KATALYSATOREN FÜR DIE HERSTELLUNG VON ISOCYANURATEN AUS ISOCYANATEN
    2.
    发明公开
    KATALYSATOREN FÜR DIE HERSTELLUNG VON ISOCYANURATEN AUS ISOCYANATEN 审中-公开
    KATALYSATORENFÜRDIE HERSTELLUNG VON ISOCYANURATEN AUS ISOCYANATEN

    公开(公告)号:EP3230333A1

    公开(公告)日:2017-10-18

    申请号:EP15807926.9

    申请日:2015-12-10

    摘要: The invention relates to a method for producing isocyanurates and isocyanurate-containing polyurethanes, comprising the step of reacting an isocyanate in the presence of a catalyst. Said method is characterized in that the catalyst comprises the product of the reaction of a carboxylic acid containing thiol groups with an alkali-metal, alkaline-earth-metal, scandium-group, or lanthanoid base, wherein the reaction is performed in the absence of compounds containing tin and/or lead, wherein the degree of deprotonation of the catalyst is > 50% to ≤ 100% and the H atoms present in carboxyl groups, the carboxylate groups, the H atoms present in thiol groups, and the thiolate groups are also taken into account in the calculation of the degree of deprotonation. The catalyst is preferably a dipotassium salt of 2-mercaptoacetic acid, 3-mercaptopropionic acid, 4-mercaptobutyric acid, and/or thiosalicylic acid. Even at low temperatures, isocyanurates and/or isocyanurate units and in particular mixtures of isocyanurates and/or isocyanurate units and carbamates and/or urethane units, which are present in isocyanurate-containing polyurethanes (PUR/PIR systems), are obtained at a higher reaction speed than in the case of comparable methods in which catalysts that do not contain mercapto groups, such as potassium acetate, are used.

    摘要翻译: 本发明涉及一种生产异氰脲酸酯和含异氰脲酸酯的聚氨酯的方法,该方法包括在催化剂存在下使异氰酸酯反应的步骤。 所述方法的特征在于所述催化剂包含含硫醇基团的羧酸与碱金属,碱土金属,钪基团或镧系元素碱的反应产物,其中所述反应在不存在 含有锡和/或铅的化合物,其中催化剂的去质子化程度为> 50%至≤100%,存在于羧基中的H原子,羧酸盐基团,存在于硫醇基团中的H原子和硫醇盐基团为 在计算去质子化程度时也考虑到了这一点。 催化剂优选为2-巯基乙酸,3-巯基丙酸,4-巯基丁酸和/或硫代水杨酸的二钾盐。 即使在低温下,异氰脲酸酯和/或异氰脲酸酯单元,特别是存在于含异氰脲酸酯的聚氨酯(PUR / PIR体系)中的异氰脲酸酯和/或异氰脲酸酯单元和氨基甲酸酯和/或氨基甲酸酯单元的混合物, 反应速度比使用不含巯基的催化剂如乙酸钾的可比较方法的情况下更快。

    POLYLACTIC ACID RESIN FILM
    5.
    发明公开
    POLYLACTIC ACID RESIN FILM 审中-公开
    POLYMILCHSÄUREHARZFOLIE

    公开(公告)号:EP2669320A4

    公开(公告)日:2017-07-05

    申请号:EP11857120

    申请日:2011-11-02

    摘要: The present invention relates to a polylactic acid resin film which has excellent flexibility, mechanical properties, stability, and transparency while having a specific biodegradability of the polylactic acid resin, and is useful as a packaging material. The present invention provides a polylactic acid resin film, comprising a polylactic acid resin including a hard segment comprising a specific polylactic acid repeating unit, and a soft segment comprising a polyurethane polyol repeating unit in which a specific polyether polyol repeating units are linearly linked via a urethane bond, wherein the total Young's modulus in both machine direction and transverse direction of the film is 350 to 750 kgf/mm 2 , and the total initial tensile strength in both machine direction and transverse direction of the film is 20 kgf/mm 2 or more.

