PROCESS FOR PREPARING 2,3,3,3-TETRAFLUOROPROPENE
    5.
    发明公开
    PROCESS FOR PREPARING 2,3,3,3-TETRAFLUOROPROPENE 有权
    制备2,3,3,3-四氟丙烯的方法

    公开(公告)号:EP2318339A1

    公开(公告)日:2011-05-11

    申请号:EP09788010.8

    申请日:2009-07-24

    IPC分类号: C07C17/20 C07C17/25 C07C21/18

    摘要: The present invention provides a process for producing 2,3,3,3-tetrafluoropropene represented by the formula CF
    3 CF=CH
    2 , comprising contacting a fluorine-containing propane represented by the formula CF
    2 XCFYCH
    2 Z, wherein X is Cl, Br, or I; one of Y and Z is H, and the other is F, Cl, Br, or I, with at least one catalyst selected from the group consisting of chromium oxides, fluorinated chromium oxides, and iron fluorides in a gas phase. According to the process of the invention, 2,3,3,3-tetrafluoropropene can be easily produced under economically advantageous conditions.

    摘要翻译: 本发明提供了一种生产由式CF 3 CF = CH 2表示的2,3,3,3-四氟丙烯的方法,该方法包括使由式CF 2 XCFYCH 2 Z表示的含氟丙烷,其中X是Cl,Br或 一世; Y和Z中的一个是H,另一个是F,Cl,Br或I,其中至少一种催化剂选自气相中的氧化铬,氟化氧化铬和氟化铁。 根据本发明的方法,在经济有利的条件下可容易地生产2,3,3,3-四氟丙烯。

    PROCESS FOR PREPARING 2,3,3,3-TETRAFLUOROPROPENE
    9.
    发明公开
    PROCESS FOR PREPARING 2,3,3,3-TETRAFLUOROPROPENE 审中-公开
    制备2,3,3,3-四氟丙烯的方法

    公开(公告)号:EP2349958A2

    公开(公告)日:2011-08-03

    申请号:EP09741475.9

    申请日:2009-10-13

    摘要: The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene comprising the steps of: (a) reacting 3,3,3-trifluoropropyne with hydrogen fluoride while heating to obtain a product containing 2,3,3,3-tetrafluoropropene; (b) separating the product obtained in Step (a) into Component A containing 2,3,3,3-tetrafluoropropene and 3,3,3-trifluoropropyne, and Component B containing 1,3,3,3-tetrafluoropropene; (c) separating 2,3,3,3-tetrafluoropropene and 3,3,3-trifluoropropyne contained in Component A obtained in Step (b) into each compound; (d) conducting a dehydrofluorination reaction by heating Component B obtained in Step (b) in the presence of a catalyst; (e) separating the product obtained in Step (d) into Component C containing 2,3,3,3-tetrafluoropropene and 3,3,3-trifluoropropyne, and Component D containing 1,3,3,3-tetrafluoropropene; (f) separating 2,3,3,3-tetrafluoropropene and 3,3,3-trifluoropropyne contained in Component C obtained in Step (e) into each compound; and (g) conducting a dehydrofluorination reaction by heating Component D obtained in Step (e) in the presence of a catalyst. The present invention provides an effective and industrially applicable process for preparing 2,3,3,3-tetrafluoropropene.

    摘要翻译: 本发明提供了制备2,3,3,3-四氟丙烯的方法,该方法包括以下步骤:(a)在加热下使3,3,3-三氟丙炔与氟化氢反应,得到含2,3,3,3-三氟丙烯 -tetrafluoropropene; (b)将步骤(a)中得到的产物分离成含有2,3,3,3-四氟丙烯和3,3,3-三氟丙炔的组分A和含有1,3,3,3-四氟丙烯的组分B; (c)将步骤(b)中得到的组分A中所含的2,3,3,3-四氟丙烯和3,3,3-三氟丙炔分离成每种化合物; (d)通过在催化剂存在下加热步骤(b)中获得的组分B进行脱氟化氢反应; (e)将步骤(d)中得到的产物分离成含有2,3,3,3-四氟丙烯和3,3,3-三氟丙炔的组分C和含有1,3,3,3-四氟丙烯的组分D; (f)将步骤(e)中获得的组分C中所含的2,3,3,3-四氟丙烯和3,3,3-三氟丙炔分离成每种化合物; 和(g)通过在催化剂存在下加热步骤(e)中获得的组分D来进行脱氟化氢反应。 本发明提供了一种有效的和工业上可用的制备2,3,3,3-四氟丙烯的方法。