-
公开(公告)号：EP1558668B1
公开(公告)日：2007-09-12
申请号：EP03809735.8
申请日：2003-10-28
摘要： The invention relates to a polyamide comprising a compound having at least one hydroxyl group, chemically bonded to the end of the polymer chain by means of an amide group, a method for production of such a polyamide, and fibres, films and moulded bodies comprising at least one such polyamide.
-
公开(公告)号：EP1611184A1
公开(公告)日：2006-01-04
申请号：EP04721865.6
申请日：2004-03-19
发明人： DEININGER, Jürgen , DEMETER, Jürgen , KORY, Gad , SÖTJE, Oliver , WINTERLING, Helmut , ZEHNER, Peter , HEEGER, Michael , GANN, Martin , POLT, Axel , TREULING, Ulrich , WEINLE, Werner
摘要： The invention relates to a method for producing polyamides, their oligomers or mixtures thereof, optionally containing other reaction products, by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine and optionally additional polyamide-forming monomers and/or oligomers with water in a reactor (1) with a vertical longitudinal axis. According to said method, the reaction product is exfiltrated from the sump in the reactor (1) and accumulated ammonia and optionally other accumulated low-molecular compounds and water are drawn off via the head (2). The invention is characterised in that the reactor (1) comprises at least two chambers (4) arranged in a longitudinal direction one above the other, that the chambers (4) are separated from one another by liquid-tight floors (5), that each chamber (4) is connected to the one (4) immediately below by a respective liquid overflow (6) and a liquid product stream is drawn off via the liquid overflow (6) of the lowest chamber (4), that the gas chamber (7) above the liquid level in each chamber (4) is connected to the respective chamber (4) lying immediately above it via one or several conduits (8), which open respectively into a gas diffuser (9) comprising orifices (11) for the discharge of gas below the liquid level. The reactor also comprises at least one respective deflector plate (12) positioned vertically around each gas diffuser (9), the upper end of said plate terminating below the liquid level and the lower end terminating above the liquid-tight floor (5) of the chamber (4), thus sub-dividing each chamber (4) into one or more compartments supplied with gas (13) and one or more compartments without gas (14).
摘要翻译： 本发明涉及通过将氨基腈或二腈和二胺或含有氨基腈，二腈和二胺的混合物以及任选另外的形成聚酰胺的单体和/或低聚物与含有其它反应产物的聚酰胺及其低聚物或其混合物 在具有垂直纵轴的反应器（1）中的水。 根据所述方法，反应产物从反应器（1）中的槽中渗出并且积聚氨和任选地其他积聚的低分子化合物和水经由头部（2）排出。 本发明的特征在于，反应器（1）包括至少两个沿上下方向纵向排列的室（4），室（4）通过液密地板（5）彼此分隔开， 每个腔室（4）通过相应的液体溢流（6）与正下方的一个（4）连接，并且液体产品物流通过最低腔室（4）的液体溢流（6）排出，使得气体腔室 （4）中液面以上的通道（7）通过一个或多个导管（8）连接到位于其正上方的相应室（4），所述导管分别通向包括孔口（11）的气体扩散器（9） 用于排放低于液位的气体。 该反应器还包括至少一个分别垂直放置在每个气体扩散器（9）周围的相应偏转板（12），所述板的上端终止于液位下方，并且其下端终止于液体密封层 从而将每个腔室（4）细分成供应有气体（13）的一个或多个隔室和不含气体（14）的一个或多个隔室。
-
公开(公告)号：EP1499656A1
公开(公告)日：2005-01-26
申请号：EP03720432.8
申请日：2003-04-08
IPC分类号： C08G69/00
摘要： The invention relates to a method for producing a polyamide by converting a mixture containing a monomer that comprises a nitrile group and at least one additional functional group that is capable of forming a carboxamide group, in addition to water in the presence of titanium dioxide, which acts as the catalyst. Said method is characterised in that the titanium dioxide has a BET surface area ranging between 5 and 35 m2/g, determined by means of a volumetric process according to a multipoint method, as per the German standard DIN 66 131.
-
公开(公告)号：EP1383822A1
公开(公告)日：2004-01-28
申请号：EP02735165.9
申请日：2002-03-20
发明人： WINTERLING, Helmut , BLINNE, Gerd , VOGEL, Gunter
摘要： The invention relates to a method of producing polyamides in an aqueous reaction mixture that contains a nitrile, selected from 6-aminocapronitrile and adipodinitrile. The inventive method is characterized by using a nitrile through which, in its liquid state, a gas that is inert with respect to the nitrile, was led.
