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1.发明公开NON-AQUEOUS ELECTROLYTE SECONDARY CELL AND ITS CHARGING METHOD 有权SEKUNDÄRZELLEMITNICHTWÄSSRIGEMELEKTROLYTEN UND VEFAHREN ZU DESSEN AUFLADUNG
公开(公告)号：EP1052713A1
公开(公告)日：2000-11-15
申请号：EP99973176.3
申请日：1999-11-30
CPC分类号： H01M4/134 , H01M4/02 , H01M4/131 , H01M4/362 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/42 , H01M10/052 , H01M10/44 , H01M2004/027
摘要： The negative electrode of the present invention is characterized by its composite particles constructed in such a manner that at least part of the surrounding surface of nuclear particles containing at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound , which is composed of, the element included in the nuclear particles, and at least one other element except the elements included in the nuclear particles selected from a group comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements except carbon of the Periodic Table. The present invention is characterized that the lithium content of the nuclear particles of the composite particles is 40-95 atomic percent of the theoretical limit of lithium content of each constituent element of the nuclear particles. Further, the batteries are first charged at a constant current and upon reaching the predetermined voltage, are charged at a constant voltage. The current density during charging are set at not more than 5mA/cm 2 as a in the area where the positive and negative electrodes face each other. With the foregoing construction, high energy-density non-aqueous electrolyte secondary batteries with superior cycle life properties and a charging method for the same can be obtained.
摘要翻译： 本发明的负极的特征在于，其复合颗粒的构成是将含有锡，硅和锌中的至少一种作为构成元素的至少一部分核粒子的周围表面涂布固溶体 或由包含在核粒子中的元素构成的金属间化合物，以及除了选自包含第2族元素，过渡元素，第12族元素的核粒子中的元素以外的至少一种其它元素， 第13族元素和第14族元素，除了元素周期的碳。 本发明的特征在于，复合粒子的核粒子的锂含量为核粒子的各构成元素的锂含量的理论极限的40〜95原子％。 此外，电池首先以恒定电流充电并且在达到预定电压时以恒定电压被充电。 在正极和负极彼此面对的区域中，充电期间的电流密度设定为5mA / cm 2以下。 通过上述结构，可以获得具有优异循环寿命特性的高能量密度非水电解质二次电池及其充电方法。
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2.发明公开
公开(公告)号：EP1638158A2
公开(公告)日：2006-03-22
申请号：EP04734368.6
申请日：2004-05-21
IPC分类号： H01M4/38
CPC分类号： H01M10/052 , H01M4/134 , H01M4/1395 , H01M4/362 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/621 , Y10T29/49115
摘要： A nonaqueous electrolyte secondary battery with excellent charging/discharging cycle characteristics is provided, more specifically a nonaqueous electrolyte secondary battery in which deterioration of the conductivity of a negative electrode due to charging/discharging cycle is suppressed and a method for manufacturing the same are provided. The nonaqueous electrolyte secondary battery includes: a positive electrode and a negative electrode that are capable of reversibly absorbing and desorbing Li ions; and a nonaqueous electrolyte having lithium ion conductivity. The negative electrode includes a collector and active material particles that are disposed on a surface of the collector. The active material particles include Si and at least one element R selected from the group consisting of Sn, In, Ga, Pb and Bi. Metallic bond including the element R is formed between the active material particles.
摘要翻译： 具有优良的充电非水电解质二次电池/放电循环特性被提供，更具体地非水电解质二次电池在负电极的导电性的哪恶化由于充电/放电周期被抑制，并且用于制造被设置在同一方法。 非水电解质二次电池包括：一个正电极和一个负电极确实是能够可逆地吸收和解吸Li离子; 和具有锂离子传导性的非水电解质。 负极包括集电体和活性物质粒子也被集电体的表面上地设置。 活性物质粒子包括Si和选自锡，金属键包括R的活性物质粒子的In，Ga，Pb和Bi之间形成的元件的选择的至少一种元素R ..
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3.发明公开NON-AQUEOUS ELECTROLYTE SECONDARY CELL AND MATERIAL FOR NEGATIVE PLATE USED THEREFOR 有权WIEDERAUFLADBARE BATTERIE MITNICHTWÄSSRIGEMELEKTROLYTEN UND MATERIALFÜRDIE NEGATIVE ELEKTRODE
公开(公告)号：EP1096583A1
公开(公告)日：2001-05-02
申请号：EP00902001.7
申请日：2000-01-31
CPC分类号： H01M4/46 , H01M4/134 , H01M4/38 , H01M4/386 , H01M10/052 , H01M10/0565
摘要： In cycles of charging and discharging, an excellent capacity maintenance rate is obtained. The charging and discharging cycle characteristic of battery is enhanced. Further, an excellent initial discharging capacity is obtained. A negative electrode, a positive electrode, and a non-aqueous electrolyte are contained. The negative electrode includes an alloy of Si, a first element and a second element. The first element includes at least one element selected from the group consisting of the second group element except Mg in the periodic table, transition elements, twelfth group element, thirteenth group element except B, and fourteenth group element except Si. The second element includes at least one element of B and Mg.
