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    Alkylation process using an alkyl halide promoted pyridinium ionic liquid catalyst
    2.
    发明授权
    Alkylation process using an alkyl halide promoted pyridinium ionic liquid catalyst 有权
    使用烷基卤促进的吡啶鎓离子液体催化剂的烷基化方法

    公开(公告)号：EP2597078B1

    公开(公告)日：2017-12-13

    申请号：EP13156447.8

    申请日：2007-03-20

    申请人： Chevron U.S.A. Inc.

    发明人： Elomari, Saleh

    IPC分类号： C07C2/60 ,  C07C2/62 ,  C10G29/20

    CPC分类号： C07C2/62 ,  C07C2/60 ,  C07C2527/11 ,  C07C2531/02 ,  C10G29/205

    摘要： Disclosed is an alkylation process. The process comprises contacting a hydrocarbon mixture comprising at least one olefin having from 2 to 6 carbon atoms and at least one isoparaffin having from 3 to 6 carbon atoms under alkylation conditions in the presence of an acidic ionic liquid catalyst. The catalyst comprising a mixture of at least one acidic ionic liquid and at least one alkyl halide. The acidic ionic liquid is a chloroaluminate ionic liquid prepared by mixing aluminum trichloride (AlCl 3 ) and a hydrocarbyl substituted pyridinium halide having the general formula A: where R = H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a chloroaluminate; and wherein the isoparaffin and the olefin are alkylated.

    HF ALKYLATION PROCESS
    3.
    发明公开
    HF ALKYLATION PROCESS 审中-公开
    HF-ALKYLIERUNGSVERFAHREN

    公开(公告)号：EP3083902A1

    公开(公告)日：2016-10-26

    申请号：EP14824972.5

    申请日：2014-12-03

    申请人： ExxonMobil Research and Engineering Company

    发明人： SPRY, David B. ,  FITT, Jeffrey M.

    IPC分类号： C10G29/20 ,  G01N9/36 ,  C07C2/62

    CPC分类号： G01N27/06 ,  B01J19/24 ,  B01J2219/24 ,  C07C2/62 ,  C07C2527/1206 ,  C10G29/205 ,  G01N9/36 ,  G01N25/00 ,  C07C9/16

    摘要： An HF olefin/isoparaffin alkylation process is carried out in an alkylation unit with a settling vessel in which the alkylate product is separated from the HF acid catalyst containing water and acid soluble oil (ASO). The density of the liquids in the settling vessel is measured at different levels by means of a nuclear density profile analyzer. The acid strength of the acid phase is determined from the density measurement and an optional temperature measurement. The proportion of water in the acid phase may also be measured separately by measurement of its electrical conductivity to determine the respective contributions of the water and the ASO to the density of the HF acid phase.

    摘要翻译： 在具有沉淀容器的烷基化单元中进行HF烯烃/异构烷烃烷基化方法，其中烷基化物产物与含有水和酸溶性油（ASO）的HF酸催化剂分离。 沉降容器中液体的密度通过核密度分布分析仪在不同水平上进行测量。 酸相的酸强度由密度测量和可选的温度测量确定。 酸相中水的比例也可以通过测量其电导率来分别测量，以确定水和ASO对HF酸相的密度的各自贡献。

    ALKYLATION PROCESS USING AN ALKYL HALIDE PROMOTED IONIC LIQUID CATALYST
    4.
    发明公开
    ALKYLATION PROCESS USING AN ALKYL HALIDE PROMOTED IONIC LIQUID CATALYST 有权
    烷基化过程中烷基卤开采离子液体的催化剂

    公开(公告)号：EP2016035A4

    公开(公告)日：2011-11-16

    申请号：EP07758932

    申请日：2007-03-20

    申请人： CHEVRON USA INC

    发明人： ELOMARI SALEH

    IPC分类号： C07C2/60 ,  C07C2/62 ,  C10G29/20

    CPC分类号： C07C2/62 ,  C07C2/60 ,  C07C2527/11 ,  C07C2531/02 ,  C10G29/205

    摘要： Disclosed is an alkylation process. The process comprises contacting a hydrocarbon mixture comprising at least one olefin having from 2 to 6 carbon atoms and at least one isoparaffin having from 3 to 6 carbon atoms under alkylation conditions in the presence of an acidic ionic liquid catalyst. The catalyst comprising a mixture of at least one acidic ionic liquid and at least one alkyl halide. The acidic ionic liquid is a chloroaluminate ionic liquid prepared by mixing aluminum trichloride (AlCl 3 ) and a hydrocarbyl substituted pyridinium halide having the general formula A: where R = H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a chloroaluminate; and wherein the isoparaffin and the olefin are alkylated.

    METHOD FOR REDUCING ORGANIC FLUORIDE LEVELS IN HYDROCARBONS
    6.
    发明公开
    METHOD FOR REDUCING ORGANIC FLUORIDE LEVELS IN HYDROCARBONS 审中-公开
    一种用于减少有机氟化物GEAHLTS碳氢化合物

    公开(公告)号：EP1177038A4

    公开(公告)日：2007-02-21

    申请号：EP00908360

    申请日：2000-01-24

    申请人： CONOCOPHILLIPS CO

    发明人： RANDOLPH BRUCE B ,  HOOVER KENNETH CHARLES

    IPC分类号： C10G35/06 ,  C07C2/62 ,  C07C7/148 ,  C10G29/20 ,  C10G59/02 ,  B01J8/00 ,  B01J8/04 ,  B01J10/00 ,  C07C2/56 ,  C07C7/00 ,  C07C7/10 ,  C07C7/17 ,  C10G17/00

    CPC分类号： C10G29/205 ,  C07C2/62 ,  C07C7/148

    摘要： A system and/or process for decreasing the level of at least one organic fluoride present in a hydrocarbon mixture (118) by first passing the hydrocarbon mixture (118) to an eductor (120) and educting into the hydrocarbon mixture a catalyst (122) comprising a volatility reducing additive and hydrofluoric acid to produce a hydrocarbon-catalyst mixture (132), permitting the hydrocarbon-catalyst mixture (132) to undergo a phase separation to produce a hydrocarbon phase (128) having a lower concentration of at least one organic fluoride than the hydrocarbon mixture (132) and to produce a catalyst phase (130), and withdrawing at least a portion of the hydrocarbon phase to thereby form a hydrocarbon product stream (134), are disclosed. In an alternate embodiment, a system and/or process for controlling the concentration of at least one organic fluoride and/or the RON of the hydrocarbon mixture by adjusting the amount of the volatility reducing additive present in the catalyst are disclosed.