HETEROATOM-CONTAINING NANOCARBON MATERIAL, PREPARATION METHOD AND USE THEREOF, AND METHOD FOR DEHYDROGENATION REACTION OF HYDROCARBONS
    3.
    发明公开
    HETEROATOM-CONTAINING NANOCARBON MATERIAL, PREPARATION METHOD AND USE THEREOF, AND METHOD FOR DEHYDROGENATION REACTION OF HYDROCARBONS 审中-公开
    含杂原子的纳米碳材料及其制备方法和用途以及烃类脱氢反应方法

    公开(公告)号:EP3251746A1

    公开(公告)日:2017-12-06

    申请号:EP16742630.3

    申请日:2016-01-27

    摘要: The present invention provides a heteroatom-containing nano-carbon material, a preparation process and use thereof, based on the total weight of said heteroatom-containing nano-carbon material and calculated as the elements, the oxygen content is 1-6wt%, the nitrogen content is 0-2wt%, the carbon content is 92-99wt%; in the XPS, the ratio of the oxygen content as determined with the peak(s) in the range of 531.0-532.5eV to the oxygen content as determined with the peak(s) in the range of 532.6-533.5eV is 0.2-0.8; the ratio of the carbon content as determined with the peak(s) in the range of 288.6-288.8eV to the carbon content as determined with the peak(s) in the range of 286.0-286.2eV is 0.2-1; the ratio of the nitrogen content as determined with the peak(s) in the range of 398.5-400.1eV to the total nitrogen content is 0.7-1. Said heteroatom-containing nano-carbon material shows a good catalytic capability in dehydrogenation of hydrocarbons, and can notably increase the conversion of the starting material and the selectivity for the target product

    摘要翻译: 本发明提供了一种含杂原子的纳米碳材料及其制备方法和用途,基于所述含杂原子的纳米碳材料的总重量计算并且作为元素计算,氧含量为1-6wt%, 氮含量为0-2wt%,碳含量为92-99wt% 在XPS中,用在531.0-532.5eV范围内的峰值测定的氧含量与用532.6-533.5eV范围内的峰值测定的氧含量的比率为0.2-0.8 ; 用288.6-288.8eV范围内的峰值测定的碳含量与用286.0-286.2eV范围内的峰值测定的碳含量的比率为0.2-1; 用398.5-400.1eV范围内的峰值测定的氮含量与总氮含量的比率为0.7-1。 所述含杂原子的纳米碳材料在烃的脱氢中显示出良好的催化能力,并且可显着提高原料的转化率和目标产物的选择性

    PROCESSES AND SYSTEMS FOR RECOVERY OF STYRENE FROM A STYRENE-CONTAINING FEEDSTOCK
    7.
    发明公开
    PROCESSES AND SYSTEMS FOR RECOVERY OF STYRENE FROM A STYRENE-CONTAINING FEEDSTOCK 审中-公开
    方法和系统苯乙烯从含苯乙烯基资源回收

    公开(公告)号:EP2454220A4

    公开(公告)日:2015-08-12

    申请号:EP10800199

    申请日:2010-05-22

    IPC分类号: C07C7/00

    摘要: In various embodiments, the present disclosure describes processes and systems for recovery of styrene from a styrene-rich feedstock. The processes and systems maintain performance of an extractive solvent used in the styrene recovery. In general, the processes include introducing a styrene-rich feedstock to an extractive distillation column, removing a styrene-rich stream from the extractive distillation column, introducing the styrene-rich stream to a solvent recovery column, removing a styrene-lean stream from the solvent recovery column, separating and treating a portion of the styrene-lean stream to form a treated extractive solvent and recycling the treated extractive solvent. In some embodiments, the treating process also includes steam stripping. Styrene-recovery systems including an extractive distillation column, a solvent recovery column, a solvent treatment apparatus having at least one equilibrium stage and a continuous circulation loop connecting these components are also disclosed herein.