摘要翻译： 在充放电循环中，能够获得良好的容量维持率。 电池的充放电循环特性得到提高。 此外，获得了优异的初始放电容量。 包含负极，正极和非水电解质。 负极包括Si的合金，第一元素和第二元素。 第一元素包括选自周期表中除Mg以外的第二组元素，过渡元素，第十二组元素，除B以外的第十三组元素，以及Si以外的第十四组元素中的至少一种元素。 第二元素包括B和Mg中的至少一种元素。
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公开(公告)号：EP1052712A1
公开(公告)日：2000-11-15
申请号：EP99973175.5
申请日：1999-11-30
发明人： KASAMATSU, Shinji , YOSHIZAWA, Hiroshi , OKAMURA, Kazuhiro , KOSHINA, Hizuru , SHIMAMURA, Harunari , NITTA, Yoshiaki
CPC分类号： H01M4/38 , H01M4/04 , H01M4/13 , H01M4/364 , H01M4/366 , H01M4/386 , H01M4/387 , H01M4/485 , H01M4/58 , H01M4/5835 , H01M6/10 , H01M10/0525 , H01M10/446 , H01M2010/4292
摘要： The present invention relates to non-aqueous electrolyte secondary batteries comprising an positive electrode and a negative electrode capable of intercalating and de-intercalating lithium, a non-aqueous electrolyte and separators or solid electrolytes. The negative electrode contains, as a main component , composite particles constructed in such a manner that at least part of the surface of nuclear particles comprising at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound composed of the element included in the nuclear particles and another predetermined element which is not an element included in the nuclear particles. To improve the ability of the battery, the composite particles mentioned above can include at least one trace element selected from iron, lead and bismuth. The porosity of a mixture layer at the negative electrode is 10% or more and 50% or less. The amount of the non-aqueous electrolyte, the thickness of the separators or the like is restricted in a specific value. The foregoing construction suppresses occurrence of an internal short circuit between the positive electrode and the negative electrode caused by expansion of the negative electrode materials , thereby achieving a high capacity battery with a superior charge/discharge cycle properties, which is suitable for a high-speed charging.
摘要翻译： 本发明涉及非水电解质二次电池，该非水电解质二次电池包括能够插入和脱嵌锂的正极和负极，非水电解质和隔膜或固体电解质。 作为主要成分的负极以作为构成元素的锡，硅，锌中的至少一种的核粒子的至少一部分的表面的固溶体或 包含在核粒子中的元素构成的金属间化合物和不包含在核粒子中的元素的另一规定元素。 为了提高电池的能力，上述复合颗粒可以包括至少一种选自铁，铅和铋的痕量元素。 负极上的混合层的孔隙率为10％以上且50％以下。 非水电解质的量，分离器的厚度等被限制在特定值。 上述结构抑制由负极材料的膨胀引起的正极和负极之间的内部短路的发生，从而实现具有优异的充放电循环特性的高容量电池，适用于高速 充电。
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公开(公告)号：EP1052711A1
公开(公告)日：2000-11-15
申请号：EP99973174.8
申请日：1999-11-30
CPC分类号： H01M4/366 , H01M2/0275 , H01M4/134 , H01M4/38 , H01M4/386 , H01M4/387 , H01M6/181 , H01M10/052 , H01M10/0562 , H01M10/0565 , H01M2300/0085
摘要： The present invention relates to non-aqueous electrolyte secondary batteries. The negative electrode contains, as main a component, composite particles constructed in such a manner that at least part of the surface of nuclear particles comprising at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound composed of elements included in the nuclear particle and at least one element , exclusive of the element included in said nuclear particle, selected from a group of elements in a Periodic Table, comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements exclusive of carbon. The batteries of the present invention include non-aqueous electrolytic solution and solid electrolytes comprising polymer gel electrolytes. The construction of the present invention provides a non-aqueous electrolytic secondary battery with which a possibility of the generation of gas is extremely low when stored at high temperatures. It also provides a battery having higher capacity, and superior cycle properties, high-rate charge/discharge properties.
