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公开(公告)号:EP1611184B1
公开(公告)日:2006-09-27
申请号:EP04721865.6
申请日:2004-03-19
发明人: DEININGER, Jürgen , DEMETER, Jürgen , KORY, Gad , SÖTJE, Oliver , WINTERLING, Helmut , ZEHNER, Peter , HEEGER, Michael , GANN, Martin , POLT, Axel , TREULING, Ulrich , WEINLE, Werner
摘要: The invention relates to a method for producing polyamides, their oligomers or mixtures thereof, optionally containing other reaction products, by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine and optionally additional polyamide-forming monomers and/or oligomers with water in a reactor (1) with a vertical longitudinal axis. According to said method, the reaction product is exfiltrated from the sump in the reactor (1) and accumulated ammonia and optionally other accumulated low-molecular compounds and water are drawn off via the head (2). The invention is characterised in that the reactor (1) comprises at least two chambers (4) arranged in a longitudinal direction one above the other, that the chambers (4) are separated from one another by liquid-tight floors (5), that each chamber (4) is connected to the one (4) immediately below by a respective liquid overflow (6) and a liquid product stream is drawn off via the liquid overflow (6) of the lowest chamber (4), that the gas chamber (7) above the liquid level in each chamber (4) is connected to the respective chamber (4) lying immediately above it via one or several conduits (8), which open respectively into a gas diffuser (9) comprising orifices (11) for the discharge of gas below the liquid level. The reactor also comprises at least one respective deflector plate (12) positioned vertically around each gas diffuser (9), the upper end of said plate terminating below the liquid level and the lower end terminating above the liquid-tight floor (5) of the chamber (4), thus sub-dividing each chamber (4) into one or more compartments supplied with gas (13) and one or more compartments without gas (14).
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2.
公开(公告)号:EP1242506A1
公开(公告)日:2002-09-25
申请号:EP00990757.7
申请日:2000-12-14
摘要: The invention relates to a method for the production of polyamides from amino nitriles and water, (1) by reacting aminonitriles with water at a temperature of 180 - 350 °C and a pressure of 30 - 120 bar adjusted in such a way that in addition to a liquid phase, a gaseous phase is also present in the first reaction step; (2) relaxation of the reaction mixture obtained in the first reaction step via an evaporator zone or adiabatically with removal of water and ammonia in a second reaction step and (3) post-condensation in the second reaction step at a pressure 0.1 mbar to 5 bar at a temperature of 230 - 320 °C.
摘要翻译: 本发明涉及由氨基腈和水生产聚酰胺的方法,(1)通过使氨基腈与水在180-350℃的温度和30-120巴的压力下反应,以使得另外 在液相中,气相也存在于第一反应步骤中; (2)通过蒸发器区在第一反应步骤中获得的反应混合物的松弛或在第二反应步骤中通过除去水和氨而绝热,和(3)在第二反应步骤中在0.1毫巴至5巴的压力下进行后缩合 在230-320℃的温度下进行。
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公开(公告)号:EP1499657A1
公开(公告)日:2005-01-26
申请号:EP03717299.6
申请日:2003-04-14
IPC分类号: C08G69/04 , C08G69/14 , C08G69/48 , C08F299/02
CPC分类号: C08G69/04 , C08F299/022 , C08G69/48
摘要: The invention relates to a polyamide that comprises a monoolefinically unsaturated monocarbonic acid chemically bonded to the terminus of the polymer chain, to a method for producing such a polyamide, to a polyamide obtained by cross-linking such a polyamide, and to fibers, films and molded bodies that contain at least one such polyamide.
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公开(公告)号:EP1349886A2
公开(公告)日:2003-10-08
申请号:EP01989503.6
申请日:2001-11-22
摘要: The invention relates to a method for producing polyamides. Said method is characterised in that the polymerisation of starting monomers is carried out in the presence of between 2.3 and 10 mmol - in relation to 1 mol of carboxamide group of the polyamide - of a compound used as a chain transfer agent, comprising a nitrile group and a functional group capable of forming a carboxamide group.
