摘要:
The invention relates to a method for producing prussic acid by catalytically dehydrating gaseous formamide in at least one main reactor and in a secondary reactor arranged downstream thereof and to the use of a secondary reactor in a method for producing prussic acid by catalytically dehydrating gaseous formamide.
摘要:
The invention provides an oxygen Andrussow process for production of hydrogen cyanide from a methane-containing feedstock such as natural gas in the presence of oxygen and ammonia over a platinum catalyst, wherein the production of byproduct organonitrile impurities, such as acrylonitrile, is reduced. Limiting the content of C 2 + hydrocarbons in the methane feedstock in the oxygen Andrussow process, in contrast to the air Andrussow process, has been found to reduce formation of organonitriles, such as acrylonitrile. The organonitrile impurities can require additional processing for removal, cause fouling of equipment, and can also contribute to hydrogen cyanide polymerization. Reduction of C 2 + hydrocarbon levels to less than 2 wt%, or 1 wt%, or less than 0.1 wt%, in the methane can provide an improved yield of higher purity HCN. Reduction of C 2 + hydrocarbon levels also solves the problem of polymer buildup in process equipment, reducing downtime required for cleaning when higher C 2 + hydrocarbon levels are present in the reaction feed.
摘要:
A hydrogen cyanide production process that recovers ammonia and hydrogen cyanide from a crude hydrogen cyanide product comprising from 25 to 50 vol.% water. When heat is recovered from the ammonia stripper, in the form of low pressure steam, and the steam can be integrated with the refining of hydrogen cyanide.
摘要:
A static mixer is disclosed for a hydrogen cyanide reaction process that thoroughly mixes the reactant gases to form a ternary gas mixture that has a coefficient of variation of less than 0.1 across the diameter of the catalyst bed. The static mixer comprises tabs that are inserted through non-continuous slots in the conduit and the tabs are secured to the external wall of the conduit.
摘要:
The invention relates to a cover device (1) for an open-air leachate storage tank (2), comprising: at least two longitudinal members (3) intended to be disposed on each side of the storage tank (2); a network of at least two slings (4) disposed parallel to one another and stretched between the two longitudinal members (3); and at least one membrane (6) attached to the network of slings (4) and fully covering the storage tank (2), said longitudinal members (3) being arranged so as to create a single slope in relation to the network of slings (4) and the membrane (6). The cover device (1) is characterised in that the membrane (6) consists of a plurality of strips which are arranged parallel and perpendicular to the longitudinal axis of the slings (4) such as to overlap and which are held in place in relation to one another at individual points.
摘要:
Provided is a method for high concentration cation exchange metathesis of divalent ions such as calcium with univalent ions such as sodium or potassium. Due to the difference between ionic valences between the exchanged ions, the provided process behavior is strongly dependent upon the selection of resin properties and to total solution normality. A combination of resin properties and solution normality is provided to achieve the cation exchange.