摘要:
The present invention is to provide a means capable of realizing sufficient cycle durability while sufficiently taking advantage of the high capacity characteristics which are a feature of a solid-solution positive electrode active material in an electric device such as a lithium ion secondary battery having a positive electrode using a solid-solution positive electrode active material. In an electric device having a power generating element including a positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on the surface of a positive electrode current collector, a negative electrode in which a negative electrode active material layer containing a negative electrode active material is formed on the surface of a negative electrode current collector, and a separator, the negative electrode active material layer contains a negative electrode active material represented by Formula (1), the positive electrode active material layer contains a positive electrode active material (solid-solution positive electrode active material) represented by Formula (2), and, at this time, one that has a structure in which a silicide phase containing a silicide of a transition metal is dispersed in a parent phase containing amorphous or low crystalline silicon as a main component, a predetermined composition, and a ratio value (B/A) of a diffraction peak intensity B of a silicide of a transition metal in a range of 2θ = 37 to 45° to a diffraction peak intensity A of a (111) plane of Si in a range of 2θ = 24 to 33° in a predetermined range in an X-ray diffraction measurement using a CuKα1 ray is used as a Si-containing alloy contained in the negative electrode active material layer and a solid solution having a predetermined composition or an oxide-coated solid solution in which a coating layer containing an oxide in a predetermined amount is formed on the particle surface of the solid solution is used as a solid-solution positive electrode active material contained in the positive electrode active material layer.
摘要:
[TECHNICAL PROBLEM] To provide a negative electrode for an electrical device such as a Li ion secondary battery that has a high initial capacity and exhibits good balance characteristics while maintaining high cycle characteristics. [SOLUTION TO PROBLEM] A negative electrode for an electrical device includes: a current collector; and an electrode layer containing a negative electrode active material, an electrically-conductive auxiliary agent and a binder, wherein the negative electrode active material contains an alloy represented by a following formula (1): Si x Sn y M z A a (where M is M is at least one metal selected from the group consisting of Al, V, C and combinations thereof, A is inevitable impurity, and x, y, z and a are values of mass%, where 0
摘要:
[TECHNICAL PROBLEM] There is provided a negative electrode for an electric device such as a Li ion secondary battery capable of exhibiting well-balanced characteristics of a high cycle property and a high initial capacity. [SOLUTION TO PROBLEM] The negative electrode for an electric device includes a current collector and an electrode layer containing a negative electrode active material, a conductive auxiliary agent and a binder and formed on a surface of the current collector, wherein the negative electrode active material contains an alloy represented by the following formula (1): Si x Sn y M z A a (in the formula (1), M is at least one metal selected from the group consisting of Al, V, C and a combination thereof, A is inevitable impurities, and x, y, z and a represent mass percent values and satisfy the conditions of 0
摘要:
The negative electrode active material for an electric device of the present invention has an alloy containing Si in a range from 12% by mass or more to less than 100% by mass, Sn in a range from more than 0% by mass to 45% by mass or less, Al in a range from more than 0% by mass to 43% by mass or less, and indispensable impurities as remains. The negative electrode active material can be obtained, for example, using a multiple DC magnetron sputtering apparatus with Si, Sn and Al as targets. Electric devices to which the negative electrode active material of the present invention is applied have an improved cycle life and are excellent in the capacity and cycle durability.
摘要:
A negative electrode active material for an electric device includes an alloy containing silicon in a range from 27% by mass to 100% by mass exclusive, aluminum in a range from 0% by mass to 73% by mass exclusive, niobium in a range from 0% by mass to 58% by mass exclusive, and inevitable impurities as a residue. The negative electrode active material can be obtained with a multi DC magnetron sputtering apparatus by use of, for example, silicon, aluminum and niobium as targets. An electric device using the negative electrode active material can achieve a high cycle property while keeping a high discharge property
摘要:
To provide a means capable of improving the cycle durability of an electrical device such as a lithium ion secondary battery. A negative electrode active material containing a Si-containing alloy having a composition to be represented by Chemical Formula (1) : Si x Sn y M z Al w A a (in Chemical Formula (1) above, M is one or two or more transition metal elements, A is an unavoidable impurity, and x, y, z, w, and a represent values of percentage by mass, where y, z, and w are 2 ≤ y ≤ 10, 25 ≤ z ≤ 35, and 0.3 ≤ w ≤ 3, respectively, and x and a are remainder) is used in an electrical device.