR systems), are obtained at a higher reaction speed than in the case of comparable methods in which catalysts that do not contain mercapto groups, such as potassium acetate, are used.

    摘要翻译： 本发明涉及一种生产异氰脲酸酯和含异氰脲酸酯的聚氨酯的方法，该方法包括在催化剂存在下使异氰酸酯反应的步骤。 所述方法的特征在于所述催化剂包含含硫醇基团的羧酸与碱金属，碱土金属，钪基团或镧系元素碱的反应产物，其中所述反应在不存在 含有锡和/或铅的化合物，其中催化剂的去质子化程度为> 50％至≤100％，存在于羧基中的H原子，羧酸盐基团，存在于硫醇基团中的H原子和硫醇盐基团为 在计算去质子化程度时也考虑到了这一点。 催化剂优选为2-巯基乙酸，3-巯基丙酸，4-巯基丁酸和/或硫代水杨酸的二钾盐。 即使在低温下，异氰脲酸酯和/或异氰脲酸酯单元，特别是存在于含异氰脲酸酯的聚氨酯（PUR / PIR体系）中的异氰脲酸酯和/或异氰脲酸酯单元和氨基甲酸酯和/或氨基甲酸酯单元的混合物， 反应速度比使用不含巯基的催化剂如乙酸钾的可比较方法的情况下更快。

    FUNKTIONALISIERTE POLYOXYMETHYLEN-BLOCK-COPOLYMERE
    8.
    发明公开
    FUNKTIONALISIERTE POLYOXYMETHYLEN-BLOCK-COPOLYMERE 有权
    FUNKTIONALISIERTE聚氧乙烯嵌段共聚物

    公开(公告)号：EP2935381A2

    公开(公告)日：2015-10-28

    申请号：EP13814099.1

    申请日：2013-12-18

    申请人： Covestro Deutschland AG

    发明人： MÜLLER, Thomas Ernst ,  GÜRTLER, Christoph ,  LEITNER, Walter ,  VOGT, Henning ,  BARATH, Gabor

    IPC分类号： C08G2/38 ,  C08G18/48 ,  C08G18/56 ,  C08G65/16 ,  C08G65/331 ,  C08G65/332

    CPC分类号： C08G65/00 ,  C08G2/38 ,  C08G18/08 ,  C08G18/48 ,  C08G18/4825 ,  C08G18/4829 ,  C08G18/4887

    摘要： The invention relates to a method for producing functionalized polyoxymethylene block copolymers comprising the step of polymerizing formaldehyde in a reaction vessel in the presence of a catalyst, the polymerization of formaldehyde in addition taking place in the presence of a starter compound comprising at least 2 Zerewitinoff active H atoms, to obtain an intermediate product. The intermediate product obtained is subsequently reacted with a cyclic carboxylic acid ester or carbonic acid ester, thus obtaining a functionalized polyoxymethylene block copolymer. The invention further relates to functionalized polyoxymethylene block copolymers obtained by such a method and to the use of said copolymers.

    摘要翻译： 本发明涉及一种生产官能化聚甲醛嵌段共聚物的方法，其包括在催化剂存在下在反应容器中聚合甲醛的步骤，另外在存在起始化合物的情况下进行甲醛的聚合，所述起始化合物包含至少2个Zerewitinoff活性 H原子，得到中间产物。 随后将所得中间产物与环状羧酸酯或碳酸酯反应，得到官能化聚甲醛嵌段共聚物。 本发明还涉及通过这种方法获得的官能化聚甲醛嵌段共聚物和所述共聚物的用途。

    CATALYSTS FOR THE SYNTHESIS OF OXAZOLIDINONE COMPOUNDS
    10.
    发明公开
    CATALYSTS FOR THE SYNTHESIS OF OXAZOLIDINONE COMPOUNDS 有权
    用于合成恶唑烷酮化合物的催化剂

    公开(公告)号：EP3143059A1

    公开(公告)日：2017-03-22

    申请号：EP15722991.5

    申请日：2015-05-07

    申请人： Covestro Deutschland AG

    发明人： MÜLLER, Thomas Ernst ,  GÜRTLER, Christoph ,  BASU, Susmit ,  RANGHEARD, Claudine ,  WEBER, Anna ,  VOGT, Henning ,  LEITNER, Walter

    IPC分类号： C08G18/00 ,  C08G18/76 ,  C08G18/71 ,  C08G59/40 ,  C08G18/16

    CPC分类号： C08G18/003 ,  C07D263/22 ,  C08G18/168 ,  C08G18/71 ,  C08G18/7621 ,  C08G59/4028

    摘要： The present invention relates to a method for the production of oxazolidinone compounds with low colour intensity, comprising the step of reacting an isocyanate compound with an epoxide compound in the presence of a catalyst which is free of halide anions. The invention further relates to a method for the production of oligooxazolidinone and/or polyoxazolidinone compounds, comprising the step of reacting a polyisocyanate compound with a polyepoxide compound in the presence of said catalyst. The invention further relates to oligooxazolidinone and/or polyoxazolidinone compounds with low colour intensity, obtainable by a method according to the invention.

    摘要翻译： 本发明涉及生产低色度恶唑烷酮化合物的方法，该方法包括在不含卤化物阴离子的催化剂存在下使异氰酸酯化合物与环氧化合物反应的步骤。 本发明进一步涉及生产低聚唑烷酮和/或聚恶唑烷酮化合物的方法，包括在所述催化剂存在下使多异氰酸酯化合物与聚环氧化物化合物反应的步骤。 本发明进一步涉及通过根据本发明的方法可获得的低色度的低聚恶唑烷酮和/或聚恶唑烷酮化合物。