摘要:
Methods relate to making lithium vanadium oxide powders. Applications for the lithium vanadium oxide powders include use as a negative electrode or anode material for lithium ion batteries. Liquid phase reactions and reduction in vanadium oxidation state of precursor material facilitate in the making of the lithium vanadium oxide powders. Particles forming the lithium vanadium oxide powders may further contain carbon to provide electrical conductivity.
摘要:
An electrochemically active material comprising a mixture or blend of two groups of particles, exhibits synergetic effect. The two groups of particles are compounds of formula Li x H y V 3 O 8 and compounds of formula Li x M y (AO z ) v O w wherein M is one or more transition metals, comprising at least one metal which is capable of undergoing oxidation to a higher valence state, and preferred (AO z ) are PO 4 3- , BO 3 3- , SO 4 2- or SiO 4 4- . In order to obtain a synergistic effect, the particles of formula (I) and the particles of formule (II) are present in amounts of 5 :95 % by weight to 95 : 5 % by weight.
摘要:
A new electroactive material of formula H 4 V 3 O 8 obtainable from H 2 V 3 O 8 is described as well as a method for its production, an electroactive cathode coating material comprising this electroactive material, a method for its production and cathodes as well as aqueous and non aqueous, rechargeable and non rechargeable batteries comprising such cathodes.
摘要翻译:描述了由H 2 V 3 O 8获得的新的式H 4 V 3 O 8电活性材料及其制备方法,包括该电活性材料的电活性阴极涂层材料,其制备方法和阴极 作为包含这种阴极的水性和非水性,可充电和非可再充电电池。
摘要:
The invention relates to a process for isolating vanadium as a vanadium compound from a solid composition comprising oxides and/or hydroxides of aluminium, oxides of vanadium and oxides of iron. The process comprises the following steps: (i) calcination of the solid composition, (ii) oxidation by means of salt roasting of the solid composition with an alkali compound to obtain a roasted composition, (iii) contacting the roasted composition with an aqueous solution wherein the pH of the aqueous solution when in contact with the roasted composition is between 7 and 10 to obtain an aqueous solution comprising soluble salts of vanadium oxides and a remaining solid composition, (iv) separating the aqueous solution comprising soluble salts of vanadium oxides and the remaining solid composition, (v) obtaining the vanadium compound or a precursor of the vanadium compound by precipitation of the vanadium oxides with a suitable cation and wherein the resulting precipitated solids are separated from the aqueous solution by means of filtration.
摘要:
The present invention relates to a method for the production of nanoparticulate metal(III) vanadates or vanadate/phosphate mixed crystals, comprising the reaction in a reaction medium of a reactive vanadate source and optionally a phosphate source dissolvable or dispersible in the reaction medium and of a reactive metal(III) salt dissolvable or dispersible in the reaction medium under heating, wherein the reaction medium contains water and a polyol in a volume ratio of 20/80 to 90/10, and the particles thereby obtained. The synthesis provides a high yield of metal(III) vanadate or vanadate/phosphate having a narrow particle size distribution. Doped embodiments thereof are distinguished by excellent luminescence properties.
摘要:
A metal recovery process, for heavy products from a hydroconversion process, containing unconverted residue and a solid carbonaceous material containing the group 8-10 metal, the group 6 metal, and vanadium and/or nickel, is provided by the invention. The recovery process comprises a thermal treatment step to convert the heavy products/residues into ash, a leaching of the ash to form supernatant containing vanadium and molybdenum in solution and a first solid containing carbonaceous material and undissolved metals (nickel, ...). The supernatant liquid is mixed with ammonium sulphate solution to produce a first precipitate containing the vanadium, and a further precipitation step to form a second precipitate containing the molybdenum.
摘要:
The present invention relates to iron-doped vanadium(V) oxides of formula FeyV2O5, a process for their preparation and their uses as positive electrodes, especially in microbattehes.