METHOD FOR PRODUCING TRICHLOROSILANE
    12.
    发明公开
    METHOD FOR PRODUCING TRICHLOROSILANE 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON TRICHLOROSILAN

    公开(公告)号:EP2957543A1

    公开(公告)日:2015-12-23

    申请号:EP14752073.8

    申请日:2014-01-15

    IPC分类号: C01B33/107 B01J31/08

    摘要: In order to produce high-purity trichlorosilane by removing methyldichlorosilane from a mixture (S) containing methyldichlorosilane (CH 3 HSiCl 2 ), tetrachlorosilane (SiCl 4 ), and trichlorosilane (HSiCl 3 ) in the method for producing trichlorosilane of the present invention, a procedure is employed in which chlorine atoms are redistributed between methyldichlorosilane and tetrachlorosilane through catalytic treatment for conversion into trichlorosilane and methyltrichlorosilane (CH 3 SiCl 3 ). Methyldichlorosilane (boiling point: 41 °C) having a boiling point close to that of trichlorosilane (boiling point: 32°C) to be purified is converted into methyltrichlorosilane (boiling point: 66°C) having a higher boiling point through redistribution of chlorine atoms between methyldichlorosilane and tetrachlorosilane, achieving easy removal of impurities.

    摘要翻译: 为了通过在本发明的三氯硅烷的制造方法中从含有甲基二氯硅烷(CH 3 HSiCl 2),四氯硅烷(SiCl 4)和三氯硅烷(HSiCl 3)的混合物(S)中除去甲基二氯硅烷来生产高纯度三氯硅烷, 通过催化处理将氯原子重新分配在甲基二氯硅烷和四氯硅烷之间,转化为三氯硅烷和甲基三氯硅烷(CH 3 SiCl 3)的方法。 待纯化的沸点接近于三氯硅烷(沸点32℃)的甲基二氯硅烷(沸点41℃)通过再分配氯转化成沸点较高的甲基三氯硅烷(沸点:66℃) 甲基二氯硅烷和四氯硅烷之间的原子,实现了杂质的清除。