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11.
公开(公告)号:EP1100134B1
公开(公告)日:2005-11-16
申请号:EP00912892.7
申请日:2000-03-29
CPC分类号: H01M10/052 , H01M4/02 , H01M4/04 , H01M4/0402 , H01M4/134 , H01M4/366 , H01M4/386 , H01M4/40 , H01M4/463 , H01M4/466 , H01M4/58 , H01M4/625 , H01M4/626 , H01M2004/027
摘要: A high capacity negative electrode for a non-aqueous electrolyte secondary battery which has low declining rate in discharge capacity caused by charge/discharge cycles by improving the electronic conductivity on the surface of the particles of the negative electrode material. The negative electrode material is formed by coating part of or the entire surface of solid phase A comprising a nucleus particle with the solid phase B. The solid phase A contains silicon as a constituent element. The solid phase B is composed of a solid solution or intermetallic compounds composed of silicon and at least one another element selected from a group comprising of group 2 elements, transition elements, group 12 elements , group 13 elements and group 14 elements (exclusive of carbon and silicon) of the Periodic Table.
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公开(公告)号:EP1274140A1
公开(公告)日:2003-01-08
申请号:EP01917771.6
申请日:2001-03-30
CPC分类号: H01M4/134 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/40 , H01M10/052 , H01M2004/027
摘要: To obtain a nonaqueous secondary battery having a large capacity and a smell irreversible capacity while maintaining cycle characteristics, a composite particle comprising a core particle composed of a solid phase A and a coating layer composed of a solid phase B covering at least a part of the core particle is used for the negative electrode of a nonaqueous secondary battery, and at least one of the solid phase A and the solid phase B is made amorphous.
摘要翻译: 为了获得具有大容量和气味不可逆容量同时保持循环特性的非水二次电池,包含由固相A组成的芯颗粒和由固相B构成的涂层的复合颗粒,所述固体B覆盖至少一部分 核心粒子用于非水系二次电池的负极,固相A和固相B中的至少一个为无定形。
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13.
公开(公告)号:EP1100134A1
公开(公告)日:2001-05-16
申请号:EP00912892.7
申请日:2000-03-29
CPC分类号: H01M10/052 , H01M4/02 , H01M4/04 , H01M4/0402 , H01M4/134 , H01M4/366 , H01M4/386 , H01M4/40 , H01M4/463 , H01M4/466 , H01M4/58 , H01M4/625 , H01M4/626 , H01M2004/027
摘要: A high capacity negative electrode for a non-aqueous electrolyte secondary battery which has low declining rate in discharge capacity caused by charge/discharge cycles by improving the electronic conductivity on the surface of the particles of the negative electrode material. The negative electrode material is formed by coating part of or the entire surface of solid phase A comprising a nucleus particle with the solid phase B. The solid phase A contains silicon as a constituent element. The solid phase B is composed of a solid solution or intermetallic compounds composed of silicon and at least one another element selected from a group comprising of group 2 elements, transition elements, group 12 elements , group 13 elements and group 14 elements (exclusive of carbon and silicon) of the Periodic Table.
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公开(公告)号:EP1052714A1
公开(公告)日:2000-11-15
申请号:EP99973177.1
申请日:1999-11-30
CPC分类号: H01M4/38 , H01M4/02 , H01M4/36 , H01M4/366 , H01M4/386 , H01M4/387 , H01M4/40 , H01M4/42 , H01M4/624 , H01M4/625 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M10/445 , H01M2004/027
摘要: The present invention relates to a non-aqueous electrolyte secondary battery. The negative electrode of the present invention is characterized by its composite particles constructed in such a manner that at least part of the surrounding surface of nuclear particles containing at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an intermetallic compound , which are composed of the element contained in the nuclear particles, and at least one other element except the elements contained in the nuclear particles selected from a group comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements except carbon of the Periodic Table. The electrolyte uses anion lithium salts of organic acid dissolved in organic solvent with high oxidation resistant characteristics. By adopting the above construction, a battery which generates only a small amount of gas during a high temperature storing can be obtained. Furthermore, the batteries enjoy high energy density and a lower reduction rate of discharge capacity when used repeatedly as well as high charge/discharge properties.
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