摘要:
The present invention relates to lithium manganate particles having a primary particle diameter of 1 to 8 µm and forming substantially single-phase particles, which have a composition represented by the following chemical formula:
Li 1+x Mn 2-x-y Y1 y O 4 + Y2
in which Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is P and is present in an amount of 0.01 to 0.6 mol% based on Mn; and x and y satisfy 0.03 ≤ x ≤ 0.15 and 0.05 ≤ y ≤ 0.20, respectively, and which lithium manganate particles have a specific surface area of the lithium manganate particles of 0.3 to 0.9 m 2 /g (as measured by BET method); and have an average particle diameter (D 50 ) of the lithium manganate particles of 3 to 10 µm. A positive electrode active substance of a lithium ion secondary battery using the lithium manganate particles of the present invention has a high output and is excellent in high-temperature stability.
摘要翻译:本发明涉及的锂具有1至8微米的初级粒子直径和基本上形成单相颗粒,其具有由下述化学式表示的组成锰颗粒:€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ ƒ€ƒLi1 + X 2的Mn-XY Y1 Y 2 O 4 + Y2其中Y 1是选自镍,钴,镁,铁,铝,Cr,Ti中选择的至少一种元素; Y2为P,是存在于基于锰0.6%(摩尔)的0点01分量; 并且x和y满足12:03‰¤X‰¤12:15和00:05‰¤ý‰¤12:20,分别与哪个锰酸锂颗粒具有0.3的锰酸锂颗粒的至0.9米2 /克的比表面积(通过如测量 BET法); 并且对的3至10微米的锰酸锂颗粒的平均粒径(D50)。 使用本发明的锰酸锂颗粒的锂离子二次电池的正极活性物质具有高输出且具有优异的高温稳定性。
摘要:
The present invention relates to positive electrode active substance particles comprising a compound having a spinel type structure comprising at least Li, Ni and Mn, and having an Li content which is controlled such that a molar ratio of Li(Ni + Mn) therein is 0.3 to 0.65, an Ni content of 5 to 25% by weight, an Na content of 0.05 to 1.9% by weight and an S content of 0.0005 to 0.16% by weight, a sum of the Na content and the S content being 0.09 to 1.9005% by weight. The positive electrode active substance particles according to the present invention can be suitably used as positive electrode active substance particles for non-aqueous electrolyte secondary batteries which can exhibit a high discharge voltage and an excellent discharge capacity.
摘要:
The present invention relates to Li-Ni composite oxide particles that exhibit a high initial discharge capacity and are excellent in thermal stability when used as a positive electrode active substance for non-aqueous electrolyte secondary batteries, and a process for producing the Li-Ni composite oxide particles. The Li-Ni composite oxide particles of the present invention have a composition of Li x Ni 1-y-a-b Co y M1 a M2 b O 2 wherein x, y, a and b represent 1.00 ≤ x ≤ 1.10; 0
摘要:
The present invention aims to provide lithium composite compound particles which can exhibit good cycle characteristics and an excellent high-temperature storage property when used as a positive electrode active substance of a secondary battery, and a secondary battery using the lithium composite compound particles. The present invention relates to lithium composite compound particles having a composition represented by the compositional formula: Li 1+x Ni 1-y-z-a Co y Mn z M a O 2 , in which the lithium composite compound particles have an ionic strength ratio A (LiO - /NiO 2 - ) of not more than 0.5 and an ionic strength ratio B (Li 3 CO 3 + /Ni + ) of not more than 20 as measured on a surface of the respective lithium composite compound particles using a time-of-flight secondary ion mass spectrometer.
摘要:
The present invention provides lithium manganate which has a high output and is excellent in high-temperature stability. The present invention relates to lithium manganate particles which are produced by mixing a lithium compound, a manganese compound, a Y compound and an A compound with each other and then calcining the resulting mixture, and have a composition represented by the following chemical formula 1 and an average secondary particle diameter (D 50 ) of 1 to 15 µm,
(Chemical Formula) Li 1+x Mn 2-x-y Y y O 4 + zA
in which Y is at least one element selected from the group consisting of Al and Mg; A is a sintering aid element having a melting point of not higher than 850°C; x and y satisfy 0.03 ≤ x s 0.15 and 0 ≤ y ≤ 0.20, respectively; z is in the range of 0 to 2.5 mol% based on Mn, wherein the lithium manganate particles have a sulfur content of not more than 100 ppm.
