摘要:
The invention provides dam compositions which can give cured products serving as dam materials exhibiting appropriate hardness and adhesion with respect to adherends and which are preferably such that the dam materials also have inconspicuous joints with fillers. The invention also provides image displays manufactured with the compositions. An image display sealant dam composition includes (A) a polyorganosiloxane having a mercaptoalkyl group bonded to a silicon atom, and having a viscosity at 23°C of 20 to 25000 cP; (B) an aliphatic unsaturated group-containing polyorganosiloxane including an aliphatic unsaturated group-containing linear polyorganosiloxane (B1) represented by Formula (I) and optionally further including a branched polyorganosiloxane (B2) having SiO 4/2 units, R' 3 SiO 1/2 units and R' 2 SiO 2/2 units, and optionally further having R'SiO 3/2 units, at least three R' groups per molecule of the branched polyorganosiloxane (B2) are aliphatic unsaturated groups; (C) a photoreaction initiator; (D) an aliphatic unsaturated group-containing silane compound; and (E) a fumed silica having a BET specific surface area of 180 to 500 m 2 /g. In the composition, the ratio of the number of the mercaptoalkyl groups present in (A) to the total number of the aliphatic unsaturated groups in (B) and (D) is 0.45 to 1.50; the amount of (E) is 0.5 to 24 parts by weight per 100 parts by weight of (B); and the composition has a viscosity at 23°C of 20,000 to 10,000,000 cP. An image display includes an image display component and a protective component sealed with the composition.
摘要:
The invention provides dam compositions which can give cured products serving as dam materials exhibiting appropriate hardness and adhesion with respect to adherends and which are preferably such that the dam materials also have inconspicuous joints with fillers. The invention also provides image displays manufactured with the compositions. An image display sealant dam composition includes (A) a polyorganosiloxane having a mercaptoalkyl group bonded to a silicon atoms, and having a viscosity at 23°C of 20 to 25000 cP; (B) aliphatic unsaturated group-containing polyorganosiloxanes including an aliphatic unsaturated group-containing linear polyorganosiloxane (B1) represented by Formula (I), and a branched polyorganosiloxane (B2) having SiO 4/2 units, R' 3 SiO 1/2 units and R' 2 SiO 2/2 units, and optionally further having R'SiO 3/2 units, at least three R' groups per molecule of the branched polyorganosiloxane (B2) are aliphatic unsaturated groups (the proportion of the number of the aliphatic unsaturated groups in (B2) to the total number of the aliphatic unsaturated groups in (B) is more than 50% and not more than 95%); (C) a photoreaction initiator; (D) a silane compound; and (E) an MQ resin having a weight average molecular weight of 2,000 to 2,500,000 and/or an MDQ resin having a weight average molecular weight of 2,000 to 1,000,000. In the composition, the ratio of the number of the mercaptoalkyl groups in (A) to the number of the aliphatic unsaturated groups in (B) is 0.5 to 3.0; the amount of (E) is 30 to 200 parts by weight per 100 parts by weight of (B); and the composition has a viscosity at 23°C of 20,000 to 150,000 cP. An image display includes an image display component and a protective component sealed with the composition.
摘要:
The present invention relates to a resin composition for electric/electronic components, comprising: (A) a polyorganosiloxane that contains a mercaptoalkyl group bonded to a silicon atom and has a viscosity at 23°C of 20 to 3,000 cP; (B) a polyorganosiloxane containing an aliphatic unsaturated group wherein the polyorganosiloxane (B) includes: (B1) a linear polyorganosiloxane represented by the formula (I) and optionally (B2) a branched polyorganosiloxane including a SiO 4/2 unit, an R' 3 SiO 1/2 unit and an R' 2 SiO 2/2 unit, and optionally further an R'SiO 3/2 unit wherein at least three R' groups per molecule of the branched polyorganosiloxane (B2) are aliphatic unsaturated groups; (C) a photoreaction initiator; (D) a chemically surface-treated silica having a BET specific surface area of 50 to 250 m 2 /g and a pH of 5.0 to 9.0; and (E) a polyoxyalkylene glycol in which an alkylene unit is a linear or branched alkylene group having 2 to 4 carbon atoms, and/or a derivative of the polyoxyalkylene glycol, wherein the ratio of the number of mercaptoalkyl groups in (A) to the total number of aliphatic unsaturated groups in (B) is 0.45 to 2.00, the content of (D) is 0.5 to 26 parts by mass relative to 100 parts by mass of (B), the proportion of the content of (E) is 0.001 to 1.0 mass% relative to the total mass of (A) to (E), and the viscosity at 23°C is 500 to 100,000 cP.
