摘要:
The invention concerns a method for thickening an aqueous composition, by introducing into said composition to be thickened at least one polymer, characterized in that said polymer contains at least one anionic monomer which is an organophosphate monomer. The invention also concerns aqueous compositions thus thickened and containing said polymers.
摘要:
The invention relates to associative thickeners, and more particularly, HASE type associative thickeners used in aqueous formulations, firstly concerning novel hydrophobic compounds of the radical-substituted cumyl phenol type, produced by the reaction of a cumyl phenol and an alkene or a mixture of alkenes. Said products can be used in the composition of novel associative HASE type thickeners, which permit an improvement in the rheology of aqueous formulations to which they are applied.
摘要:
The invention relates to polymers produced by using sulphur compounds for a method for the controlled radical polymerisation of acrylic acid and/or acrylic acid with hydrosoluble monomers in water. Said invention also relates to the use of said polymers in the form of dispersing agents or grinding aid agents and/or aid agents for combined grinding of mineral materials in an aqueous suspension or in the form of dispersing agents directly incorporated into aqueous formulations containing mineral materials. The formulations of the thus obtained mineral materials are also disclosed.
摘要:
The invention concerns the use for making paper coating slips of a water soluble copolymer in neutral or alkaline medium as agent for simultaneously adjusting water retention in coating slips and the Brookfield viscosity of said coating slips. The invention also concerns a novel water retention agent of paper coating slips water soluble in neutral or alkaline medium. The invention further concerns coating slips and coated paper and cardboard resulting therefrom.
摘要:
The invention concerns the technical field of polymerisation of acrylic acid and its salts, more particularly in solution, more particularly controlled free-radical polymerisation, the use of corresponding organo-sulphur transfer agents, the resulting acrylic acid polymers, having very low polydispersity (or very low polymolecularity index, which is equivalent in meaning), and their industrial uses.
摘要:
Water-soluble weakly anionic copolymer comprises ethylenically unsaturated anionic monomers with mono-carboxylic, di-carboxylic, sulfonic, phosphoric or phosphonic groups, non-ionic ethylenically unsaturated monomer, (meth)acrylamide or (meth)acrylate type monomer(s) and doubly ethylenically unsaturated monomers. Water-soluble weakly anionic copolymer, used as dispersing/grinding agent for aqueous suspensions of pigments and/or mineral fillers, comprises: (a) at least one ethylenically unsaturated anionic monomer A with mono-carboxylic group, selected from (meth)acrylic acids or diacid hemi-esters such as 1-4C monoesters of maleic or itaconic acids, or their mixtures; (b) optionally at least one ethylenically unsaturated anionic monomer B with dicarboxylic, sulfonic, phosphoric or phosphonic group, or their mixtures, selected from crotonic, isocrotonic, cinnamic, itaconic, maleic or citraconic acids, or anhydrides such as maleic anhydride, acrylamido-methyl- propane-sulfonic acid, sodium meth-allyl sulfonate, vinyl sulfonic and styrene-sulfonic acids, or vinyl phosphoric acid, ethylene or propylene glycol (meth)acrylate phosphate and their ethoxylates, or from vinyl phosphonic acid, or their mixtures; and (c) at least one non-ionic ethylenically unsaturated monomer of formula (I); (d) optionally a monomer D of type of (meth)acrylamide or their derivatives and mixtures, or one or more water non-soluble monomers D1 such as alkyl (meth)acrylate, vinyl acetate, vinylpyrrolidone, styrene, alpha-methyl styrene and their derivatives; and (e) optionally at least one monomer E with at least two ethylenic unsaturations, selected from ethylene glycol dimethacrylate, trimethylol propane triacrylate, allyl acrylate or maleates, methylene- bis-(meth)acrylamide, tetra-allyloxy ethane, triallyl cyanurates and allylic ethers obtained from polyols such as pentaerythritol, sorbitol, sucrose or others, with components (a), (b), (c), (d) and (e) amounting to total of 100%. The copolymer has specific viscosity up to 10 and especially up to 2. [Image] R1H, methyl or ethyl radical; R2H, methyl or ethyl radical; R : polymerizable unsaturated radical, selected from (meth)acrylic, maleic, itaconic, crotonic and vinylphthalic esters, unsaturated urethanes such as (meth)acryl urethane, alpha-alpha dimethyl- isopropenyl-benzyl urethane and allyl urethane, allyl or vinyl esters or ethylenically unsaturated amides; R' : 1-5C hydrocarbon radical; m and p : number of alkylene oxide groups up to 150; n : number of ethylene oxide groups up to 150; q : at least 1, with (m+n+p)q equal 5-150 Independent claims are also included for: (1) dispersing and/or grinding agent for pigments and/or mineral fillers in aqueous suspensions, consisting of copolymer as claimed, of composition as described below; (2) aqueous suspension of fillers and/or pigments, containing 0.05-5 wt.% (preferably 0.3-1.0 wt.%) of dispersing agent as claimed; (3) use of aqueous suspension of fillers and/or pigments in making and/or layering of paper; (4) paper sheets containing aqueous suspension of fillers and/or pigments as claimed; (5) use of aqueous suspension of fillers and/or pigments as claimed in drilling muds for oil prospecting or extraction, especially saturated saline muds and marine muds; (6) drilling mud containing aqueous suspension of fillers and/or pigments as claimed; (7) use of dispersing and/or grinding agent for pigments and/or mineral fillers in aqueous suspensions as claimed employed in paint industry; and (8) use of dispersing and/or grinding agent for pigments and/or mineral fillers in aqueous suspensions as claimed employed in field of plastic materials, especially thermoplastic or thermosetting resins.
摘要:
The invention concerns the use for making paper coating slips of a water soluble copolymer in neutral or alkaline medium as agent for simultaneously adjusting water retention in coating slips and the Brookfield viscosity of said coating slips. The invention also concerns a novel water retention agent of paper coating slips water soluble in neutral or alkaline medium. The invention further concerns coating slips and coated paper and cardboard resulting therefrom.
摘要:
The present invention relates to a novel method for solvent-free preparation of a polymer of (meth)acrylic acid in a solution, said polymer having a molecular weight of less than 8,000 g/mol and a polydispersity index (PDI) of 2 to 5 by radical polymerisation.