PROCESS FOR RECOVERY OF METAL VALUES FROM MATERIALS CONTAINING ARSENIC AND/OR ANTIMONY
    11.
    发明公开
    PROCESS FOR RECOVERY OF METAL VALUES FROM MATERIALS CONTAINING ARSENIC AND/OR ANTIMONY 审中-公开
    一种获得砷和/或含锑材料金属材料价值

    公开(公告)号:EP1937857A1

    公开(公告)日:2008-07-02

    申请号:EP06790403.7

    申请日:2006-10-19

    摘要: A method for the recovery of metal values from a metal value-bearing material containing arsenic and/or antimony and a source of sulphate ions such as sulphide ore or concentrate is disclosed. In one form the method comprises the steps of: (a) providing a feed stream comprising a metal value-bearing material containing arsenic and/or antimony and a source of sulphate ions; (b) subjecting the feed stream to oxidative conditions under elevated temperature and pressure conditions in the presence of at least one component selected to decrease the effective concentration of free acid generated during the pressure oxidation step and promote the formation of pH-stable iron (III) sulphate products, thereby forming a slurry comprising a metal value-containing leach solution and a solid leach residue containing pH-stable iron (III) sulphate products and environmentally stable iron-arsenic and/or iron-antimony products; (c) separating the metal value-containing leach solution from the solid leach residue; (d) recovering the metal value (s) from the metal value-containing leach solution; and (e) recovering precious metal values, if present, in the solid leach residue by cyanide leaching.

    EP0963451A4 -
    12.
    发明公开
    EP0963451A4 - 失效
    EP0963451A4 - Google专利

    公开(公告)号:EP0963451A4

    公开(公告)日:1999-12-15

    申请号:EP97926439

    申请日:1997-05-12

    摘要: A method is provided for the hydrometallurgical recovery of metal values from sources containing more than one metal of antimony, lead, copper, zinc, bismuth, tin, cadmium and other metals by leaching the metal containing source with a ferric fluoborate/fluroboric acid solution to provide a leachant metal containing solution. The leachant solution is contacted with specific organic extractants such as an organophosphoric acid ester, an alkyl salicylaldoxime and an amidobis(thiophosphoryl) compound in a series of extraction steps to separate metals based on the extractant used. The organic extractant solution is stripped of the extracted metal(s) and the metal(s) recovered. The remaining leach solution after extraction being either further treated to extract other metals or processed to provide metal values contained therein.

    摘要翻译: 提供了一种方法,用于通过用氟硼酸铁/氟硼酸溶液浸提含金属源来从含有多于一种锑,铅,铜,锌,铋,锡,镉和其它金属的金属的源的湿法冶金回收金属 提供包含浸出溶液的溶液。 在一系列萃取步骤中,浸出溶液与特定的有机萃取剂如有机磷酸酯,烷基水杨醛肟和酰胺基双(硫代磷酰基)化合物接触,以基于所用萃取剂分离金属。 将有机萃取剂溶液除去萃取的金属并回收金属。 提取后剩余的浸出溶液要么进一步处理以提取其他金属,要么进行处理以提供其中所含的金属价值。