摘要:
The invention provides dam compositions which can give cured products serving as dam materials exhibiting appropriate hardness and adhesion with respect to adherends and which are preferably such that the dam materials also have inconspicuous joints with fillers. The invention also provides image displays manufactured with the compositions. An image display sealant dam composition includes (A) a polyorganosiloxane having a mercaptoalkyl group bonded to a silicon atom, and having a viscosity at 23°C of 20 to 25000 cP; (B) an aliphatic unsaturated group-containing polyorganosiloxane including an aliphatic unsaturated group-containing linear polyorganosiloxane (B1) represented by Formula (I) and optionally further including a branched polyorganosiloxane (B2) having SiO 4/2 units, R' 3 SiO 1/2 units and R' 2 SiO 2/2 units, and optionally further having R'SiO 3/2 units, at least three R' groups per molecule of the branched polyorganosiloxane (B2) are aliphatic unsaturated groups; (C) a photoreaction initiator; (D) an aliphatic unsaturated group-containing silane compound; and (E) a fumed silica having a BET specific surface area of 180 to 500 m 2 /g. In the composition, the ratio of the number of the mercaptoalkyl groups present in (A) to the total number of the aliphatic unsaturated groups in (B) and (D) is 0.45 to 1.50; the amount of (E) is 0.5 to 24 parts by weight per 100 parts by weight of (B); and the composition has a viscosity at 23°C of 20,000 to 10,000,000 cP. An image display includes an image display component and a protective component sealed with the composition.
摘要:
This is to provide a heat-curable polyorganosiloxane composition. The heat-curable polyorganosiloxane composition comprises (A) an alkenyl group-containing linear polyorganosiloxane represented by the formula (I); (B1) a linear polyorganohydrogensiloxane represented by the formula (II); (B2) a cyclic polyorganohydrogensiloxane comprising an R e 2 HSiO 1/2 unit (wherein R e represents a hydrogen atom or C 1 -C 6 alkyl group) and an SiO 4/2 unit, and having three or more hydrogen atoms bonded to a silicon atom in one molecule; (C) a platinum series catalyst; and (D) an adhesion promoter, a ratio of a sum (H B1 +H B2 ) of a number H B1 of the hydrogen atom(s) of (B1) and a number H B2 of the hydrogen atom(s) of (B2) based on a number Vi A of the alkenyl group(s) of (A) is 0.2 to 1.0, and H B1 is 0.5 to 0.8 based on H B1 +H B2 .
摘要:
This is to provide a heat-curable polyorganosiloxane composition. The heat-curable polyorganosiloxane composition comprises (A) an alkenyl group-containing linear polyorganosiloxane represented by the formula (I); (B1) a linear polyorganohydrogensiloxane represented by the formula (II); (B2) a cyclic polyorganohydrogensiloxane comprising an R e 2 HSiO 1/2 unit (wherein R e represents a hydrogen atom or C 1 -C 6 alkyl group) and an SiO 4/2 unit, and having three or more hydrogen atoms bonded to a silicon atom in one molecule; (C) a platinum series catalyst; and (D) an adhesion promoter, a ratio of a sum (H B1 +H B2 ) of a number H B1 of the hydrogen atom(s) of (B1) and a number H B2 of the hydrogen atom(s) of (B2) based on a number Vi A of the alkenyl group(s) of (A) is 0.2 to 1.0, and H B1 is 0.5 to 0.8 based on H B1 +H B2 .
摘要:
Disclosed is a room temperature curable silicon group-containing polymer composition containing a reactive silicon group-containingpolymer (A) having agrouprepresentedby the formula (I) at an end of the main chain, which is obtained through a reaction between a polyoxypropylene polyol and a γ-isocyanate propyltrialkoxysilane, a curing catalyst (B), an amino-functional organosiloxane (C), and optionally an inorganic filler (D) which is surface-treated with glycol. Also disclosed is a room temperature curable silicon group-containing polymer composition which contains, as the reactive silicon group-containing polymer (A), a mixture of a polymer (Al) having a reactive silicon-containig group at two or more ends, which is obtained through a reaction between a polyoxypropylene polyol and a γ-isocyanate propyltrialkoxysilane, and another polymer (A2) having a reactive silicon containing-group only at one end, which is obtained through a reaction between a hydroxypolyoxypropylene having a hydroxyl group at one end and a γ-isocyanate propyltrialkoxysilane, a curing catalyst (B) and an amino group-substituted alkoxysilane (Cl) or an amino-functional organosiloxane(C2).