公开(公告)号：EP2022582A1

公开(公告)日：2009-02-11

申请号：EP07739304.9

申请日：2007-03-22

Applicant: OSAKA Titanium Technologies Co., Ltd.

Inventor： NISHIOKA, Kazuo ,  FUJITA, Makoto ,  ARIMOTO, Nobuhiro

IPC: B22F9/08 ,  C22C14/00 ,  C22C21/00

CPC classification number: C22C14/00 ,  B22F9/082 ,  B22F2009/043 ,  C22C1/06 ,  C22C21/00 ,  C22F1/183

Abstract: In production of a titanium alloy spherical powder by a gas atomizing method, the difference in alloy composition depending on the product particle size is reduced economically. To achieve this, sponge titanium particles and additive metal element particles are mixed by means of a mixer having a pulverizing function such as a ball mill. The mixed particles are compressed to form a rod-formed raw material for melting. The formed rod-formed raw material for melting is powderized by a gas atomizing method. In the mixing step, the additive metal element particles are pulverized, or ground depending on the kind of particles, and solidly adhered to the surface of the sponge titanium particles, so that uniform mixing is possible.

Abstract translation: 在通过气体雾化法制造钛合金球状粉末时，根据产品粒径的合金组成的差异经济地降低。 为了实现这一点，海绵钛颗粒和添加金属元素颗粒通过具有粉碎功能的混合器如球磨机混合。 将混合的颗粒压缩以形成用于熔化的棒状原料。 通过气体雾化法将成形的棒状熔融原料粉化。 在混合步骤中，添加金属元素颗粒根据颗粒的种类进行粉碎或研磨，并牢固地附着在海绵钛颗粒的表面上，从而可以均匀混合。

公开(公告)号：EP1443126B1

公开(公告)日：2008-05-07

申请号：EP02765557.0

申请日：2002-09-13

Applicant: OSAKA Titanium Technologies Co., Ltd.

Inventor： NISHIOKA, Kazuo

IPC: C23C14/24 ,  C01B33/113

CPC classification number: C23C14/24 ,  C23C14/10 ,  C23C14/225

Abstract: In a method for preparing a silicon monoxide vapor deposition material wherein a mixture of a silicon powder and a silicon dioxide powder is heated and reacted in a raw material chamber under vacuum to generate a silicon monoxide gas and silicon monoxide is precipitated on a precipitation substrate in a precipitation chamber provided above the raw material chamber, an improvement which comprises using, as the precipitation substrate, a cylindrical body wherein a circumference wall is inclined from the perpendicular by 1 to 45 degrees and the inner diameter of the upper end thereof is smaller than that of the lower end, and effecting the precipitation under a vacuum of 7 Pa to 40 Pa. The method allows the preparation of a silicon monoxide vapor deposition material exhibiting a weight reduction rate in the rattler test a rattler value of 1.0 % or less and being reduced in the occurrence of the splash phenomenon during the formation of a silicon monoxide vapor deposition film.

公开(公告)号：EP1908858A1

公开(公告)日：2008-04-09

申请号：EP06780718.0

申请日：2006-07-03

Applicant: OSAKA Titanium Technologies Co., Ltd. ,  International Manufacturing and Engineering Services Co., Ltd. ,  Kido, Junji

Inventor： NATSUME, Y., c/o Osaka Titanium technologies Co ltd ,  OGASAWARA, T, Osaka titanium technologies Co ltd ,  AZUMA, K., c/o Osaka titanium technologies Co ltd ,  MORI, K., Int. Manufact. & Eng. Services Co., Ltd.

IPC: C23C14/34

CPC classification number: C23C14/3414 ,  C23C14/08 ,  H01B1/08 ,  H01L51/5253 ,  H05B33/26

Abstract: Provided is a sputtering target which can give a high water barrier property and a high flexibility to a sputtering film, can keep a high film forming rate certainly in sputtering, and can make damages to an objective substance wherein a film is to be formed as small as possible. In order to realize this, a mixed powder which contains 20 to 80% by weight of a SiO powder, the balance of the powder being made of a TiO 2 powder and/or a Ti powder, is pressed and sintered. The sintered body has a composition of SiαTiβOγ wherein α, β and γ are mole ratios of Si, Ti and O, respectively, and the ratio of α/β ranges from 0.45 to 7.25 and the ratio of γ/(α + β) ranges from 0.80 to 1.70.