摘要翻译： 本发明涉及非水电解质二次电池。 负极含有作为主要组分的复合颗粒，所述复合颗粒以这样的方式构造，使得包含锡，硅和锌中的至少一种作为构成元素的核颗粒的至少部分表面涂覆有固溶体或 由核颗粒中包含的元素和至少一种元素构成的金属间化合物，除了所述核颗粒中包含的元素以外，所述元素选自元素周期表中包含第2族元素，过渡元素，第12族元素 ，不含碳的13族元素和14族元素。 本发明的电池包括非水电解液和包含聚合物凝胶电解质的固体电解质。 本发明的结构提供了一种非水电解二次电池，其在高温下储存时产生气体的可能性非常低。 它还提供具有更高容量和优异的循环特性，高速率充电/放电特性的电池。
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6.发明公开NEGATIVE ELECTRODE MATERIAL FOR NONAQUEOUS ELECTRODE SECONDARY BATTERY AND METHOD FOR PRODUCING THE SAME 审中-公开负极材料作为电极的非水，二次电池及其制造方法THE SAME
公开(公告)号：EP1028476A1
公开(公告)日：2000-08-16
申请号：EP99940637.4
申请日：1999-09-03
发明人： KAMINAKA, Hideya , ABE, Masaru , NEGI, Noriyuki , NITTA, Yoshiaki , SHIMAMURA, Harunari , OKAMURA, Kazuhiro
CPC分类号： H01M4/58 , B22F2009/041 , B22F2998/00 , H01M4/02 , H01M4/0454 , H01M4/13 , H01M4/133 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/383 , H01M4/583 , H01M2004/8684 , H01M2300/0017 , H01M2300/0082 , H01M2300/0085 , Y10T29/49108 , B22F9/008 , B22F9/04
摘要： A negative electrode material for a nonaqueous electrolyte secondary battery having a high discharge capacity and a good cycle life is made from alloy particles having an average particle diameter of 0.1 - 50 µm and including Si phase grains 40 and a phase of a solid solution or an intermetallic compound of Si and other element selected from Group 2A elements, transition elements, Group 3B elements, and Group 4B elements from the long form periodic table (for example, an NiSi 2 phase 42 and an [NiSi 2 + NiSi] phase 41) at least partially enveloping the Si phase grains. 5-99 wt% of this material is Si phase grains. The alloy particles can be manufactured by rapid solidification (such as atomization or roller quenching) of a melt including Si and the other element or by adhering the other element to Si powder by electroless plating or mechanical alloying and then performing heat treatment. Even if rapid solidification is carried out, a negative electrode material having a good discharge capacity and cycle life is obtained without heat treatment.
摘要翻译： 50微米，并且包括Si相的晶粒40和固体溶液的相位或 - 用于具有高的放电容量和良好的循环寿命的非水电解质二次电池用负极材料是由具有上0.1的平均粒径的合金粒子制成 在从2A族元素，过渡元素，3B族元素，和4B族元素从长周期型周期表（例如，在NiSi2相42和ÄNiSi2+NiSiÜ阶段41）中选择Si和其他元素的金属间化合物至少部分地 包围Si相颗粒。 这种材料的5-99重量％是Si相颗粒。 合金粒子可通过快速凝固来制造（：如雾化或辊淬火）熔体包含Si和其他元件，或者由通过非电解镀或机械合金化秉承另一元件与Si粉末，然后进行热处理的。 即使快速凝固中进行时，具有良好的放电容量和循环寿命的负极材料获得无热处理。
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7.发明公开CATHODE MATERIAL AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY USING IT 审中-公开SEKUNDÄRBATTERIEMIT WASSERFREIEM ELEKTROLYT DAMIT的KATHODENMATERIAL
公开(公告)号：EP1487037A1
公开(公告)日：2004-12-15
申请号：EP03708654.3
申请日：2003-03-17
CPC分类号： H01M4/134 , H01M4/131 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M10/052 , H01M10/0587
摘要： The present invention relates to a negative electrode material for non-aqueous electrolyte secondary batteries, characterized in that the negative electrode material comprises a composite particle including solid phases A and B, the solid phase A being dispersed in the solid phase B, and the ratio (I A /I B ) of the maximum diffracted X-ray intensity (I A ) attributed to the solid phase A to the maximum diffracted X-ray intensity (I B ) attributed to the solid phase B satisfies 0.001 ≦ I A /I B ≦ 0.1, in terms of a diffraction line obtained by a wide-angle X-ray diffraction measurement of the composite particle.