摘要:
The present invention relates to lithium manganate particles having a primary particle diameter of not less than 1 µm and an average particle diameter (D 50 ) of not less than 2 µm and not more than 10 µm as measured by a particle size distribution meter, and forming particles having substantially a single phase, which have a composition represented by the following chemical formula: Li 1 + x Mn 2 - x - y Y 1 y O 4 + Y 2 where Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is at least one element constituting a sintering aid having a melting point of not higher than 800°C, x and y satisfy 0.03 ≤ x ≤ 0.15 and 0.05 ≤ y ≤ 0.20, respectively, and Y2 is present in an amount of 0.1 to 2.5 mol% based on Mn; the Y1 element being dispersed within the respective particles, and an X-ray diffraction intensity ratio of I(400)/I(111) of the particles being not less than 38% and an X-ray diffraction intensity ratio of I(440)/I(111) thereof being not less than 18%. The lithium manganate particles of the present invention have a high output and are excellent in high-temperature stability.
摘要:
The present invention aims at providing lithium manganate having a high output and an excellent high-temperature stability. The above aim can be achieved by lithium manganate particles having a primary particle diameter of not less than 1 µm and an average particle diameter (D 50 ) of kinetic particles of not less than 1 µm and not more than 10 µm, which are substantially in the form of single crystal particles and have a composition represented by the following chemical formula: Li 1+x Mn 2-x-y Y y O 4 in which Y is at least one element selected from the group consisting of Al, Mg and Co; x and y satisfy 0.03 ≤ x ≤ 0.15 and 0.05 ≤ y ≤ 0.20, respectively, wherein the Y element is uniformly dispersed within the respective particles, and an intensity ratio of I(400)/I(111) thereof is not less than 33% and an intensity ratio of I(440)/I(111) thereof is not less than 16%.
摘要:
The present invention provides lithium manganate which has a high output and is excellent in high-temperature stability. The present invention relates to lithium manganate particles which are produced by mixing a lithium compound, a manganese compound, a Y compound and an A compound with each other and then calcining the resulting mixture, and have a composition represented by the following chemical formula 1 and an average secondary particle diameter (D 50 ) of 1 to 15 µm, €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(Chemical Formula)€ƒ€ƒ€ƒ€ƒ€ƒLi 1+x Mn 2-x-y Y y O 4 + zA in which Y is at least one element selected from the group consisting of Al and Mg; A is a sintering aid element having a melting point of not higher than 850°C; x and y satisfy 0.03 ‰¤ x s 0.15 and 0 ‰¤ y ‰¤ 0.20, respectively; z is in the range of 0 to 2.5 mol% based on Mn, wherein the lithium manganate particles have a sulfur content of not more than 100 ppm.
摘要:
The present invention relates to positive electrode active substance particles comprising a compound having at least a crystal system belonging to a space group of R-3m and a crystal system belonging to a space group of C2/m, and boron, wherein the compound is a composite oxide comprising at least Li, Mn, and Co and/or Ni; a relative intensity ratio [(a)/(b)] of a maximum diffraction peak intensity (a) observed at 2θ = 20.8±1° in a powder X-ray diffraction pattern of the positive electrode active substance as measured using a Cu-Kα ray to a maximum diffraction peak intensity (b) observed at 28 = 18.6±1° in the powder X-ray diffraction pattern, is 0.02 to 0.5; a content of Mn in the positive electrode active substance particles is controlled such that a molar ratio of Mn/(Ni + Co + Mn) therein is not less than 0.55; and the positive electrode active substance particles comprise the boron in an amount of 0.001 to 3% by weight. The positive electrode active substance particles of the present invention are produced by calcining a mixture comprising precursor particles comprising Mn, and Ni and/or Co, a lithium compound and a boron compound at a temperature of 500 to 1500°C. The positive electrode active substance particles of the present invention can provide a secondary battery which can be improved in charge/discharge capacity and cycle characteristics.