Abstract translation: 本发明提供一种溅射靶，可以给一个高水阻隔性和高的柔韧性，以溅射电影，可以在溅射当然保持高的成膜速度，并且可以使损伤在目标物质worin的膜被形成为小 成为可能。 为了实现这一点，其中含有20至80％（重量）的SiO粉末的混合粉末，该粉末的其余部分由TiO 2粉末和/或Ti粉末，被压制和烧结。 烧结体具有Si的组合物±Ti²O³worin±，²和³是分别因为Si，Ti和O，的摩尔比，和±的比率/²范围为0时45至7:25的比率³/（±+² ）为0.80至1.70。

公开(公告)号：EP4215484A1

公开(公告)日：2023-07-26

申请号：EP21869003.0

申请日：2021-07-13

Applicant: OSAKA Titanium Technologies Co., Ltd.

Inventor： KASHITANI, Yusuke

IPC: C01B33/113 ,  H01M4/48

Abstract: An object of the present invention is to provide a silicon monoxide gas generating raw material in which a reaction that generates a silicon monoxide (SiO) gas is hardly inhibited. The silicon monoxide gas generating raw material according to the present invention has a water content of 0.6 wt % or less.

公开(公告)号：EP2618407A1

公开(公告)日：2013-07-24

申请号：EP11832271.8

申请日：2011-10-07

Applicant: OSAKA Titanium Technologies Co., Ltd.

Inventor： YASUDA, Kouji ,  FUJITA, Takehisa ,  KIZAKI, Shingo ,  SHIMOSAKI, Shinji

IPC: H01M4/48 ,  H01G9/058 ,  H01M4/36

CPC classification number: H01M4/386 ,  H01G11/24 ,  H01G11/50 ,  H01M4/366 ,  H01M4/483 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/13

Abstract: In a lithium ion secondary battery using a negative electrode material powder including a lower silicon oxide powder as a negative electrode material, a charge electric potential at 0.45-1.0 V relative to a Li reference upon initial charging results in a lithium ion secondary battery having a large discharge capacity with excellent cycle characteristics, which can be durable in practical use. On this occasion, the charge electric potential being 0.45-1.0 V relative to the Li reference upon initial charging means that an electric potential plateau caused by the generation of Li-silicate is observed, and the Li-silicate is uniformly generated in the negative electrode material. The negative electrode material powder according to the present invention having the charge electric potential of 0.45-1.0 V relative to the Li reference upon initial charging prevents the negative electrode material from being finely torn apart upon charging/discharging which results in cycle characteristic degradation, and excellent cycle characteristics are obtained. It is preferable for the negative electrode material powder according to the present invention to have an electrically conductive carbon film on the surface, and for the ratio of the electrically conductive carbon film to the surface of the powder to be 0.2-10 mass %.

Abstract translation: 在使用负极材料粉末包括下部的氧化硅粉末作为负极材料，在0.45-1.0 V相的电荷电位在锂离子具有二次电池在初始充电的结果的锂基准的锂离子二次电池 放电容量大，具有优异的循环特性，可在实际使用耐用。 在这种情况下，充电电势是相对于在初始充电bedeutet锂参考0.45-1.0 V，DASS在由硅酸锂的生成引起的电位高原-观察到的，和硅酸锂在负电极均匀地产生 材料。 的负极材料粉末gemäß到本发明的具有相对于在初始充电时的锂参考0.45-1.0 V的电荷电位被精细地撕开时的充电/放电，这导致劣化的循环特性，防止负电极材料，以及 优异的循环特性得到。 优选的是，负极材料粉末gemäß到本发明的具有在导电的碳薄膜的表面，并为导电性碳电影到粉末的表面的比例为0.2〜10质量％。

公开(公告)号：EP2581970A1

公开(公告)日：2013-04-17

申请号：EP11795367.9

申请日：2011-06-03

Applicant: OSAKA Titanium Technologies Co., Ltd.

