公开(公告)号：EP1325774B1

公开(公告)日：2013-11-06

申请号：EP01963511.9

申请日：2001-09-07

申请人： Nippon Steel & Sumitomo Metal Corporation

发明人： ITO, Wataru ,  SAKON, Tadashi ,  DOHNOMAE, Hitoshi ,  NAGAI, Toru

IPC分类号： B01D71/02 ,  B01J8/00 ,  B01J12/00 ,  B01J19/02 ,  C01B13/02 ,  C01G51/00 ,  H01M8/02 ,  B01D53/22 ,  B01D63/02 ,  B01D67/00 ,  B01J19/24 ,  B01J19/00

CPC分类号： H01M8/0282 ,  B01D53/22 ,  B01D63/02 ,  B01D67/0046 ,  B01D71/02 ,  B01D71/024 ,  B01D2313/38 ,  B01D2313/42 ,  B01D2323/08 ,  B01D2323/12 ,  B01D2325/04 ,  B01J8/009 ,  B01J12/007 ,  B01J19/0073 ,  B01J19/02 ,  B01J19/2475 ,  B01J2219/0218 ,  B01J2219/0236 ,  C01B13/0255 ,  C01B2210/0046 ,  C01G51/006 ,  C01G51/44 ,  C01G51/66 ,  C01G51/68 ,  C01P2002/34 ,  C01P2006/40 ,  H01M8/0271 ,  H01M2008/1293 ,  Y02P20/149 ,  Y10T428/24174 ,  Y10T428/24322 ,  Y10T428/24331 ,  Y10T428/2462 ,  Y10T428/249997

公开(公告)号：EP1580826A2

公开(公告)日：2005-09-28

申请号：EP05007855.9

申请日：1998-06-30

申请人： MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

发明人： Kawano, Tomoko ,  Kobayashi, Shigeo ,  Watanabe, Shoichiro ,  Fujiwara, Takafumi ,  Hashimoto, Akira ,  Syoji, Yasuhiko

IPC分类号： H01M4/58 ,  H01M4/04 ,  H01M4/02 ,  H01M10/40 ,  C01G51/00 ,  C01G55/00

CPC分类号： H01M4/485 ,  C01G51/42 ,  C01G51/44 ,  C01G53/00 ,  C01G53/42 ,  C01G53/44 ,  C01G55/002 ,  C01P2004/32 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0587

摘要： Lithium composite metal oxides prepared by mixing two or more hydroxides of different types of metal selected from the group of nickel, cobalt, manganese and aluminum and a lithium compound of which the D50 value is in the range 5 to 50 µm, the D90 value is 90 µm or smaller, and in which particles 100 µm or greater in particle size do not exist, followed by calcinating in the temperature range 700 to 1000°C and for 2 to 30 hours, and grinding, are used as the active materials of a positive electrode which is laminated with a negative electrode with a separator interposed and spirally wound thereby forming an electrode group. By using the positive active materials prepared in this manner, discharge capacity and cycle characteristic of a non-aqueous electrolyte secondary cell can be improved.

摘要翻译： 通过混合选自镍，钴，锰和铝和锂化合物的D50值的范围是从5至50微米的选择的不同类型的金属的两种或多种的氢氧化物制备锂复合金属氧化物，该D90值是 90微米或更小，并且其中在颗粒尺寸颗粒100微米或更大是不存在的，其次是在温度范围内煅烧700〜1000℃，进行2〜30小时，并研磨，被用作一个活性材料 正极所有被层压带分离器插入并螺旋卷绕从而在电极组形成负极。 通过使用以这种方式，放电容量和非水电解质二次电池的循环特性中制备的正极活性材料可以被改善。

公开(公告)号：EP1497876A1

公开(公告)日：2005-01-19

申请号：EP03717762.3

申请日：2003-04-22

申请人： LG Chem Ltd.

