SUBSTRATES WITH IMPROVED OXIDATION RESISTANCE
    94.
    发明公开
    SUBSTRATES WITH IMPROVED OXIDATION RESISTANCE 审中-公开
    基质麻醉药氧化剂氧化酶

    公开(公告)号:EP1019920A4

    公开(公告)日:2001-02-28

    申请号:EP98957311

    申请日:1998-09-30

    摘要: An alloy article having improved oxidation resistance and biaxially textured surfaces formed by thermo-mechanical techniques has up to 60 atomic % nickel, 0.1 to 25 atomic % of an oxide former selected from Mg, Al, Ti, Cr, Ga, Ge, Zr, Hf, Y, Si, Pr, Eu, Gd, Tb, Dy, Ho, Lu, Th, Er, Tm, Be, Ce, Nd, Sm, Yb, La, and mixtures thereof, with the balance copper. The surface smoothness of the article may be improved by thermomechanical techniques without impairing its surface texture. The CTE of the article may be reduced and its mechanical strength increased by incorportation of additional materials into the article without impairing its surface texture. The alloy article is useful as a conductive substrate for superconducting composites where the substrate is coated with a superconducting oxide. Methods of producing the alloy article by melting and sheath and core thechniques are also disclosed.

    摘要翻译: 通过热机械技术形成的具有改善的耐氧化性和双轴纹理化表面的合金制品具有至多60原子%的镍,0.1至25原子%的选自Mg,Al,Ti,Cr,Ga,Ge,Zr的氧化物, Hf,Y,Si,Pr,Eu,Gd,Tb,Dy,Ho,Lu,Th,Er,Tm,Be,Ce,Nd,Sm,Yb,La及其混合物。 可以通过热机械技术改善制品的表面光滑度,而不损害其表面纹理。 可以减少制品的CTE,并且通过将附加材料嵌入到制品中而不损害其表面纹理而增加其机械强度。 合金制品可用作超导复合材料的导电基底,其中基底用超导氧化物涂覆。 还公开了通过熔融和护套和核心技术生产合金制品的方法。

    A process for the production of a surface-coated cemented carbide
    99.
    发明公开
    A process for the production of a surface-coated cemented carbide 失效
    一种生产表面涂层硬质合金的方法

    公开(公告)号:EP0583853A2

    公开(公告)日:1994-02-23

    申请号:EP93203091.9

    申请日:1989-04-10

    摘要: A process for the production of a coated cemented carbide alloy having jointly a high toughness and high wear resistance is characterized by specifying the cooling rate during sintering in efficient manner. The alloy so produced comprises a cemented carbide substrate consisting of a hard phase of at least one member selected from the group consisting of carbides, nitrides and carbonitrides of Group IVa, Va and VIa metals of the Periodic Table and a binder phase consisting of at least one member selected from the iron group metals, and a monolayer or multilayer, provided thereon, consisting of a least one member selected from the group consisting of carbides, nitrides, oxides and borides of Group IVa, Va and VIa metals of the Periodic Table, solid solutions thereof and aluminium oxide, in which the hardness of the cemented carbide substrate in the range of 2 to 5 µm from the interface between the coating layer and substrate is 800 to 1300 kg/mm² by Vickers hardness at a load of 500 g, is monotonously increased toward the interior of the substrate and becomes constant in the range of about 50 to 100 µm from the interface.

    摘要翻译: 生产共同具有高韧性和高耐磨性的涂覆硬质合金合金的方法的特征在于,以有效的方式指定烧结期间的冷却速率。 如此生产的合金包含硬质合金基体,其由硬质相组成,该硬质相由选自元素周期表IVa族,Va族和VIa族金属的碳化物,氮化物和碳氮化物中的至少一种成分组成,以及由至少一种 一种选自铁族金属和其上提供的单层或多层,由选自元素周期表IVa族,Va族和VIa族金属的碳化物,氮化物,氧化物和硼化物中的至少一种成分组成, 其固溶体和氧化铝,其中硬质合金基体在距离涂层和基体之间的界面2-5μm范围内的硬度在维氏硬度500g负载下为800-1300kg / mm 2, 朝向基板内部单调增加,在距界面约50〜100μm的范围内恒定。