Inventor： YASUDA, Kouji ,  KIZAKI, Shingo ,  SHIMOSAKI, Shinji

IPC: H01M4/48 ,  H01G9/058 ,  H01M4/36

CPC classification number: H01M4/134 ,  H01G11/06 ,  H01G11/42 ,  H01G11/50 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/1395 ,  H01M4/36 ,  H01M4/38 ,  H01M10/052 ,  Y02E60/13

Abstract: Provided is a negative-electrode material powder used for a lithium-ion secondary battery having a large discharge capacity and sufficient cycle characteristics as being durable in use. The powder for the battery includes a conductive carbon film on a lower silicon oxide powder, surface and satisfies requirements that: Si in SiC is 15.1 wt% or less in content, or A3 (=A2-A1) is 15.1 or less, given A1 (wt%): Si content measured by acid solution process, and A2 (wt%): Si content measured by alkali solution process; and a specific resistance is 30,000 Ωcm or less. In the lower silicon oxide powder, a maximum value P1 of SiO x -derived halos appearing at 2θ=10° to 30° and a value P2 of the strongest line peak of Si (111) appearing at 2θ=28.4±0.3°, in XRD using CuKα beam, preferably satisfy P2/P1

Abstract translation: 提供的是用于具有大放电容量和足够的循环特性为在使用耐用的锂离子二次电池的负极材料粉末。 对于电池内的粉末包括在下部的氧化硅粉末，表面和SATIS外资企业要求的导电性碳电影的是：硅在SiC中是15.1％（重量）或更少的内容，或A3（= A2-A1）为1.15或更小，给出A1 （重量％）：Si含量由酸溶液处理测量，并且A2（重量％）：Si含量通过碱溶液处理的测量; 和比电阻为30,000©cm以下。 在较低的氧化硅粉末的SiO的极大值P1 X衍生的晕圈在2 = 10°露面至30°和Si中的2 = 28.4±0.3°亮相的最强线的峰（111）的值P2 在使用CuK±光束XRD，优选满足P2 / P1 <0.01。 焦油成分的含量优选为1ppm以上且4000 ppm以下。

公开(公告)号：EP2445038A1

公开(公告)日：2012-04-25

申请号：EP10789144.2

申请日：2010-04-21

Applicant: OSAKA Titanium Technologies Co., Ltd.

Inventor： KIZAKI, Shingo

IPC: H01M4/48 ,  C01B33/113 ,  H01M4/13

CPC classification number: H01M4/485 ,  C01B33/113 ,  H01M4/134 ,  H01M10/0525 ,  Y02E60/122

Abstract: Provided is a silicon oxide to be used for a negative electrode active material of a lithium-ion secondary battery, characterized in that : a g-value measured by an ESR spectrometer is in the range of not less than 2.0020 to not more than 2.0050; and given that A, B, and C are the area intensities of peaks near 420 cm -1 , 490 cm -1 and 520 cm -1 respectively in a Raman spectrum measured by a Raman spectroscopy, A/B is not less than 0.5 and C/B is not more than 2. The silicon oxide is used as a negative electrode active material, whereby a lithium-ion secondary battery having excellent cycle characteristic and initial efficiency in addition to high capacity can be obtained. The silicon oxide preferably has a spin density in the range of not less than 1×10 17 spins/g to not more than 5×10 19 spins/g. A negative electrode material for lithium-ion secondary battery contains not less than 20% by mass of this silicon oxide as a negative electrode active material.

Abstract translation: 提供一种用于锂离子二次电池的负极活性物质的氧化硅，其特征在于：由ESR光谱仪测定的g值在不小于2.0020〜2.0050的范围内; 并且A，B和C分别是通过拉曼光谱测量的拉曼光谱中分别在420cm -1，490cm -1和520cm -1附近的峰的面积强度，A / B不小于0.5， C / B为2以下。作为负极活性物质使用氧化硅，可以得到除了高容量以外，具有优异的循环特性和初期效率的锂离子二次电池。 氧化硅优选具有在不小于1×10 17自旋/ g至不大于5×10 19自旋/ g的范围内的自旋密度。 作为负极活性物质，作为锂离子二次电池用负极材料含有20质量％以上的氧化硅。

公开(公告)号：EP1795624B1

公开(公告)日：2012-04-25

申请号：EP05770381.1

申请日：2005-08-09

Applicant: OSAKA Titanium Technologies Co., Ltd.

