摘要:
[Object] There is provided an active material for a lithium secondary battery, which has a high initial efficiency and a high discharge capacity, and particularly has a high discharge capacity at a low temperature (excellent low-temperature characteristic), and a lithium secondary battery using the active material. [Solution] An active material for a lithium secondary battery, which contains a solid solution of a lithium transition metal composite oxide having an ±-NaFeO 2 crystal structure, wherein the composition ratio of metal elements contained in the solid solution satisfies, Li 1+x-y Na y Co a Ni b Mn c O 2+d (0
摘要:
An object of the present invention is to provide a positive active material for a nonaqueous electrolyte secondary battery which has a large discharge capacity and is superior in charge-discharge cycle performance, initial efficiency and high rate discharge performance, and a nonaqueous electrolyte secondary battery using the positive active material. The present invention pertains to a positive active material for a nonaqueous electrolyte secondary battery containing a lithium transition metal composite oxide which has a crystal structure of an ±-NaFeO 2 type, is represented by a compositional formula Li 1+± Me 1-± O 2 (Me is a transition metal element including Co, Ni and Mn, ± > 0), and has a molar ratio Li/Me of Li to the transition metal element Me of 1.2 to 1.6, wherein a molar ratio Co/Me of Co in the transition metal element Me is 0.02 to 0.23, a molar ratio Mn/Me of Mn in the transition metal element Me is 0.62 to 0.72, and the lithium transition metal composite oxide is observed as a single phase attributed to a space group R3-m on an X-ray diffraction chart when it is electrochemically oxidized up to a potential of 5.0 V (vs. Li/Li + ).
摘要:
It is an object of the present invention to provide an active material for a lithium secondary battery having high discharge capacity and excellent in high rate discharge characteristics and a lithium secondary battery using the same. The active material for a lithium secondary battery containing a solid solution of a lithium-transition metal composite oxide having an ±-NaFeO 2 type crystal structure and the lithium secondary battery using the same have features that the composition ratios of the metal elements contained in the solid solution satisfy Li 1 +( x/3 )Co 1-x-y-z Ni y/2 Mg z/2 Mn (2x/3)+(y/2)+(z/2) (x > 0; y > 0; z > 0; x + y + z