    IMPROVED AMINE BASED ADDITIVE COMPOSITION FOR CONTROL AND INHIBITION OF POLYMERIZATION OF AROMATIC VINYL MONOMERS, AND METHOD OF USE THEREOF
    8.
    发明公开
    IMPROVED AMINE BASED ADDITIVE COMPOSITION FOR CONTROL AND INHIBITION OF POLYMERIZATION OF AROMATIC VINYL MONOMERS, AND METHOD OF USE THEREOF 有权
    改进的添加组合物AMIN BASIS用于控制和阻聚乙烯基芳族单体以及它们的使用方法

    公开(公告)号:EP2797864A1

    公开(公告)日:2014-11-05

    申请号:EP12839194.3

    申请日:2012-12-21

    摘要: Improved Amine Based Additive Composition for Control and Inhibition of Polymerization of Aromatic Vinyl Monomers, and Method of Use thereof. The present invention relates to an improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers including styrene comprising one or more of the quinone methide or derivatives thereof, one or more of nitroxide compounds and further comprising one or more of aliphatic tertiary amines. In one embodiment, the present invention also relates to method of use of presently provided composition. In another embodiment, the present invention also relates to method of controlling and inhibiting polymerization of aromatic vinyl monomers, particularly of styrene by employing presently provided composition. In still another embodiment, the present invention also relates to method of preparation of presently provided composition.

    PROCÉDÉ DE PRÉPARATION D'UN CATALYSEUR A BASE D'UN MÉTAL DU GROUPE VIII PRÉPARE AVEC IMPRÉGNATION AU MOYEN D'AU MOINS UN ADDITIF ORGANIQUE ET PROCÈDE D'HYDROGÉNATION SÉLECTIVE METTANT EN OEUVRE LEDIT CATALYSEUR
    9.
    发明公开

    公开(公告)号:EP2794096A1

    公开(公告)日:2014-10-29

    申请号:EP12821263.6

    申请日:2012-12-11

    摘要: The invention relates to a method for preparing a selective hydrogenation catalyst, the active phase of which includes at least one Group VIII metal, and at least one substrate consisting of at least one oxide, wherein said method includes: a) at least a step of preparing a solution containing at least one precursor of said Group VIII metal and at least one additive, said precursor and said additive being added during the preparation of the solution with an additive/Group VIII metal molar ratio of less than or equal to 1.5; b) at least a step of impregnating said substrate with the solution prepared in step a); c) at least a step of drying the impregnated substrate from step b); and d) at least a step of calcining the dried substrate from step c) so as to obtain at least said Group VIII metal in an oxide form. The invention also relates to a hydrogenation method implementing said catalyst. The additives are organic compounds having one to three carboxylic acid functions, preferably carboxylic acids selected from among glycine, aspartic acid, citric acid, and tartric acid. The catalyst obtained by this specific preparation method has catalytic performance that is enhanced in terms of selectivity while still having high activity.

    摘要翻译: 本发明涉及一种用于制备选择性氢化催化剂,该活性相,其包含至少一种VIII族金属,以及至少一个基片由至少一种氧化物的,worin所述方法包括:a)至少一个步骤 制备含有所述第VIII族金属中的至少一种前体和至少一种添加剂,所述前体和所述添加剂的溶液与添加剂/第VIII族金属的摩尔的小于或等于1.5比溶液的制备过程中加入; b)至少浸渍所述的步骤与在步骤a)制备的溶液的底物; c)至少干燥来自步骤b浸渍的底物)的步骤; 和d)至少从步骤c煅烧干燥的底物),以便在获得以氧化物形式的至少所述VIII族金属的步骤。因此,本发明涉及一种加氢方法实施所述催化剂。 添加剂是具有一至三个羧酸官能团,优选为甘氨酸,天冬氨酸,柠檬酸,和酒石酸中选择羧酸的有机化合物。 通过该特定的制备方法得到的催化剂具有催化性能并在选择性方面增强而静静具有高活性。