摘要:
The present invention relates to a method and apparatus for steam purging a solid oxide fuel cell stack. Purging the SOFC stack with steam has a physical flushing effect, removing carbon monoxide containing reformate and free oxygen gas from the anode area thereby reducing the potential for nickel oxide or nickel carbonyl formation.
摘要:
A solid oxide fuel cell stack includes a fuel cell unit consisting of a fuel cell framed by a cell holder plate and upper and lower cushioning elements. The fuel cell unit is stacked with flow field seals and solid flow separator plates. The fuel cell thus floats without direct contact with rigid stack elements.
摘要:
A solid state ionic device includes a dense electrolyte sandwiched between two porous electrodes. In one embodiment, the device is anode supported and the cathode is formed of a porous three-dimensional solid phase structure having an electrocatalytic phase of a plurality of electrocatalytic particles (14) and an ionic conducting phase of a plurality of ionic conductor particles (16). The mean or median size of the electrocatalytic particles is larger than the mean or median size of the ionic conductor particles. The device may further include a long range electronic conducting layer of lantham cobaltate or other electronically conducting material.
摘要:
A thermally integrated fuel cell system includes a stack zone, a burner zone and a low temperature zone. The fuel is combined with steam and passed sequentially through a primary reformer and a secondary reformer or a radiative fuel heat exchanger. Air may be passed sequentially or in parallel through an afterburner heat exchanger and a radiative air heat exchanger. The stack exhaust is combusted in an afterburner. Afterburner exhaust heats the primary reformer, the high temperature air heat exchanger, the low temperature air heat exchanger and steam generator. The stack zone includes the stacks, the secondary reformer, the radiative heat exchanger and the equalization heat exchanger. The burner zone includes the afterburner, the primary reformer and the high temperature air heat exchanger. The low temperature zone includes the low temperature air heat exchanger and a steam generator.
摘要:
A flexible seal for use in a solid oxide fuel cell stack is formed from a fiber matrix with a plurality of solid particles through tape casting method. The fibers and particles are preferably ceramic and may be formed from alumina or zirconia. The seal may be formed by forming a slurry of fibers, particles, a binder and a non-aqueous solvent, tape casting the slurry, drying the tape seal, die-cutting, prior to installation in the fuel cell stack.
摘要:
In embodiments, a fuel cell stack is provided that includes an interconnect between a first fuel cell and a second fuel cell, and a contact layer in contact with, and disposed between, an electrode of the first fuel cell and the interconnect. The contact layer may include a chromium-getter material. This chromium-getter material may consist of lanthanum oxide, lanthanum carbonate, and/or calcium carbonate.
摘要:
In some embodiments, a solid oxide fuel system is provided. The solid oxide fuel cell system may include a chromium-getter material. The chromium-getter material may react with chromium to remove chromium species from chromium vapor. The solid oxide fuel cell system may also include an inert substrate. The chromium-getter material may be coated onto the inert substrate. The coated substrate may remove chromium species from chromium vapor before the chromium species can react with a cathode in the solid oxide fuel cell system.
摘要:
A high temperature, redox tolerant fuel cell anode electrode and method of fabrication in which the anode electrode is pre-conditioned by application of an initial controlled redox cycle to the electrode whereby an initial re-oxidation of the anode electrode is carried out at temperatures less than or equal to about 650° C.