发明人： Park, Hong-Kyu ,  Kwon, Yong Hoon ,  Park, Seong Yong ,  Kim, Jin On ,  Lee, Ki Young

IPC分类号： H01M4/58

CPC分类号： H01M10/0525 ,  C01G51/42 ,  C01G51/44 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/02 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/88 ,  C01P2004/84 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/366 ,  H01M4/525 ,  H01M4/62 ,  Y10T428/2982 ,  Y10T428/2991

摘要： This invention relates to complex lithium metal oxides, which are cathode active materials of a lithium or lithium ion secondary battery with enhanced cycle life and safety, and a process for preparation thereof. The core particles are complex lithium metal oxides capable of absorbing, storing and emitting lithium ions, and a coating layer comprised of amorphous complex lithium cobalt oxides that are formed on the surface of the core particle, which is structurally stable and inactive with electrolytes. Because the amorphous complex lithium cobalt oxides are inactive with electrolytes, the oxides stabilize the surface structure of the complex lithium metal oxide and improve on high temperature storage properties, as well as safety and cycle life.

公开(公告)号：EP0929111A4

公开(公告)日：2004-06-02

申请号：EP98929778

申请日：1998-06-30

申请人： MATSUSHITA ELECTRIC IND CO LTD

发明人： KAWANO TOMOKO ,  KOBAYASHI SHIGEO ,  WATANABE SHOICHIRO ,  FUJIWARA TAKAFUMI ,  HASHIMOTO AKIRA ,  SYOJI YASUHIKO

IPC分类号： H01M10/05 ,  C01B31/04 ,  C01G51/00 ,  C01G55/00 ,  H01M4/02 ,  H01M4/04 ,  H01M4/131 ,  H01M4/133 ,  H01M4/36 ,  H01M4/48 ,  H01M4/485 ,  H01M4/50 ,  H01M4/505 ,  H01M4/52 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0587 ,  H01M10/36 ,  H01M4/58 ,  C01G53/00 ,  H01M10/40

CPC分类号： H01M4/485 ,  C01G51/42 ,  C01G51/44 ,  C01G53/00 ,  C01G53/42 ,  C01G53/44 ,  C01G55/002 ,  C01P2004/32 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0587

公开(公告)号：EP1211741A2

公开(公告)日：2002-06-05

申请号：EP01309960.1

申请日：2001-11-28

申请人： Toda Kogyo Corporation

发明人： Maeda, Hideaki ,  Fujino, Shoichi ,  Hatatani, Mitsuaki ,  Watanabe, Hiroyasu ,  Sugiyama, Norimiki ,  Sadamura, Hideaki

IPC分类号： H01M4/52

CPC分类号： C01G45/1228 ,  B82Y30/00 ,  C01G51/44 ,  C01G51/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01M4/02 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/028

摘要： A cathode active material for a non-aqueous electrolyte secondary cell of the present invention, having a c-axis length of lattice constant of 14.080 to 14.160 Å, an average particle size of 0.1 to 5.0 µm, and a composition represented by the formula:

        LiCo (1-x-y) Mn x Mg y O 2

wherein x is a number of 0.008 to 0.18; and y is a number of 0 to 0.18.

摘要翻译： 的正极活性物质用于本发明的非水电解质二次电池，其具有14.080晶格常数的c轴长到14.160埃，至0.1平均颗粒尺寸为5.0微米，和由下式表示的组合物 ：的LiCo（1-XY）MnxMgyO2 worin x是一个数的0.008至0:18; 和y为0〜12点十八。