-
公开(公告)号：EP1625173B1
公开(公告)日：2007-08-15
申请号：EP04731336.6
申请日：2004-05-06
发明人： WINTERLING, Helmut , DEMETER, Jürgen , DEININGER, Jürgen , KORY, Gad , SÖTJE, Oliver , WILMS, Axel , WEISS, Robert , KREMPEL, Kurt , BENISCH, Christoph
IPC分类号： C08G69/02
CPC分类号： C08G69/26 , C08G69/02 , C08G69/08 , C08G69/14 , C08G69/265
摘要： The invention relates to a polyamide, the main chain thereof containing a chemically bonded amine selected from the group consisting of 2-methyl-1,5-diaminopentane and 1-amino-2-R-cyclopent-1-ene, wherein R represents a functional group that can react with an amino group to form an amide group. The invention also relates to a method for producing one such polyamide, and to fibres, films and moulded bodies containing the same.
摘要翻译： 本发明涉及一种聚酰胺，其主链含有选自2-甲基-1,5-二氨基戊烷和1-氨基-2-R-环戊-1-烯的化学键合的胺，其中R表示 官能团可以与氨基反应形成酰胺基团。 本发明还涉及一种制造这种聚酰胺的方法，并涉及含有该聚酰胺的纤维，膜和模制体。
-
公开(公告)号：EP1658321A1
公开(公告)日：2006-05-24
申请号：EP04763248.4
申请日：2004-07-15
发明人： DEMETER, Jürgen , SÖTJE, Oliver , BASSLER, Hans-Jürgen , DEININGER, Jürgen , KLAPPERT, Karl-Heinrich , WINTERLING, Helmut
CPC分类号： C08G69/28 , B01J19/02 , B01J2219/0236 , B01J2219/0286 , B01J2219/029 , C08G69/04
摘要： Disclosed is a method for producing polyamides and the oligomers or mixtures thereof, optionally with additional reaction products, by reacting a reaction mixture containing monomers that comprise CN groups or -CONH2 groups, other optional polyamide-forming monomers and/or oligomers, and water in a device. Said method is characterized in that the surfaces of the device, which enter in contact with the reaction mixture, are entirely or partly made of a material that is selected among a group comprising: a) an austenitic steel containing 15 to 25 percent by weight of chromium, 3 to 35 percent by weight of nickel, 0 to 10 percent by weight of molybdenum, and other optional alloy components, the balance being made up of iron and the percentages by weight being in relation to a); b) a duplex steel containing 20 to 30 percent by weight of chromium, 3 to 10 percent by weight of nickel, 0 to 5 percent by weight of molybdenum, and other optional alloy components, the balance being made up of iron and the percentages by weight being in relation to b); and c) a basic nickel alloy containing 12 to 25 percent by weight of chromium, 12 to 20 percent by weight of molybdenum, and other optional alloy components, the balance being made up of nickel and the percentages being in relation to c). Also disclosed are devices that are used in or intended for such a method.
摘要翻译： 本发明公开了通过使含有CN基团或-CONH 2基团的单体，其它任选的形成聚酰胺的单体和/或低聚物以及水的反应混合物与含有CN基团的单体和/或低聚物反应来制备聚酰胺及其低聚物或其混合物的方法 一个装置。 所述方法的特征在于与所述反应混合物接触的所述装置的表面全部或部分地由选自包括以下的组中的材料制成：a）含有15至25重量％的奥氏体钢 铬，3至35重量％的镍，0至10重量％的钼和其它任选的合金组分，余量由铁构成，并且重量百分比与a）相关; b）含有20至30重量％的铬，3至10重量％的镍，0至5重量％的钼和其它任选的合金组分的双相钢，余量由铁和百分比组成 重量与b）有关; 和c）含有12-25重量％铬，12-20重量％钼和其它任选合金组分的碱性镍合金，余量由镍构成，并且其百分数与c）相关。 还公开了用于或用于这种方法的设备。
-
公开(公告)号：EP1631615A1
公开(公告)日：2006-03-08
申请号：EP04731364.8
申请日：2004-05-06
发明人： WINTERLING, Helmut , DEMETER, Jürgen , DEININGER, Jürgen , KORY, Gad , SÖTJE, Oliver , NEUHAUS, Ralf , KREMPEL, Kurt , BENISCH, Christoph
摘要： The invention relates to a polyamide, the main chain thereof containing a chemically bonded N-alkyl lactam. The invention also relates to a method for producing one such polyamide, and to fibres, films and moulded bodies containing the same.
