摘要:
Yield and assay (purity) improvements in the reaction of bromine and the Diels-Alder addition product of maleic anhydride and a conjugated diene in the presence of a nitrogenous acid acceptor are realized in the instant process. The heating time after completion of bromine addition is increased to more completely eliminate hydrogen bromide from the reaction medium and thereby drive the reaction to completion. Also, the type of catalyst selected for use is one which will yield a phthalimide by-product impurity having a boiling point which differs enough from the boiling point of the desired product to allow for distillative separation of the impurity and desired product.
摘要:
Certain gem-dimethyl substituted bicyclic phenolic pyrazines of formula III possess eukalemic diuretic properties. They are of value in treating those diseases and conditions in which a eukalemic diuretic effect is required, for example in treating edema, hypertension and/or related conditions.
摘要:
This invention relates to the use of polymerized substituted benzoid alkyl sulfonic acids and their salts as protective colloids and oil-in-water emulsion stabilizers to prevent formation of an invert emulsion during encapsulation of water-insoluble materials wherein the encapsulating agent forming the microcapsule wall is an organic polyisocyanate which forms a polyurea capsule enclosure.
摘要:
Polymers having substituted urea groups, and molded objects therefrom, can be made by reacting, in a reaction injection molding (RIM) process, a composition comprising (A) a polyisocyanate and (B) a mixture comprising an imino functional resin and a chain extender. The chain extender may also be imino functional.
摘要:
2,2,6,6-tetramethyl-4-oxopiperidine is prepared from acetone and ammonia in the presence of catalytic amounts of active halogen compounds selected from sulfonylhalides, sulfurylhalides, N-haloamides, N-haloimides, β-haloesters, α-haloketones, α-halohydroxy compounds, and β-halonitriles.
摘要:
Novel fungicidal pyridyl cyclopropane carboxamides having the general structural formula wherein R is selected from the group consisting of C₁-C₃ alkoxy, C₁-C₃ haloalkoxy and halogen; and R₁ is C₁-C₆ haloalkyl; and fungicidally acceptable organic and inorganic salts thereof.
摘要:
A polyisocyanate composition, suitable for use in the production of elastomers by the RIM process, or foams, said composition being the product of reacting an imino-functional or enamine-containing compound having a molecular weight of at least 1000 with a stoichiometric excess of an organic polyisocyanate.
摘要:
The present invention relates to a process for the preparation of alkyl semicarbazides by reaction of a dithiocarbamate and hydrazine in a weakly basic reaction media using a metal rearrangement catalyst.
R is alkyl, phenyl, substituted phenyl, alkylsulfonyl, alkoxy, halo, or haloalkyl; R 1 is hydrogen, alkyl, phenyl or halo substituted phenyl; R 2 is hydrogen or alkyl; R 3 is
wherein: R 4 and R 5 are independently hydrogen, alkyl, phenyl, halophenyl, phenalkyl, halophenalkyl, cycloalkyl, cycloalkylmethyl, naphthyl, pyridyl, pyridylalkyl, or R 4 and R 5 taken together with nitrogen form hexamethyleneimine, piperidine, phenylpiperidine, benzylpiperidine, indoline, or perhydroindole; and V is oxygen or sulfur; provided that when R 1 is methyl and R 3 is
wherein R 4 is methyl and R 5 is phenyl, then R is other than 2-chlorophenyl or 2-methoxyphenyl; and when R 1 is hydrogen or ethyl and R 3 is
wherein R 4 is methyl and Rs is phenyl, then R is other than 3,4-dichlorophenyl; and herbicidal compositions and methods utilizing said compounds.