公开(公告)号：EP1856019A1

公开(公告)日：2007-11-21

申请号：EP06735554.5

申请日：2006-02-21

申请人： EASTMAN CHEMICAL COMPANY

发明人： LAVOIE, Gino, Georges ,  HEMBRE, Robert, Thomas ,  SUMNER, Charles, Edwan, Jr. ,  BAYS, Joseph, Nathaniel ,  COMPTON, Daniel, Burts ,  TENNANT, Brent, Alan ,  DAVENPORT, Bryan, Wayne ,  LANGE, David ,  FLOYD, Thomas, Richard

IPC分类号： C07C51/265 ,  C07C63/16 ,  C07C63/24 ,  C07C63/26 ,  C07C63/15

CPC分类号： C07C51/265 ,  C07C63/26 ,  C07C63/15 ,  C07C63/16 ,  C07C63/24

摘要： Processes for producing aromatic dicarboxylic acids are disclosed, the processes including a step of combining in a reaction medium a dialkyl aromatic, a solvent comprising water and a saturated organic acid having from 2-4 carbon atoms, and an oxygen-containing gas, at a temperature from about 125°C to about 1550C, in the presence of a catalyst composition comprising cobalt, manganese, zirconium, and bromine, wherein the weight ratio of cobalt to manganese in the reaction mixture is fro about 10 to about 400. The processes provide improved conversion, while reducing the formation of carbon oxides and other by-products.

公开(公告)号：EP1784377A2

公开(公告)日：2007-05-16

申请号：EP05793517.3

申请日：2005-08-29

申请人： EASTMAN CHEMICAL COMPANY

发明人： WONDERS, Alan, George ,  LAVOIE, Gino, Georges ,  SUMNER, Charles, Edwan, Jr. ,  DAVENPORT, Bryan, Wayne

IPC分类号： C07C51/265

CPC分类号： C07C51/265 ,  C07C51/487 ,  C07C63/26

摘要： Disclosed is an optimized process for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

摘要翻译： 公开了用于更有效和经济地进行可氧化化合物的液相氧化的优化方法。 这种液相氧化在气泡塔反应器中进行，其在相对低的温度下提供高效反应。 当氧化的化合物是对二甲苯并且来自氧化反应的产物是粗对苯二甲酸（CTA）时，这种CTA产物可以通过比如果CTA由常规高温形成时可以采用的更经济的技术来纯化和分离 氧化过程。

公开(公告)号：EP1784377B1

公开(公告)日：2010-09-22

申请号：EP05793517.3

申请日：2005-08-29

申请人： EASTMAN CHEMICAL COMPANY

发明人： WONDERS, Alan, George ,  LAVOIE, Gino, Georges ,  SUMNER, Charles, Edwan, Jr. ,  DAVENPORT, Bryan, Wayne

IPC分类号： C07C51/265

CPC分类号： C07C51/265 ,  C07C51/487 ,  C07C63/26

摘要： Disclosed is an optimized process for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

公开(公告)号：EP1890991A1

公开(公告)日：2008-02-27

申请号：EP06771091.3

申请日：2006-05-24

申请人： EASTMAN CHEMICAL COMPANY

发明人： WONDERS, Alan, George ,  LAVOIE, Gino, Georges ,  SUMNER, Charles, Edwan, Jr. ,  DAVENPORT, Bryan, Wayne ,  DE VREEDE, Marcel ,  TENNANT, Brent, Alan

IPC分类号： C07C51/265

CPC分类号： C07C51/265 ,  C07C63/26

摘要： Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.