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    MAGNESIUM COMPOUND, SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR PRODUCING POLYOLEFIN
    114.
    发明公开
    MAGNESIUM COMPOUND, SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR PRODUCING POLYOLEFIN 审中-公开
    镁化合物，用于烯烃聚合，烯烃聚合催化剂对AND PROCESS FOR聚烯烃制造的固体催化剂组分

    公开(公告)号：EP1508559A1

    公开(公告)日：2005-02-23

    申请号：EP03725827.4

    申请日：2003-05-19

    申请人： IDEMITSU KOSAN CO., LTD.

    发明人： TANASE, Shojiro ,  SADASHIMA, Takanori ,  FUNABASHI, Hideo ,  KURAMOTO, Masahiko

    IPC分类号： C07C29/70 ,  C07C31/30 ,  C08F4/654 ,  C07F3/02

    CPC分类号： C08F110/06 ,  C07C29/70 ,  C08F10/00 ,  C08F10/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F4/6548 ,  C08F4/6565 ,  C08F2500/15 ,  C08F2500/24 ,  C07C31/30

    摘要： A magnesium compound obtained by reacting metallic magnesium having a sphericity (S) of less than 4.00, the sphericity (S) being represented by the following formula (I), an alcohol, and a halogen and/or a halogen-containing compound containing halogen atoms in an amount of 0.0001 gram atom or more relative to one gram atom of the metallic magnesium, S = (L 1 /L 2 ) 3    wherein L 1 represents the maximum diameter of projection views of metallic magnesium determined by photographing with a scanning electron microscope and thereafter an image processing, and L 2 represents a diameter of a circle having an area equal to the area of the projection view of metallic magnesium. A solid catalyst component is obtained from the magnesium compound and a titanium compound, and a catalyst for olefin polymerization is obtained using the solid catalyst component.

    摘要翻译： 通过使具有小于4.00的球形度（S）金属镁得到的镁化合物中，球形度（S）由下式（I）至醇和卤素和/或含卤素的含卤素化合物为代表 原子在0.0001克原子或相对更重要的金属镁，<= DF NUM “（I）”> S =（L1 / L2），一个原子的量<3> worin L1 darstellt最大直径 的金属镁的投影视图确定性通过用扫描型电子显微镜和此后的图像处理的拍摄开采，并且L2 darstellt直径上具有面积等于金属镁的投影视图的面积的圆的。 的固体催化剂组分是由镁化合物和钛化合物获得的，并且用于烯烃聚合的催化剂，使用固体催化剂成分得到。

    IMPROVED METHOD OF PREPARATION OF LITHIUM TERTIARY-BUTOXIDE
    119.
    发明公开
    IMPROVED METHOD OF PREPARATION OF LITHIUM TERTIARY-BUTOXIDE 无效
    过程改进锂的制造叔丁醇

    公开(公告)号：EP0721445A4

    公开(公告)日：1996-11-13

    申请号：EP94929124

    申请日：1994-09-02

    申请人： FMC CORP

    发明人： MORRISON ROBERT CHARLES ,  KAMIENSKI CONRAD WILLIAM ,  SCHWINDEMAN JAMES ANTHONY

    IPC分类号： C07C29/68 ,  C07C29/70 ,  C07C31/30

    CPC分类号： C07C29/70 ,  C07C31/30

    摘要： A process for quickly preparing easily separable solutions of lithium tertiary-alkoxides. Comprising the steps of reacting lithium metal in bulk form, containing less than 0.6 % by weight of sodium, with a tertiary alcohol in mole ratios of metal to alcohol ranging from 1 to 1 to 10 to 1 in a solvent selected from ethereal or hydrocarbon solvents under an inert atmosphere at elevated temperature for 1 to 10 hours, cooling the product and separating the product solution from the unreacted lithium metal in the reactor, and optionally adding solvent and sufficient lithium metal and alcohol to said unreacted metal in said reactor to maintain said mole ratio of lithium metal to alcohol, and continuing the reaction, thereby to form further lithium tert-alkoxide, and repeating said steps a number of times.