VERWENDUNG VON SULFONS UREGRUPPENHALTIGEN COPOLYMEREN ALS ZUSATZ IN WASCH- UND REINIGUNGSMITTELN
    14.
    发明授权
    VERWENDUNG VON SULFONS UREGRUPPENHALTIGEN COPOLYMEREN ALS ZUSATZ IN WASCH- UND REINIGUNGSMITTELN 有权
    砜UREGRUPPENHALTIGEN的使用共聚物在洗涤剂和清洁剂作为附加

    公开(公告)号:EP1516040B1

    公开(公告)日:2009-08-12

    申请号:EP03740180.9

    申请日:2003-06-04

    Applicant: BASF SE

    CPC classification number: C11D3/378

    Abstract: The invention relates to sulfonic acid group-containing copolymers, which also contain the following constituents that are incorporated by polymerization in a statistical or block-by-block manner: (a) 30 to 95 mol % of a least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic acid ester, or one water-soluble salt of a monoethylenically unsaturated carboxylic acid; (b) 3 to 35 mol % of at least one sulfonic acid group-containing monomer of formula (I), in which the variables have the following meanings: R represents hydrogen or methyl; X represents a chemical bond or -C00-R -; R represents unbranched or branched C1-C4 alkylene; M represents hydrogen, alkali metal or ammonium, and; (c) 2 to 35 mol % of at least one non-ionic monomer of formula (II), in which the variables have the following meanings: R represents hydrogen or methyl; R represents a chemical bond or unbranched or branched C1-C6 alkylene; R represents identical or different unbranched or branched C2-C4 alkylene groups; R represents unbranched or branched C1-C6 alkyl, C5-C8 cycloalkyl or aryl, and; n represents 3 to 50. These copolymers are used as an additive in detergents and cleansers.

    NIEDERMOLEKULARE PHOSPHORHALTIGE POLYACRYLSÄUREN UND DEREN VERWENDUNG ALS BELAGSINHIBITOREN IN WASSERFÜHRENDEN SYSTEMEN
    18.
    发明公开
    NIEDERMOLEKULARE PHOSPHORHALTIGE POLYACRYLSÄUREN UND DEREN VERWENDUNG ALS BELAGSINHIBITOREN IN WASSERFÜHRENDEN SYSTEMEN 有权
    耐高温磷酸盐聚合物在德国VERWENDUNG ALS BELAGSINHIBITOREN在WASSERFÜHRENDENSYSTEMEN

    公开(公告)号:EP2670523A1

    公开(公告)日:2013-12-11

    申请号:EP12701528.7

    申请日:2012-02-01

    Applicant: BASF SE

    Abstract: The invention relates to an aqueous solution of acrylic acid polymers obtainable by polymerizing acrylic acid in feed mode with peroxodisulphate as initiator in the presence of hypophosphite in water as solvent, where (i) water and optionally one or more ethylenically unsaturated comonomers are introduced initially, and (ii) acrylic acid in acidic, non-neutralized form, optionally one or more ethylenically unsaturated comonomers, aqueous peroxodisulphate solution and aqueous hypophosphite solution are added continuously, and (iii) after the end of the acrylic acid feed, a base is added to the aqueous solution, the comonomer content not exceeding 30% by weight, based on the total monomer content.

    Abstract translation: 本发明涉及丙烯酸聚合物的水溶液,其通过在次亚磷酸盐作为溶剂的存在下,以进料方式与过氧二硫酸盐作为引发剂聚合丙烯酸,其中(i)水和任选的一种或多种烯属不饱和共聚单体最初引入, 和(ii)酸性,非中和形式的丙烯酸,任选的一种或多种烯键式不饱和共聚单体,过氧二硫酸水溶液和次磷酸钠水溶液,并且(iii)在丙烯酸进料结束后,加入碱 相对于水溶液,基于总单体含量,共聚单体含量不超过30重量%。

    VERWENDUNG VON ALKYLENOXIDEINHEITEN ENTHALTENDEN COPOLYMEREN ALS ZUSATZ ZU WÄSSRIGEN SYSTEMEN
    19.
    发明授权
    VERWENDUNG VON ALKYLENOXIDEINHEITEN ENTHALTENDEN COPOLYMEREN ALS ZUSATZ ZU WÄSSRIGEN SYSTEMEN 有权
    使用含共聚物亚水性体系中加入

    公开(公告)号:EP1896372B1

    公开(公告)日:2012-03-21

    申请号:EP06763728.0

    申请日:2006-06-14

    Applicant: BASF SE

    Abstract: The invention relates to the use of copolymers containing alkylene oxides as an additive to aqueous systems containing phosphate and/or phosphonate in industrial technical installations. These copolymers, while being incorporated by polymerization in a statistical or block-by-block manner, contain: (a) 50 to 93 mol- % of acrylic acid and/or of a water-soluble salt of the acrylic acid; (b) 5 to 30 mol- % of methacrylic acid and/or of a water-soluble salt of methacrylic acid, and; (c) 2 to 20 mol- % of at least one nonionic monomer of formula (I) in which the variables have the following meaning: R1 represents hydrogen or methyl; R2 represents a chemical bond or an unbranched or branched C1-C6 alkylene; R3 represents the same or different unbranched or branched C2-C4 alkylene radicals; R4 represents unbranched or branched C1-C6 alkyl, and; n represents 3 to 50.

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