METHOD FOR PRODUCING ALPHA-METHYL STYRENE FROM CUMENE
    111.
    发明授权
    METHOD FOR PRODUCING ALPHA-METHYL STYRENE FROM CUMENE 有权
    从枯烯中生产α-甲基苯乙烯的方法

    公开(公告)号:EP2822920B1

    公开(公告)日:2018-05-02

    申请号:EP13756997.6

    申请日:2013-03-01

    发明人: KEENAN, Scott R.

    IPC分类号: C07C7/04 C07C7/20 C07C15/44

    摘要: A method for controlling the production of heavy compounds in the production of alpha-methyl styrene is provided. In one embodiment, the method includes providing a first composition to a distillation column, said first composition comprising acetone, phenol, cumene and alpha-methyl styrene; refining the first composition in the distillation column to produce a second composition comprising at least 1 wt. % alpha-methyl styrene and at least one organic acid, wherein the second composition includes a higher weight percentage of alpha-methyl styrene than the first composition; and adding an amine to the second composition.

    MISCHUNGEN, ENTHALTEND MONOMERE UND STABILISATOREN
    115.
    发明授权
    MISCHUNGEN, ENTHALTEND MONOMERE UND STABILISATOREN 失效
    MIXES含酸单体和稳定剂

    公开(公告)号:EP0906257B2

    公开(公告)日:2010-04-07

    申请号:EP97925003.2

    申请日:1997-05-28

    申请人: BASF SE

    CPC分类号: C07B63/04 C07C7/20 C07C15/46

    摘要: The invention concerns substance mixtures containing: (A) monomers containing vinyl groups; and (B) an active amount of a mixture which inhibits premature polymerization of the monomers containing vinyl groups during their purification or distillation and contains: (i) between 0.05 and 4.5 wt %, relative to the total mixture (B), of at least one N-oxyl compound of a secondary amine which has no hydrogen atom at the α-C atoms; and (ii) between 99.95 and 95.5 wt %, relative to the total mixture (B), of at least one nitro compound. The invention further concerns a process for inhibiting the premature polymerization of monomers, and the use of mixture (B) for inhibiting the premature polymerization of monomers.

    PROCESS FOR PRODUCING PROPYLENE OXIDE
    119.
    发明公开
    PROCESS FOR PRODUCING PROPYLENE OXIDE 审中-公开
    生产环氧丙烷的方法

    公开(公告)号:EP1681288A1

    公开(公告)日:2006-07-19

    申请号:EP04773382.9

    申请日:2004-09-16

    摘要: A process for producing propylene oxide, which comprises the following steps:

    oxidation step: a step of obtaining cumene hydroperoxide by oxidizing cumene;
    epoxidation step: a step of obtaining propylene oxide and cumyl alcohol by reacting cumene hydroperoxide obtained in the oxidation step with propylene in the presence of an epoxidation catalyst; and
    conversion step: a step of obtaining cumene by subjecting cumyl alcohol obtained in the epoxidation step to hydrogenation-containing reaction and recycling the cumene to the oxidation step,

    wherein a concentration of 1,2-epoxy-2-phenylpropane contained in the reaction mixture after the oxidation step, is 1% by weight or less.

    摘要翻译: 一种生产氧化丙烯的方法,其包括以下步骤:氧化步骤:通过氧化异丙苯获得氢过氧化枯烯的步骤; 环氧化步骤:通过使在氧化步骤中获得的氢过氧化枯烯与丙烯在环氧化催化剂的存在下反应而获得环氧丙烷和枯基醇的步骤; 和转化步骤:通过使在环氧化步骤中获得的枯基醇进行含氢化反应并将枯烯循环至氧化步骤来获得异丙苯的步骤,其中反应混合物中所含的1,2-环氧-2-苯基丙烷的浓度 在氧化步骤之后,为1重量%或更少。

    METHOD FOR PRODUCING ALPHA-METHYLSTYRENE
    120.
    发明公开
    METHOD FOR PRODUCING ALPHA-METHYLSTYRENE 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON ALPHA-METHYLSTYROL

    公开(公告)号:EP1621527A1

    公开(公告)日:2006-02-01

    申请号:EP04722712.9

    申请日:2004-03-23

    CPC分类号: C07D303/04 C07C1/24 C07C15/44

    摘要: A process for producing α-methyl styrene from cumyl alcohol via dehydration in the presence of an activated alumina, characterized in that a concentration of an organic acid contained in a raw material containing cumyl alcohol is 10 to 1000 ppm by weight.

    摘要翻译: 一种在活性氧化铝存在下通过脱水由异丙醇生产±甲基苯乙烯的方法,其特征在于含有枯草醇的原料中含有的有机酸的浓度为10〜1000重量ppm。