摘要翻译： 本发明涉及聚酰胺，其主链含有化学键合的N-烷基内酰胺。 本发明还涉及一种制造这种聚酰胺的方法，并涉及含有该聚酰胺的纤维，膜和模制体。
-
公开(公告)号：EP1242506B1
公开(公告)日：2005-06-01
申请号：EP00990757.7
申请日：2000-12-14
摘要： The invention relates to a method for the production of polyamides from amino nitriles and water, (1) by reacting aminonitriles with water at a temperature of 180 - 350 DEG C and a pressure of 30 - 120 bar adjusted in such a way that in addition to a liquid phase, a gaseous phase is also present in the first reaction step; (2) relaxation of the reaction mixture obtained in the first reaction step via an evaporator zone or adiabatically with removal of water and ammonia in a second reaction step and (3) post-condensation in the second reaction step at a pressure 0.1 mbar to 5 bar at a temperature of 230 - 320 DEG C.
摘要翻译： 本发明涉及一种由氨基腈和水生产聚酰胺的方法，（1）在180-350℃的温度和30-120巴的压力下使氨腈与水反应，使得另外调节 在液相中，气相也存在于第一反应步骤中; （2）通过蒸发器区在第一反应步骤中获得的反应混合物的松弛或在第二反应步骤中通过除去水和氨而绝热，和（3）在第二反应步骤中在0.1毫巴至5巴的压力下进行后缩合 在230-320℃的温度下
-
19.发明公开
公开(公告)号：EP1299450A1
公开(公告)日：2003-04-09
申请号：EP01967141.1
申请日：2001-07-10
摘要： The invention relates to a continuous method for producing a polyamide by reacting at least one aminonitrile with water. Said method comprises the following steps: (1) at least one aminonitrile is reacted with water in the presence of an organic liquid diluting agent at a temperature of 90 to 400 °C and a pressure of 0.1 to 35 x 106 Pa in a stream tube containing a Brönsted acid catalyst selected from a beta-zeolite, phyllosilicate, or titanium dioxide catalyst consisting of 70 to 100 wt. % of anatase and 0 to 30 wt. % of rutile, in which up to 40 wt. % of the titanium dioxide can be replaced by tungsten oxide, in order to obtain a reaction mixture, (2) the reaction mixture is further reacted at a temperature of 150 to 400 °C and a pressure which is lower than the pressure in step 1, in the presence of a Brönsted acid catalyst selected from a beta-zeolite, phyllosilicate, or titanium dioxide catalyst consisting of 70 to 100 wt. % anatase and 0 to 30 wt. % rutile, in which up to 40 wt. % of the titanium dioxide can be replaced by tungsten oxide, the temperature and the pressure being chosen in such a way that a first gas phase and a first liquid phase or a first solid phase or a mixture of a first solid phase and a first liquid phase is obtained, the first gas phase being separated from the first liquid phase or first solid phase or the mixture of the first liquid phase and first solid phase, and (3) the first liquid phase or the first solid phase or the mixture of the first liquid phase and first solid phase is mixed with a gaseous phase or a liquid phase containing water, at a temperature of 150 to 370 °C and a pressure of 0.1 to 30 x 106 Pa, in order to obtain a product mixture.
-
20.发明公开
公开(公告)号：EP1280846A1
公开(公告)日：2003-02-05
申请号：EP01943299.6
申请日：2001-04-30
发明人： OHLBACH, Frank , WINTERLING, Helmut , ANSMANN, Andreas , FISCHER, Rolf-Harmuth , MELDER, Johann-Peter , MAIXNER, Stefan , BASSLER, Peter , LUYKEN, Hermann
CPC分类号： C08G69/14 , C08G69/04 , C08G69/16 , Y10T428/29 , Y10T428/2969 , Y10T428/2971
摘要： The invention relates to a method for producing a polymer. Said method is characterized as follows: a) a mixture (I) containing 6-aminocapronitrile and water is converted into a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers in the presence of a catalyst; then b) the ammonia is removed from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers; subsequently c) the water is completely or partially eliminated from mixture (III) to obtain a mixture (IV) containing caprolactam, high boilers and low boilers; and finally d) mixture (IV) is subjected to a polymerization reaction. The invention also relates to a polymer obtained according to said method, to its use in the production of fibres, flat material and moulded bodies that are obtained using a polymer of this type.
-
-
-
-
-
-
-
-
-
搜索结果
20 条记录 (耗时 0.018 秒)
