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    Method for the preparation of metallocene catalysts
    1.
    发明公开
    Method for the preparation of metallocene catalysts 有权
    茂金属催化剂的制备方法

    公开(公告)号：EP1234837A1

    公开(公告)日：2002-08-28

    申请号：EP02075520.3

    申请日：2002-02-11

    申请人： FINA TECHNOLOGY, INC.

    发明人： Gauthier, William J. ,  Lopez, Margarito ,  Rauscher, David J. ,  Campbell, Donald G., Jr. ,  Kerr, Margaret Elaine

    IPC分类号： C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08F4/65916 ,  C08F2500/16 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/15

    摘要： Process of preparing silica-supported catalysts. A support material comprising silica particles impregnated with an alumoxane co-catalyst with at least one-half of the co-catalyst disposed within the internal pore volume of the silica is contacted with a dispersion of a metallocene catalyst in an aromatic solvent. The dispersion and support are mixed at a temperature of about 10°C or less to enable the metallocene to become reactively supported on and impregnated within the alumoxane-impregnated silica particles. The supported catalyst is recovered from the aromatic solvent and washed with an aromatic hydrocarbon and then a paraffinic hydrocarbon at a temperature of about 10°C or less. The washed catalyst is dispersed in a viscous mineral oil.

    摘要翻译： 制备二氧化硅负载型催化剂的方法。 包含用铝氧烷助催化剂浸渍的二氧化硅颗粒与载体在二氧化硅的内孔体积内的至少一半助催化剂的载体材料与金属茂催化剂在芳族溶剂中的分散体接触。 分散体和载体在约10℃或更低的温度下混合以使茂金属能够反应性负载并浸渍在铝氧烷浸渍的二氧化硅颗粒内。 从芳香族溶剂中回收负载型催化剂，并在约10℃或更低的温度下用芳烃然后用链烷烃洗涤。 洗过的催化剂分散在粘稠的矿物油中。

    Method for the preparation of metallocene catalysts
    2.
    发明公开
    Method for the preparation of metallocene catalysts 有权
    Verfahren zur Herstellung von Metallocen-Katalysatoren

    公开(公告)号：EP1231225A1

    公开(公告)日：2002-08-14

    申请号：EP02075540.1

    申请日：2002-02-11

    申请人： FINA TECHNOLOGY, INC.

    发明人： Gauthier, William J. ,  Lopez, Margarito ,  Campbell, Donald G. Jr.

    IPC分类号： C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08F4/65916 ,  C08F2500/15 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/16

    摘要： A process for the preparation of a supported metallocene catalyst incorporating metallocene and co-catalysts components on a support. There is provided a particulate catalyst support material in which an alumoxane co-catalyst is incorporated onto the support particles and contacted with a dispersion of a metallocene catalyst in an aromatic hydrocarbon solvent. The metallocene solvent dispersion and the alumoxane-containing support are mixed at a temperature of about 10°C or less for a period sufficient to enable the metallocene to become reactively supported on the alumoxane support material. The supported catalyst is recovered from the aromatic solvent and then washed optionally with an aromatic hydrocarbon and then sequentially with a paraffinic hydrocarbon solvent at a temperaturc of about 10°C or less. The washed catalyst is dispersed in a viscous mineral oil having a viscosity which is substantially greater that the viscosity of the paraffinic hydrocarbon solvent.

    摘要翻译： 一种制备负载金属茂催化剂的方法，该催化剂在载体上加入金属茂和助催化剂组分。 提供了一种颗粒催化剂载体材料，其中铝氧烷助催化剂被引入载体颗粒上并与茂金属催化剂在芳族烃溶剂中的分散体接触。 金属茂溶剂分散体和含铝氧烷的载体在约10℃或更低的温度下混合足够的时间以使茂金属反应地负载在铝氧烷载体材料上。 负载的催化剂从芳族溶剂中回收，然后任选用芳族烃洗涤，然后依次用约10℃或更低温度的链烷烃溶剂洗涤。 经洗涤的催化剂分散在粘度矿物油中，其粘度基本上大于链烷烃溶剂的粘度。