公开(公告)号：EP2660907A4

公开(公告)日：2016-12-21

申请号：EP11852696

申请日：2011-12-27

申请人： GS YUASA INT LTD

发明人： ENDO DAISUKE ,  KATAYAMA YOSHIHIRO ,  MURAI TETSUYA ,  SHIBATA MASAFUMI

IPC分类号： H01M4/525 ,  C01G53/00 ,  H01B1/08 ,  H01M4/505 ,  H01M10/052 ,  H01M10/44

CPC分类号： H01M4/505 ,  C01G45/1221 ,  C01G45/1228 ,  C01G51/44 ,  C01G51/50 ,  C01G53/44 ,  C01G53/50 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01B1/08 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： An object of the present invention is to provide a positive active material for a nonaqueous electrolyte secondary battery which has a large discharge capacity and is superior in charge-discharge cycle performance, initial efficiency and high rate discharge performance, and a nonaqueous electrolyte secondary battery using the positive active material. The present invention pertains to a positive active material for a nonaqueous electrolyte secondary battery containing a lithium transition metal composite oxide which has a crystal structure of an ±-NaFeO 2 type, is represented by a compositional formula Li 1+± Me 1-± O 2 (Me is a transition metal element including Co, Ni and Mn, ± > 0), and has a molar ratio Li/Me of Li to the transition metal element Me of 1.2 to 1.6, wherein a molar ratio Co/Me of Co in the transition metal element Me is 0.02 to 0.23, a molar ratio Mn/Me of Mn in the transition metal element Me is 0.62 to 0.72, and the lithium transition metal composite oxide is observed as a single phase attributed to a space group R3-m on an X-ray diffraction chart when it is electrochemically oxidized up to a potential of 5.0 V (vs. Li/Li + ).

摘要翻译： 本发明的一个目的是提供一种用于具有大的放电容量和在充放电循环性能，初始效率和高速率放电性能优良的非水电解质二次电池提供正极活性材料，和一种非水电解质二次电池用 的正极活性物质。 键入本发明涉及的正极活性物质为含有具有一个-NaFeO±2的晶体结构的锂过渡金属复合氧化物的非水电解质二次电池中，由组成式Li 1 +±1±我0所表示 2（Me为过渡金属元素含有Co，Ni和Mn，±> 0），并且具有的摩尔比锂/ Me的Li与过渡金属元素的1.2〜1.6 Me中，worin的摩尔比Co / Me的钴的 在过渡金属元素Me为12:02到12点23分，摩尔比的Mn / Me的Mn的过渡金属元素Me为0.62〜0.72，和锂过渡金属复合氧化物中观察到，作为归属于空间群R3的单相 到的X射线衍射图表米当电化学氧化高达5.0 V（相对于Li / Li +）的电位。

公开(公告)号：EP2660907A1

公开(公告)日：2013-11-06

申请号：EP11852696.1

申请日：2011-12-27

申请人： GS Yuasa International Ltd.

发明人： ENDO, Daisuke ,  KATAYAMA , Yoshihiro ,  MURAI , Tetsuya ,  SHIBATA, Masafumi

IPC分类号： H01M4/525 ,  C01G53/00 ,  H01M4/505 ,  H01M10/052 ,  H01M10/058 ,  H01M10/44

CPC分类号： H01M4/505 ,  C01G45/1221 ,  C01G45/1228 ,  C01G51/44 ,  C01G51/50 ,  C01G53/44 ,  C01G53/50 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01B1/08 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： An object of the present invention is to provide a positive active material for a nonaqueous electrolyte secondary battery which has a large discharge capacity and is superior in charge-discharge cycle performance, initial efficiency and high rate discharge performance, and a nonaqueous electrolyte secondary battery using the positive active material. The present invention pertains to a positive active material for a nonaqueous electrolyte secondary battery containing a lithium transition metal composite oxide which has a crystal structure of an α-NaFeO 2 type, is represented by a compositional formula Li 1+α Me 1-α O 2 (Me is a transition metal element including Co, Ni and Mn, α > 0), and has a molar ratio Li/Me of Li to the transition metal element Me of 1.2 to 1.6, wherein a molar ratio Co/Me of Co in the transition metal element Me is 0.02 to 0.23, a molar ratio Mn/Me of Mn in the transition metal element Me is 0.62 to 0.72, and the lithium transition metal composite oxide is observed as a single phase attributed to a space group R3-m on an X-ray diffraction chart when it is electrochemically oxidized up to a potential of 5.0 V (vs. Li/Li + ).

