摘要:
The present invention relates to Li-Ni-based composite oxide particles comprising Mn, and Co and/or Al, wherein Co and Al are uniformly dispersed within the particles, and Mn is present with a gradient of its concentration in a radial direction of the respective particles such that a concentration of Mn on a surface of the respective particles is higher than that at a central portion thereof. The Li-Ni-based composite oxide particles can be produced by allowing an oxide and a hydroxide comprising Mn to mechanically adhere to Li-Ni-based oxide comprising Co and/or Al; and then heat-treating the obtained material at a temperature of not lower than 400°C and not higher than 1,000°C. The Li-Ni-based composite oxide particles of the present invention are improved in thermal stability and alkalinity.
摘要:
The present invention relates to positive electrode active substance particles comprising a compound having at least a crystal system belonging to a space group of R-3m and a crystal system belonging to a space group of C2/m, and boron, wherein the compound is a composite oxide comprising at least Li, Mn, and Co and/or Ni; a relative intensity ratio [(a)/(b)] of a maximum diffraction peak intensity (a) observed at 2θ = 20.8±1° in a powder X-ray diffraction pattern of the positive electrode active substance as measured using a Cu-Kα ray to a maximum diffraction peak intensity (b) observed at 28 = 18.6±1° in the powder X-ray diffraction pattern, is 0.02 to 0.5; a content of Mn in the positive electrode active substance particles is controlled such that a molar ratio of Mn/(Ni + Co + Mn) therein is not less than 0.55; and the positive electrode active substance particles comprise the boron in an amount of 0.001 to 3% by weight. The positive electrode active substance particles of the present invention are produced by calcining a mixture comprising precursor particles comprising Mn, and Ni and/or Co, a lithium compound and a boron compound at a temperature of 500 to 1500°C. The positive electrode active substance particles of the present invention can provide a secondary battery which can be improved in charge/discharge capacity and cycle characteristics.
摘要:
The present invention relates to Li-Ni composite oxide particles for a non-aqueous electrolyte secondary cell which have a large charge/discharge capacity, an excellent packing density and excellent storage performance. The Li-Ni composite oxide particles for a non-aqueous electrolyte secondary cell which have a composition represented by the formula:
Li x Ni 1-y-z Co y Al z O 2
in which 0.9 2 thereto, and a sulfate ion content of not more than 1.0%, can be produced by mixing Ni-Co hydroxide particles having a sulfate ion content of not more than 1.0% whose surface is coated with an Al compound having a primary particle diameter of not more than 1 µm, with a lithium compound; and calcining the resulting mixture.
摘要:
The present invention relates to Li-Ni composite oxide particles that exhibit a high initial discharge capacity and are excellent in thermal stability when used as a positive electrode active substance for non-aqueous electrolyte secondary batteries, and a process for producing the Li-Ni composite oxide particles. The Li-Ni composite oxide particles of the present invention have a composition of Li x Ni 1-y-a-b Co y M1 a M2 b O 2 wherein x, y, a and b represent 1.00 ≤ x ≤ 1.10; 0
摘要:
The present invention provides lithium composite compound particles having good high-temperature storage property and excellent cycle characteristics as an active substance for a non-aqueous electrolyte secondary battery, and a secondary battery using the lithium composite compound particles. The Li-Ni composite oxide particles for a non-aqueous electrolyte secondary battery according to the present invention have a BET specific surface area of 0.05 to 0.8 m 2 /g; an atomic ratio (Ma/Ni) of a concentration of an amphoteric metal to a concentration of Ni on an outermost surface of the respective Li-Ni composite oxide particles is 2 to 6; and the concentration of the amphoteric metal on the outermost surface of the respective Li-Ni composite oxide particles is higher than a concentration of the amphoteric metal at a position spaced by 50 nm from the outermost surface toward a center of the respective Li-Ni composite oxide particles.
摘要:
The present invention relates to lithium composite compound particles having a composition represented by the formula: Li 1+x Ni 1-y-z Co y M z O 2 (M = B or Al), wherein the lithium composite compound particles have an ionic strength ratio A (LiO - /NiO 2 - ) of not more than 0.3 and an ionic strength ratio B (Li 3 CO 3 + /Ni + ) of not more than 20 as measured on a surface of the respective lithium composite compound particles using a time-of-flight secondary ion mass spectrometer. The lithium composite compound particles of the present invention can be used as a positive electrode active substance of a secondary battery which has good cycle characteristics and an excellent high-temperature storage property.
摘要翻译:本发明涉及的锂具有由下式表示的组合物的复合化合物颗粒:栗1 + X的Ni 1-YZ CO Y MžO 2(M = B或Al),worin的锂复合化合物颗粒具有离子强度比 A(LIO - /的NiO 2 - )不大于0.3,并在离子强度比B(栗3 CO 3 + /镍+)的不超过20作为使用时间测量的respectivement锂复合化合物颗粒的表面上 -of-飞行二次离子质谱仪。 本发明的锂复合化合物颗粒可以用作具有良好的循环特性和优异的高温保存特性的二次电池的正极活性物质。
摘要:
The present invention relates to Li-Ni composite oxide particles for a non-aqueous electrolyte secondary battery which have a large charge/discharge capacity and are excellent in thermal stability under a charged condition. The above object can be achieved by the Li-Ni composite oxide particles for a non-aqueous electrolyte secondary battery, comprising a Li-Ni composite oxide whose secondary particles form core particles thereof and have a composition represented by the formula: Li x1 Ni 1-y1-z1-w1 Co y1 Mn z1 M w1 O 2 (in which 0.9 ≤ x1 ≤ 1.3; 0.1 ≤ y1 ≤ 0.3; 0.0 ≤ z1 ≤ 0.3; 0 ≤ w1 s 0.1; and M is at least one metal selected from the group consisting of Al and Fe), wherein a Li-Ni composite oxide having a composition represented by the formula: Li x2 Ni 1-y2-z2-w2 Co y2 Mn z2 M w2 O 2 (in which 0.9 ≤ x2 ≤ 1 + z2; 0 ≤ y2 ≤ 0.33; 0 ≤ z2 ≤ 0.5; 0 ≤ w2 ≤ 0.1; and M is at least one metal selected from the group consisting of Al, Fe, Mg, Zr and Ti, is coated or present on a surface of the respective secondary particles.