摘要:
A fluoroalkylated allylurethane represented by the following general formula:
RfROCONHR'NHCOOC n H 2n OCH 2 CH=CH 2
where Rf is a perfluoroalkyl group having 2 to 20 carbon atoms, R is a divalent organic group, R' is a diisocyanate residue, and n is an integer of 2 to 6, can undergo emulsion polymerization with at least one of a methacrylate ester, an acrylate ester and vinylidene chloride to give an effective aqueous copolymer emulsion for a water- and oil-repellent, anti-soiling processing agent.
摘要:
Methanol extract of Maytenus ilicifolia , powder obtained as an aqueous layer component and oily substance obtained a chloroform layer component by intersolvent distribution of a methanol extract between chloroform and water, chromatographic eluate fractions by polystyrene-based resin of the powder obtained as the aqueous layer component, n-hexane insoluble substance obtained from the oily substance as the chloroform layer component, and friedelan-3-β-ol contained therein have a distinguished anti-ulcerative effect on gastric mucosa lesions caused by ethanol.
摘要:
A novel acrylic copolymer elastomer comprising [ ] an alkyl acrylate; [ ] (a) CH 2 =CRCOOR 2 OCOR 1 , (b) CH 2 =CRCO[O(CH 2 ) pCO]qOR 1 or (c) CH 2 =CRCOOR 2 O[CO(CH 2 )pO]qCOR 1 ; and [ ] (1) CH 2 = CRCOO(CH 2 )nPhOR', (2) CH 2 =CRCOO(CH 2 )nOCO(CH 2 )mPhOR', (3) CH 2 = CHOCO(CH 2 )mPhOR', (4) CH 2 =CHOCO(CH 2 )nOCO(CH 2 )mPhOR', (5) CH 2 = CHO(CH 2 )nOCO(CH 2 )mPhOR' or (6) CH 2 =CHPh(CH 2 )nOCO(CH 2 )mPhOR' where R is a hydrogen atom or a methyl group, R 1 is an alkyl group, R 2 is an alkylene group, R' is a hydrogen atom, an acyl group or a trialkylsilyl group and Ph is a phenylene group, provides a blend rubber having an improved cold resistance and an intermediate heat resistance between the heat resistance of acrylic copolymer elastomer and that of fluorine-containing elastomer, when blended with the fluorine-containing elastomer.
摘要:
A fluorine-containing elastomer composition comprising a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and cyano group-containing (perfluorovinylether), and a less expensive of the ammonium salt of organic or inorganic acid as a curing agent produce a vulcanization product having good heat resistance and solvent resistance, and when no carbon black, etc. are contained in the composition for curing, transparent vulcanization product having satisfactory physical properties are obtainable.
摘要:
A perfluoro unsaturated nitrile compound represented by the following general formula:
CF₂=CFO(CF₂)nOCF(CF₃)CN
is produced by reaction of chlorine or bromine to a perfluoro unsaturated carboxylic acid ester represented by the following general formula:
CF₂=CFO(CF₂)nOCF(CF₃)COOR
followed by reaction with ammonia, thereby converting the ester group to an acid amide group, and then conducting a dehydration reaction and a dehalogenation reaction of the resulting perfluoro unsaturated carboxylic acid amide represented by the following general formula:
CF₂=CFO(CF₂)nOCF(CF₃)CONH₂
in any desired sequence, and is effectively applied as a cross-linking site monomer for fluorine-containing elastomers.
摘要:
A fluorine-containing elastomer composition, which comprises a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and a perfluoro unsaturated nitrile compound represented by the following general formula:
CF₂=CFO(CF₂)nOCF(CF₃)CN
, wherein n is an integer of 2 to 5, and a bis(aminophenyl) compound represented by the following general formula as a cross-linking agent:
, wherein A is an alkylidene group having 1 to 6 carbon atoms or a perfluoroalkylidene group having 1 to 10 carbon atoms and X and Y are a hydroxyl group or an amino group, can produce vulcanized products having good vulcanization physical properties and a good compression set.
摘要:
Novel compound, 2,2-bis(4-carboxyphenyl)hexafluoropropane bisamidrazone, obtained by conversion of the carboxy groups of 2,2-bis(4-carboxyphenyl)hexafluoropropane to acid chloride groups, followed by reaction with ammonia; dehydration reaction of the resulting 2,2-bis(4-carboxyphenyl)hexafluoropropane diamide; reaction of the thus obtained 2,2-bis(4-cyanophenyl)hexafluoropropane with alcohol; and reaction of the resulting 2,2-bis(4-carboxyphenyl)hexafluoropropane bisiminoalkyl ether with hydrazine is a useful vulcanizing agent for fluorine-containing elastomer having cyano group.