High-molecular-weight novolak substituted phenolic resins and their preparation
    4.
    发明公开
    High-molecular-weight novolak substituted phenolic resins and their preparation 失效
    高分子量NOVOLAK取代酚醛树脂及其制备

    公开(公告)号:EP0032062A3

    公开(公告)日:1981-12-23

    申请号:EP80304746

    申请日:1980-12-29

    IPC分类号: C08G08/28 C08G08/04 C08G08/12

    摘要: Conventional novolak phenolic resins generally possess molecular weights of 1200 or less and exhibit unsatisfactory heat resistance and mechanical properties for all intended uses. Attempts to produce higher-molecular-weight resins have failed. These difficulties have been overcome and a high-molecular-weight novolak substituted phenolic resin having a number average molecular weight of at least 1500 is prepared by reacting (A) (i) a phenol component mainly comprising a bifunctional phenol or (ii) a low-molecular-weight novolak substituted phenolic resin derived from this phenol and an aldehyde, with (B) a chain extender selected from (i) dimethylolated products of bifunctional or trifunctional phenols, (ii) a low-molecular-weight resol substituted phenolic resin derived from a phenol component mainly comprising a bifunctional phenol and an aldehyde, (iii), an aldehyde, (iv) a ketone, (v) a diol and (vi) a dihalide in the presence of an acid catalyst, with the proviso that if the reactant (A) is the phenol component (i), the chain extender (B), is the resol substituted phenolic resin (ii). These high-molecular-weight novolak resins can be used in setting resin compositions with setting resins such as epoxy resins.