摘要:
A process for producing a heat- and pressure-resistant polyester bottle, comprising a primary blow-molding step of obtaining a primary molded article by biaxially stretch-blow-molding a preform of a polyester resin, a heat-treating step of obtaining a secondary molded article that is heat-shrunk by heat-treating the primary molded article, and a secondary blow-molding step of obtaining a finally molded article by biaxially stretch-blow-molding the secondary molded article, wherein the primary blow-molding step biaxially stretches the neck portion of the primary molded article to a size nearly the same as the neck portion of the finally molded article, and the heat-treating step does not cause the neck portion of the secondary molded article to be heat-shrunk. The heat- and pressure-resistant polyester bottle has a slender neck portion of the shape of a so-called crane neck and is suited for containing beer without eradicating the impression of the traditional glass-bottled beer, wherein the length of the neck portion is in a range of 10 to 40% of the height of the bottle, the crystallinity of the neck portion is in a range of 20 to 35%, and the crystallinity of the body portion is in a range of 35 to 50%.
摘要:
To provide a thermoplastic resin container that contains food or drink subjected to a retort processing for which completion of the retort processing can be confirmed and supervised with simple means without the need of an expensive member or facility, not only whether the temperature of the retort processing is reached but also whether the retort processing is performed as specified can be confirmed, and the consumer also can easily confirm completion of the retort processing of the product. The container is produced by two-stage stretch blow molding of a preform made of a thermoplastic resin in such a manner a part that is not stretched or is insufficiently stretched is formed at a part of the container, and the part that is not stretched or is insufficiently stretched is whitened to form a retort processing completion confirming part by heating in the retort processing after a content is packed and sealed in the container.
摘要:
A biaxially stretch-blow molded light weight bottle container, wherein a portion of a cylindrical wall of the container which contains at least one traversed cross section containing an inflection point at a connecting portion between parts of the wall having different traversed cross sectional areas and the like have a thickness of 109 % or more relative to the average thickness of the wall of the stretch-blow molded portion of the container; and a method for producing the bottle container. Illustratively, connection portions between heel parts (14, 24 and 34)and bottom parts (15, 25 and 35), waist portions (16 and 26), concave ribs (27, 37 and 39) and a projected portion (28) are molded so as to have an increased thickness. The above bottle container exhibits an enhanced buckling strength while maintaining the amount of a synthetic resin raw material at a low level.
摘要:
A stretch mold container of the present invention is obtained by draw-forming a resin composition containing a poly-L-lactic acid (A) and a poly-D-lactic acid (B) at a molar ratio A:B in a range of 95:5 to 60:40, and has an amount of heat shrinkage of 5.0% or less under heat treatment conditions of 65°C x 24 hours . Despite of being made from the polylactic acids, the stretch mold container exhibits excellent heat resistance.
摘要:
A stretch-blow-molded container obtained by biaxially stretching and blow-molding a thermoplastic polyester and which exhibits heat resistance or heat resistance and pressure resistance to withstand sterilization by heating at the time of hot filling. The stretch-blow-molded container is obtained by stretch-blow-molding a preform formed of a thermoplastic polyester as a chief component, wherein the body portion, bottom portion and shoulder portion are stretch-oriented, and at least the central portion in the bottom has an endothermic peak (B) due to the extinction of pseudo crystals in a temperature region higher than a glass transition point of the polyester but lower than a temperature at which the crystals of the polyester start melting as measured by using a differential scanning calorimeter (DSC).
摘要:
A heat resistant polyester container comprising a body whose temperature (T) exhibited when the shrinkage factor of the formula: shrinkage factor (%) = (extent of shrinkage /gauge length) x 100 (1) (wherein the extent of shrinkage is measured by TMA under such conditions that no preliminary load is applied and the temperature rise rate from 30°C is 3°C/min with respect to a specimen cut from a body of polyester container so as to have a gauge length of 20 mm) is 0.66% is 120°C or higher. The polyester container is excellent in heat resistance, enables performing retort sterilization at high temperature after charging and sealing of food, beverages, etc., and exhibits such a high heat resistance that, even after the retort sterilization, the body of the container is not deformed.
摘要:
A multilayer preform having at least a medium or intermediate gas barrier layer is prepared in advance by the injection molding of this preform in a predetermined shape that corresponds to the shape of a finished molded product. The body portion of this preform is heated to a blow moldable temperature. The heated preform is set in a primary blow mold (12), and is blow molded in the biaxial orientation to give a primary molded intermediate (5). The primary intermediate (5) is then heated to deform it forcibly by thermal shrinkage and thereby to give the secondary molded intermediate (6). The shrunken secondary intermediate (6) is set in a secondary blow mold (13), and is subjected to the secondary blow molding in the biaxial orientation to obtain a finished molded product, which is fixed thermally to give heat history to the PET resin. As a result, the PET resin layers are given a high degree of crystallization, which serves to complement the function of the gas barrier layer or layers in such a way that the container has high and effective gas barrier properties.
摘要:
A multilayer preform having at least a medium or intermediate gas barrier layer is prepared in advance by the injection molding of this preform in a predetermined shape that corresponds to the shape of a finished molded product. The body portion of this preform is heated to a blow moldable temperature. The heated preform is set in a primary blow mold (12), and is blow molded in the biaxial orientation to give a primary molded intermediate (5). The primary intermediate (5) is then heated to deform it forcibly by thermal shrinkage and thereby to give the secondary molded intermediate (6). The shrunken secondary intermediate (6) is set in a secondary blow mold (13), and is subjected to the secondary blow molding in the biaxial orientation to obtain a finished molded product, which is fixed thermally to give heat history to the PET resin. As a result, the PET resin layers are given a high degree of crystallization, which serves to complement the function of the gas barrier layer or layers in such a way that the container has high and effective gas barrier properties.