摘要:
The invention relates to a process for preparing solid particles of a phenolic antioxidant from the IRGANOX series in the form of crystals, particularly IRGANOX 1010 and 1098, the crystal particles obtainable by the process, the further processing of the crystal particles, an aqueous dispersion comprising the phenolic antioxidant, novel crystal modifications of pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)-propionate] (μ -form) and N,N'-hexane-1,6diyl-bis[3-(3,5-di-tert-butyl-4-hydroxyphenylpropionamide)] (β -form) and aqueous dispersion comprising the new crystal modifications.
摘要:
The invention relates to a stabilising composition containing a 3-arylacrylic acid ester, a sterically hindered monomeric amine, a sterically hindered phenol, a chroman derivative, and an organic phosphite and/or phosphonite. The inventive stabilising composition is especially suitable for stabilising thermoplastic polyurethane against light, oxygen and heat.
摘要:
Disclosed is a polyacetal resin composition stable to chlorine and chlorides, which is advantageous in terms of excellent thermal stability and chlorine resistance. The polyacetal resin composition consist of 100 parts by weight of polyoxymethylene or a copolymer thereof; 0.01-1.0 part by weight of an antioxidant; 0.01-1.0 part by weight of a thermal stabilizer; 0.01-10.0 parts by weight of metal hydroxide selected from among magnesium hydroxide, calcium hydroxide, barium hydroxide, cadmium hydroxide, aluminum hydroxide and combinations thereof; and 0.01-5.0 parts by weight of metal oxide selected from synthetic aluminum silicate, calcium oxide, magnesium oxide, aluminum oxide and magnesium aluminate. An article prepared from such a polyacetal resin composition is also disclosed.
摘要:
This specification describes an optical polycarbonate composition obtained by the melt polycondensation of a bisphenol and a carbonic diester in the presence of an alkaline compound catalyst, wherein said optical polycarbonate composition comprises (i) a compound expressed by the following Formula (A) in an amount of 30 to 2000 ppm; (ii) a compound expressed by the following Formula (B) in an amount of 30 to 4000 ppm; and (iii) a compound expressed by the following Formula (C) in an amount of 80 to 8000 ppm. The polycarbonate composition has a viscosity average molecular weight of between 12,000 and 18,000 and the portion with a molecular weight (as measured by GPC) of 1000 or less accounts for 0.5 to 1.5 wt%.
摘要:
A method of preparing hindered phenolic antioxidants for lubrication oils or other organic media having reduced residual tin or titanium levels is disclosed herein. A low amount of a tin or titanium catalyst is used resulting in low residual metal levels. The method provides for deactivation of the metal transesterification catalyst with an oxidizing agent, a reducing agent or clay treatment. Treatment with clay, preferably acid treated clay, and more preferably acid treated bentonite clay, after deactivation with the oxidizing agent or reducing agent can further reduce residual tin levels to less than 10 ppm. By deactivating the metal catalyst prior to isolating the antioxidant from the reaction mixture, further reaction at the terminal diol of the reaction product is prevented. The final product mixture may be used without further purification and has improved solubility in lubrication oils and other organic media.
摘要:
The present invention relates to agricultural articles which keep their properties during the use and degrade later on, until total disintegration and disappearance of the plastic. The invention further relates to a method for controlling the weathering resistance and the degradation of agricultural articles. The desired effect is obtained with specific combinations of degradant metal salts and stabilizers. The agricultural article of the present invention comprises an organic polymer, an organic salt of Fe, Ce, Co, Mn, Cu or Vd and one or more sterically hindered amine compounds.
摘要:
A polymer composition and method for reducing the permeability of gases through molded polymeric containers and films by incorporating into the polymer from which the container or film is formed an effective amount of a barrier-enhancing additive, such as monoesters of hydroxybenzoic acid and hydroxynaphthoic acid.
摘要:
A description is given of products obtainable by reacting components a), b), c) and, if desired, d), where component a) is a compound of formula (I) or a mixture of compounds of formula (I), component b) is a compound of formula (II) or a mixture of compounds of formula (II), component c) is a component of formula (IIIa) and/or of formula (IIIb) or a mixture of compounds of formula (IIIa) and/or (IIIb), and component d) is a compound of formula (IV) or a mixture of compounds of formula (IV), in which general symbols are as defined in claim 1, where the compound of formula (I) is pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,2-propanedil, diethylene glycol, triethylene glycol, 1,1,1,-tris(hydroxymethyl)ethane, 2,2-dimethyl-1,3-propanediol or glycerol, the compound of formula (II) is methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate or methyl 3-(3'-tert-butyl-4'-hydroxy-5'-methylphenyl)propionate, the compound of formula (IIIa) is methyl pelargonate or methyl laurate and the compound of formula (IIIb) is 2-dodecenylsuccinic anhydride, and the compound of formula (IV) is, for example, C8-C30alkylbenzene or an alkane of 12 to 30 carbon atoms. These products can be employed as liquid antioxidants in fuels and polymers and as antifriction additives in lubricants.