This negative electrode material is capable of suppressing of pulverization thereof due to repeated cycles. Further, the use of this negative electrode material allows production of a non-aqueous electrolyte secondary battery having a high capacity and an excellent cycle life characteristic.摘要翻译： 非水电解质二次电池用负极材料技术领域本发明涉及一种非水电解质二次电池用负极材料，其特征在于，所述负极材料包括固相A和B的复合粒子，固相A分散在固相B中， 归因于固相A的归属于固相B的最大衍射X射线强度（IB）的最大衍射X射线强度（IA）的IA（IB / IB）满足0.001
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公开(公告)号：EP1109239A1
公开(公告)日：2001-06-20
申请号：EP00917330.3
申请日：2000-04-18
摘要： A non-aqueous electrolyte secondary battery using composite particles for its negative electrode. In the composite particles , nucleus particles including at least one element selected from tin, silicon, and zinc as their constituent element are entirely or partly covered with a solid solution or inter-metallic compound of said constituent element and at least one element selected from groups consisting of Group 2 elements, transition elements, and Group 12, Group 13, and Group 14 elements in the Periodic Table except for the constituent element of the nucleus particles and carbon. Further, the present invention is characterized in that the NMR signals of the lithium intercalated in the composite particles appear within the range of -10 to 40 ppm with respect to lithium chloride and at least one signal appears within the range of -10 to 4 ppm .
摘要翻译： 使用复合粒子作为负极的非水电解质二次电池。 在复合粒子中，包含选自锡，硅和锌中的至少一种元素作为其组成元素的核粒子全部或部分地被所述构成元素的固溶体或金属间化合物以及选自组中的至少一种元素 元素周期表中的第2族元素，过渡元素和第12族，第13族和第14族元素组成，除了核颗粒和碳的组成元素之外。 此外，本发明的特征在于，嵌入复合颗粒中的锂的NMR信号相对于氯化锂出现在-10至40ppm的范围内，并且至少一个信号出现在-10至4ppm的范围内 。
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9.发明授权
公开(公告)号：EP1052713B1
公开(公告)日：2008-05-28
申请号：EP99973176.3
申请日：1999-11-30
CPC分类号： H01M4/134 , H01M4/02 , H01M4/131 , H01M4/362 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/42 , H01M10/052 , H01M10/44 , H01M2004/027
摘要： A non-aqueous electrolyte secondary cell is characterized in that the negative plate is made chiefly of composite particles of which at least part of the core particles containing at least one kind among tin, silicon, and zinc as a constituent element are coated with a solid solution or an intermetallic compound consisting of the constituent element constituting the core particles and at least one element selected from the group consisting of Group 2 elements of the periodic table except the constituent element, transition elements, Group 12 elements, Group 13 elements, and Group 14 elements except carbon and in that the content of lithium in the core particles of the composite particles lies in the range from 50 element% to 90 element% of the theoretical limit of the lithium content. The secondary cell is further characterized in that it is charged with, first, a constant current and then with a low voltage after the voltage reaches a preset voltage, and the current density in charging is controlled. Therefore, the non-aqueous electrolyte secondary cell has a high energy density, and excellent cycle life characteristics.
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10.发明公开OXYGEN-PERMEABLE FILM, OXYGEN-PERMEABLE SHEET AND ELECTRIC CELL COMPRISING THE SAME 有权SAUERSTOFFDURCHLÄSSIGERFILM，SAUERSTOFFDURCHLÄSSIGEFOLIE UND ELEKTRISCHE ZELLE DAMIT
公开(公告)号：EP1785184A1
公开(公告)日：2007-05-16
申请号：EP05770368.8
申请日：2005-08-09
CPC分类号： H01M4/8605 , H01M8/0239 , H01M8/0245 , H01M8/04171 , H01M8/10 , H01M12/06 , Y02E60/50 , Y10T428/24331 , Y10T428/249953 , Y10T428/249981 , Y10T428/25 , Y10T428/254 , Y10T442/10 , Y10T442/60
摘要： An oxygen permeable film including an aggregate of water-repellent particles and having an average particle size of the particles of 0.01 to 50 µm has a contact angle with water of not less than 120° and super water repellency, and therefore has an excellent water vapor permeation inhibiting capability. As the particles, fluorocarbon resins such as polytetrafluoroethylene, polyvinyl fluoride and polyvinylidene fluoride are suitable. The specific surface area of the oxygen permeable film is preferably not less than 0.1 m 2 /g and not more than 500 m 2 /g.
摘要翻译： 具有0.01〜50μm的平均颗粒尺寸的疏水性颗粒聚集体的透氧膜与水的接触角不小于120，具有超疏水性，因此具有优异的水蒸汽渗透性 抑制能力。 作为颗粒，可以使用聚四氟乙烯，聚氟乙烯，聚偏氟乙烯等氟碳树脂。 透氧膜的比表面积优选为0.1m 2 / g以上500m 2 / g以下。
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