Polynuclear polyhydric phenols and process for preparation thereof
    2.
    发明公开
    Polynuclear polyhydric phenols and process for preparation thereof 失效
    Polyhydroxylierte多核苷酸苯酚和ihr Herstellungsverfahren。

    公开(公告)号:EP0117759A1

    公开(公告)日:1984-09-05

    申请号:EP84301295.6

    申请日:1984-02-28

    CPC分类号: C07C39/15

    摘要: A polynuclear polyhydric phenol of the general formula (I);
    wherein R 1 and R 2 each represent a hydrogen atom or a C 1 -C 4 alkyl group, R 3 represents a hydrogen atom, an alkyl group, an aryl group or a halogen atom, and n is an integer of from 0 to 10, can be used to provide a polyepoxy compound which is a polyglycidyl ether of the polynuclear polyhydric ether. When the polyepoxy compound is combined with a curing agent, a curable epoxy resin composition results which can be used to provide molded cured articles having excellent heat resistance characteristics.

    摘要翻译: 通式(I)的多核多元酚; ... 其中R 1和R 2各自表示氢原子或C 1 -C 4烷基,R 3表示氢原子,烷基,芳基或卤素原子,以及 n为0〜10的整数,可用于提供作为多核多羟基醚的聚缩水甘油醚的聚环氧化合物。 当聚环氧化合物与固化剂组合时,得到可用于提供耐热特性优异的模制固化物的可固化环氧树脂组合物。

    High-molecular-weight novolak substituted phenolic resins and their preparation
    3.
    发明公开
    High-molecular-weight novolak substituted phenolic resins and their preparation 失效
    酚醛清漆 - 酚醛树脂。

    公开(公告)号:EP0032062A2

    公开(公告)日:1981-07-15

    申请号:EP80304746.3

    申请日:1980-12-29

    IPC分类号: C08G8/28 C08G8/04 C08G8/12

    摘要: Conventional novolak phenolic resins generally possess molecular weights of 1200 or less and exhibit unsatisfactory heat resistance and mechanical properties for all intended uses. Attempts to produce higher-molecular-weight resins have failed. These difficulties have been overcome and a high-molecular-weight novolak substituted phenolic resin having a number average molecular weight of at least 1500 is prepared by reacting (A) (i) a phenol component mainly comprising a bifunctional phenol or (ii) a low-molecular-weight novolak substituted phenolic resin derived from this phenol and an aldehyde, with (B) a chain extender selected from (i) dimethylolated products of bifunctional or trifunctional phenols, (ii) a low-molecular-weight resol substituted phenolic resin derived from a phenol component mainly comprising a bifunctional phenol and an aldehyde, (iii), an aldehyde, (iv) a ketone, (v) a diol and (vi) a dihalide in the presence of an acid catalyst, with the proviso that if the reactant (A) is the phenol component (i), the chain extender (B), is the resol substituted phenolic resin (ii). These high-molecular-weight novolak resins can be used in setting resin compositions with setting resins such as epoxy resins.

    摘要翻译: 常规的酚醛清漆酚醛树脂通常具有1200或更小的分子量,并且对于所有预期用途表现出不令人满意的耐热性和机械性能。 生产高分子量树脂的尝试失败了。 已经克服了这些困难,通过使(A)(i)主要包含双官能酚的酚成分或(ii)低分子量酚醛树脂 衍生自该酚和醛的分子量酚醛清漆取代的酚醛树脂,(B)增链剂,选自(i)双官能或三官能酚的二羟甲基化产物,(ii)低分子量甲阶酚醛树脂取代的酚醛树脂 由主要包含双官能酚和醛的酚组分,(iii)醛,(iv)酮,(ⅴ)二醇和(vi)二卤化物在酸催化剂存在下,条件是如果 反应物(A)是苯酚组分(i),扩链剂(B)是甲阶酚醛树脂取代的酚醛树脂(ii)。 这些高分子量酚醛清漆树脂可以用于固化树脂如环氧树脂的树脂组合物中。

    Novolak resin composition and products formed therefrom
    4.
    发明公开
    Novolak resin composition and products formed therefrom 失效
    Novolakharz enthaltende Zusammensetzung und daraus gebildeteGegenstände。

    公开(公告)号:EP0032060A2

    公开(公告)日:1981-07-15

    申请号:EP80304743.0

    申请日:1980-12-29

    摘要: Resin compositions containing a setting resin and a low-molecular-weight novolak resin do not possess satisfactory heat resistance and mechanical strength characteristics for all intended uses. These difficulties can be overcome by employing a resin composition comprising (A) a setting resin and (B) 10 to 200 parts by weight, per 100 parts by weight of said resin (A), of a substantially linear, high-molecular-weight novolak substituted phenolic resin which is derived from a phenol component mainly comprising at least one bifunctional phenol and which has a number average molecular weight of at least 1500.

    摘要翻译: 含有固化树脂和低分子量酚醛清漆树脂的树脂组合物对于所有预期用途不具有令人满意的耐热性和机械强度特性。 通过使用包含(A)固化树脂和(B)每100重量份所述树脂(A)10至200重量份的基本上线性,高分子量的树脂组合物可以克服这些困难 酚醛清漆取代的酚醛树脂,其衍生自主要包含至少一种双官能酚的酚成分,其数均分子量至少为1500。

    High-molecular-weight novolak substituted phenolic resins and their preparation
    8.
    发明公开
    High-molecular-weight novolak substituted phenolic resins and their preparation 失效
    高分子量NOVOLAK取代酚醛树脂及其制备

    公开(公告)号:EP0032062A3

    公开(公告)日:1981-12-23

    申请号:EP80304746

    申请日:1980-12-29

    IPC分类号: C08G08/28 C08G08/04 C08G08/12

    摘要: Conventional novolak phenolic resins generally possess molecular weights of 1200 or less and exhibit unsatisfactory heat resistance and mechanical properties for all intended uses. Attempts to produce higher-molecular-weight resins have failed. These difficulties have been overcome and a high-molecular-weight novolak substituted phenolic resin having a number average molecular weight of at least 1500 is prepared by reacting (A) (i) a phenol component mainly comprising a bifunctional phenol or (ii) a low-molecular-weight novolak substituted phenolic resin derived from this phenol and an aldehyde, with (B) a chain extender selected from (i) dimethylolated products of bifunctional or trifunctional phenols, (ii) a low-molecular-weight resol substituted phenolic resin derived from a phenol component mainly comprising a bifunctional phenol and an aldehyde, (iii), an aldehyde, (iv) a ketone, (v) a diol and (vi) a dihalide in the presence of an acid catalyst, with the proviso that if the reactant (A) is the phenol component (i), the chain extender (B), is the resol substituted phenolic resin (ii). These high-molecular-weight novolak resins can be used in setting resin compositions with setting resins such as epoxy resins.