公开(公告)号：EP2260129A4

公开(公告)日：2011-12-21

申请号：EP08715127

申请日：2008-02-29

申请人： BYD CO LTD

发明人： CHENG TANGLI ,  HE LONG ,  JIANG ZHANFENG ,  TIAN YE ,  LIU JUNFENG

IPC分类号： H01M4/58 ,  C01B25/45 ,  C01G23/00 ,  C01G25/00 ,  C01G31/00 ,  C01G45/00 ,  C01G49/00 ,  C01G51/00 ,  C01G53/00 ,  H01M4/136 ,  H01M4/48 ,  H01M10/052 ,  H01M10/36

CPC分类号： C01B25/45 ,  C01G23/002 ,  C01G25/006 ,  C01G31/006 ,  C01G33/006 ,  C01G45/1221 ,  C01G49/009 ,  C01G51/44 ,  C01G53/44 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/136 ,  H01M4/364 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052

公开(公告)号：EP2260129A1

公开(公告)日：2010-12-15

申请号：EP08715127.0

申请日：2008-02-29

申请人： BYD Company Limited

发明人： CHENG, Tangli ,  HE, Long ,  JIANG, Zhanfeng ,  TIAN, Ye ,  LIU, Junfeng

IPC分类号： C30B29/22 ,  H01M4/58 ,  H01M4/48 ,  C01B25/45

CPC分类号： C01B25/45 ,  C01G23/002 ,  C01G25/006 ,  C01G31/006 ,  C01G33/006 ,  C01G45/1221 ,  C01G49/009 ,  C01G51/44 ,  C01G53/44 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/136 ,  H01M4/364 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052

摘要： Described is a composite lithium compound having a mixed crystalline structure. Such compound was formed by heating a lithium compound and a metal compound together. The resulting mixed metal crystal exhibits superior electrical property and is a better cathode material for lithium secondary batteries.

公开(公告)号：EP1580826A3

公开(公告)日：2010-11-03

申请号：EP05007855.9

申请日：1998-06-30

申请人： Panasonic Corporation

发明人： Kawano, Tomoko ,  Kobayashi, Shigeo ,  Watanabe, Shoichiro ,  Fujiwara, Takafumi ,  Hashimoto, Akira ,  Syoji, Yasuhiko

IPC分类号： H01M4/58 ,  H01M4/04 ,  H01M4/02 ,  H01M10/40 ,  C01G51/00 ,  C01G55/00

CPC分类号： H01M4/485 ,  C01G51/42 ,  C01G51/44 ,  C01G53/00 ,  C01G53/42 ,  C01G53/44 ,  C01G55/002 ,  C01P2004/32 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0587

摘要： Lithium composite metal oxides prepared by mixing two or more hydroxides of different types of metal selected from the group of nickel, cobalt, manganese and aluminum and a lithium compound of which the D50 value is in the range 5 to 50 µm, the D90 value is 90 µm or smaller, and in which particles 100 µm or greater in particle size do not exist, followed by calcinating in the temperature range 700 to 1000°C and for 2 to 30 hours, and grinding, are used as the active materials of a positive electrode which is laminated with a negative electrode with a separator interposed and spirally wound thereby forming an electrode group. By using the positive active materials prepared in this manner, discharge capacity and cycle characteristic of a non-aqueous electrolyte secondary cell can be improved.

摘要翻译： 通过混合选自镍，钴，锰和铝和锂化合物的D50值的范围是从5至50微米的选择的不同类型的金属的两种或多种的氢氧化物制备锂复合金属氧化物，该D90值是 90微米或更小，并且其中在颗粒尺寸颗粒100微米或更大是不存在的，其次是在温度范围内煅烧700〜1000℃，进行2〜30小时，并研磨，被用作一个活性材料 正极所有被层压带分离器插入并螺旋卷绕从而在电极组形成负极。 通过使用以这种方式，放电容量和非水电解质二次电池的循环特性中制备的正极活性材料可以被改善。