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公开(公告)号:EP1499657B1
公开(公告)日:2008-01-16
申请号:EP03717299.6
申请日:2003-04-14
IPC分类号: C08G69/04 , C08G69/14 , C08G69/48 , C08F299/02
CPC分类号: C08G69/04 , C08F299/022 , C08G69/48
摘要: The invention relates to a polyamide that comprises a monoolefinically unsaturated monocarbonic acid chemically bonded to the terminus of the polymer chain, to a method for producing such a polyamide, to a polyamide obtained by cross-linking such a polyamide, and to fibers, films and molded bodies that contain at least one such polyamide.
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公开(公告)号:EP1349886B1
公开(公告)日:2007-08-15
申请号:EP01989503.6
申请日:2001-11-22
摘要: The invention relates to a method for producing polyamides. Said method is characterised in that the polymerisation of starting monomers is carried out in the presence of between 2.3 and 10 mmol - in relation to 1 mol of carboxamide group of the polyamide - of a compound used as a chain transfer agent, comprising a nitrile group and a functional group capable of forming a carboxamide group.
摘要翻译: 本发明涉及一种生产聚酰胺的方法。 所述方法的特征在于,起始单体的聚合在用作链转移剂的化合物的相对于1mol聚酰胺的羧酰胺基团为2.3至10mmol的存在下进行,所述化合物包含腈基 和能够形成羧酰胺基团的官能团。
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7.
公开(公告)号:EP1499656B1
公开(公告)日:2006-07-05
申请号:EP03720432.8
申请日:2003-04-08
IPC分类号: C08G69/00
摘要: The invention relates to a method for producing a polyamide by converting a mixture containing a monomer that comprises a nitrile group and at least one additional functional group that is capable of forming a carboxamide group, in addition to water in the presence of titanium dioxide, which acts as the catalyst. Said method is characterised in that the titanium dioxide has a BET surface area ranging between 5 and 35 m /g, determined by means of a volumetric process according to a multipoint method, as per the German standard DIN 66 131.
摘要翻译: 本发明涉及一种生产聚酰胺的方法,该方法通过在含有二氧化钛的情况下将含有包含腈基团和至少一个能够形成羧酰胺基团的另外官能团的单体的混合物转化为水, 充当催化剂。 所述方法的特征在于,根据德国标准DIN 66 131,二氧化钛具有根据多点法通过体积法确定的5-35m 2 / g的BET表面积。
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公开(公告)号:EP1625173A1
公开(公告)日:2006-02-15
申请号:EP04731336.6
申请日:2004-05-06
发明人: WINTERLING, Helmut , DEMETER, Jürgen , DEININGER, Jürgen , KORY, Gad , SÖTJE, Oliver , WILMS, Axel , WEISS, Robert , KREMPEL, Kurt , BENISCH, Christoph
IPC分类号: C08G69/02
CPC分类号: C08G69/26 , C08G69/02 , C08G69/08 , C08G69/14 , C08G69/265
摘要: The invention relates to a polyamide, the main chain thereof containing a chemically bonded amine selected from the group consisting of 2-methyl-1,5-diaminopentane and 1-amino-2-R-cyclopent-1-ene, wherein R represents a functional group that can react with an amino group to form an amide group. The invention also relates to a method for producing one such polyamide, and to fibres, films and moulded bodies containing the same.
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公开(公告)号:EP1558668A1
公开(公告)日:2005-08-03
申请号:EP03809735.8
申请日:2003-10-28
摘要: The invention relates to a polyamide comprising a compound having at least one hydroxyl group, chemically bonded to the end of the polymer chain by means of an amide group, a method for production of such a polyamide, and fibres, films and moulded bodies comprising at least one such polyamide.
摘要翻译: 本发明涉及包含具有至少一个羟基的化合物的聚酰胺,所述化合物通过酰胺基团化学键合到聚合物链的末端,制备这种聚酰胺的方法以及纤维,膜和模制体,所述纤维,膜和模制体包含 至少一个这种聚酰胺。
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公开(公告)号:EP1631615B1
公开(公告)日:2007-11-21
申请号:EP04731364.8
申请日:2004-05-06
发明人: WINTERLING, Helmut , DEMETER, Jürgen , DEININGER, Jürgen , KORY, Gad , SÖTJE, Oliver , NEUHAUS, Ralf , KREMPEL, Kurt , BENISCH, Christoph
摘要: The invention relates to a polyamide, the main chain thereof containing a chemically bonded N-alkyl lactam. The invention also relates to a method for producing one such polyamide, and to fibres, films and moulded bodies containing the same.
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