    摘要翻译: 本发明涉及聚乳酸树脂膜,其具有优异的柔性,机械性能,稳定性和透明性,同时具有聚乳酸树脂的特定生物降解性,并且可用作包装材料。 本发明提供聚乳酸树脂膜,其包含聚乳酸树脂,该聚乳酸树脂包含含有特定聚乳酸重复单元的硬链段和软链段,该软链段包含聚氨酯多元醇重复单元,其中特定聚醚多元醇重复单元通过 氨基甲酸酯键,其中膜的纵向和横向方向上的总杨氏模量为350-750kgf / mm 2,膜的纵向和横向两个方向上的总初始拉伸强度为20kgf / mm 2或 更多。

    DIELEKTRISCHE EAP FOLIEN MIT NIEDRIGEM GLASPUNKT AUF DER BASIS VON POLYESTERPOLYOLEN

    公开(公告)号:EP3143061A1

    公开(公告)日:2017-03-22

    申请号:EP15719757.5

    申请日:2015-05-08

    摘要: The present invention relates to a method for producing a dielectric polyurethane film from a mixture comprising A) a compound containing isocyanate groups having a content of isocyanate groups of ≥ 10 and ≤ 50 wt.% and a number-average functionality of isocyanate groups of ≥ 2.6 and ≤ 4 and B) a polyester polyol having an OH-number of ≥ 27 and ≤ 120 mg KOH/g, determined in accordance with DIN 53240, characterized in that it exhibits an ester group content of ≥ 1 and ≤ 7 mol/kg and a portion of aromatic structures of ≤ 50 wt.-% The invention also relates to the dielectric polyurethane film obtainable by this method. The invention further relates to a method for preparing an electrochemical transducer and an electrochemical transducer obtainable by said method.

    摘要翻译: 本发明涉及一种由混合物制备电介质聚氨酯膜的方法,包括:A)含有异氰酸酯基含量≥10重量%和≤50重量%异氰酸酯基的化合物和异氰酸酯基的数均官能度≥ 2.6和≤4,B)根据DIN 53240测定的OH-数量≥27且≤120mgKOH / g的聚酯多元醇,其特征在于其酯基含量≥1和≤7mol/ kg,一部分芳族结构≤50wt%本发明还涉及可通过该方法获得的电介质聚氨酯膜。 本发明还涉及一种用于制备电化学换能器和通过所述方法可获得的电化学换能器的方法。

    STABILISIERTE WEICHMACHER FÜR THERMOPLASTISCHES POLYURETHAN
    8.
    发明公开
    STABILISIERTE WEICHMACHER FÜR THERMOPLASTISCHES POLYURETHAN 审中-公开
    STABILISIERTE WEICHMACHERFÜR热塑性聚氨酯

    公开(公告)号:EP3099725A1

    公开(公告)日:2016-12-07

    申请号:EP15702660.0

    申请日:2015-01-21

    申请人: BASF SE

    摘要: The invention relates to a method for producing thermoplastic polyurethane, having the steps of providing a composition Z(W) containing at least one carbodiimide selected from the group consisting of monomer aliphatic carbodiimides, oligomer aliphatic carbodiimides, polymer aliphatic carbodiimides, monomer aromatic carbodiimides, oligomer aromatic carbodiimides, and polymer aromatic carbodiimides, and at least one ester selected from the group consisting of citric acid esters, acetyl citric acid esters, phthalic acid esters, benzoic acid esters, adipic acid esters, hydrogenated phthalic acid esters, and phosphoric acid esters; and subsequently adding the composition Z(W) to a thermoplastic polyurethane or to a reaction mixture in order to produce a thermoplastic polyurethane. The invention further relates to a thermoplastic polyurethane which can be obtained or is obtained using a method according to the invention and to the use of the composition Z(W) as a plasticizer for thermoplastic polyurethanes. The invention also relates to molded bodies containing a thermoplastic polyurethane according to the invention.

    摘要翻译: 本发明涉及一种生产热塑性聚氨酯的方法,其包括提供包含至少一种选自单体脂族碳二亚胺,低聚脂族碳二亚胺,聚合脂族碳二亚胺,单体芳香族碳二亚胺的碳二亚胺的组合物Z(W) 低聚芳族碳二亚胺和聚合芳族碳二亚胺,和至少一种选自柠檬酸酯,乙酰柠檬酸酯,邻苯二甲酸酯,苯甲酸酯,己二酸酯,氢化邻苯二甲酸酯和磷酸酯的酯; 以及随后将组合物Z(W)加入到热塑性聚氨酯或用于制备热塑性聚氨酯的反应混合物中。 此外,本发明涉及通过根据本发明的方法获得或获得的热塑性聚氨酯,以及组合物Z(W)作为热塑性聚氨酯的增塑剂的用途。 本发明还涉及包含根据本发明的热塑性聚氨酯的模制品。