Inventor： NISHIOKA, Kazuo ,  KIZAKI, Shingo

IPC: C23C14/24 ,  C01B33/037 ,  C01B33/113

CPC classification number: C01B33/113 ,  C23C14/10

Abstract: Disclosed is an SiO deposition material characterized by having a hydrogen gas content of not more than 50 ppm. By using such an SiO deposition material, occurrence of splash can be suppressed when SiO is deposited on a base, and there can be formed an SiO deposited film which is excellent in transparency and barrier properties. By carrying out degasification so that the hydrogen gas content of a raw material Si powder for the deposition material is not more than 10 ppm, the SiO deposition material having a hydrogen gas content of not more than 50 ppm can be produced highly efficiently at low cost. Consequently, this method for producing SiO can be widely applied to methods for producing deposition materials for packaging materials which have transparency and barrier properties and are used for foods, medical products, medicinal products and the like.

公开(公告)号：EP1683594B1

公开(公告)日：2009-10-07

申请号：EP06006787.3

申请日：2002-02-15

Applicant: OSAKA Titanium technologies Co., Ltd.

Inventor： Onishi, Takashi ,  Ogasawara, Tadashi ,  Watanabe, Munetoshi ,  Kato, Masamichi

IPC: B22F5/00 ,  B01D39/20 ,  B22F3/11

CPC classification number: H01M8/0232 ,  B01D39/2034 ,  B01D39/2079 ,  B01D2201/188 ,  B22F1/0048 ,  B22F3/004 ,  B22F3/10 ,  B22F3/11 ,  B22F3/1103 ,  B22F3/1109 ,  B22F2998/00 ,  B22F2998/10 ,  B22F2999/00 ,  H01M8/0247 ,  Y10T428/12014 ,  Y10T428/12021 ,  B22F9/082 ,  B22F2207/11 ,  B22F3/02

Abstract: Provided are a porous sintered compact suitable for a filter, a power feeder in a polymer electrolyte membrane type water electrolyzer, a current collector in a solid polymer fuel cell and in addition a liquid dispersion plate, especially an ink dispersion plate for an ink jet printer ink and the like. A titanium powder sintered compact made of a plate-like porous compact is obtained by sintering spherical powder made of titanium or a titanium alloy produced by means of a gas atomization method. A void ratio in the range of from 35 to 55% is realized by filling without applying a pressure and sintering without applying a pressure.

公开(公告)号：EP1995353A1

公开(公告)日：2008-11-26

申请号：EP07738118.4

申请日：2007-03-09

Applicant: OSAKA Titanium Technologies Co., Ltd.

Inventor： OGASAWARA, Tadashi ,  YAMAGUCHI, Makoto

IPC: C25C3/02 ,  C01F11/32 ,  C22B5/04 ,  C22B26/20 ,  C22B34/12 ,  C25B7/00 ,  C25C7/06

CPC classification number: C22B34/129 ,  C22B26/20 ,  C22B34/1272 ,  C25C3/02 ,  C25C3/28

Abstract: The present invention provides a method by which a metal-fog-forming metal dissolved in one portion of "a molten salt mixture consisted of one or more of metal-fog-forming metal containing molten salts" (generally, a molten salt) can be removed and transferred to another portion of the molten salt to increase the concentration thereof. The method can hence be utilized as one of means for treating molten salts in various industrial fields in which metal-fog-forming metal-containing molten salts such as Ca or Na are handled. In particular, when the method is utilized in producing Ti by Ca reduction, the Ca dissolved in the molten salt to be fed to an electrolytic cell can be rapidly removed (recovered) and the Ca formation efficiency during the electrolysis of the molten salt can be enhanced. Consequently, Ca formation and TiCl 4 reduction in the electrolysis of the molten salt can be efficiently carried out and a stable operation on a commercial scale is possible. Thus, the method can be efficiently utilized in producing Ti or a Ti alloy by Ca reduction.

Abstract translation: 本发明提供了通过将金属雾形成金属在“熔融盐混合物由一种或多种的金属雾形成金属包含熔融盐”（基因集会，熔融盐）可以是一种部分溶解的方法 取出并转移到熔融盐的另一部分，以增加其浓度。 该方法可因此用作装置中的一个用于在其中各种工业领域中处理熔融盐的金属雾形成含金属的熔盐：如Ca或Na的处理方式。 特别是，当该方法在通过Ca还原制造Ti的利用，在熔融盐中溶解的钙要被馈送到在电解槽可以迅速地去除（回收）和熔融盐的电解过程中的Ca形成效率可 增强。 因此，钙的形成和在熔融盐的电解的TiCl 4还原可有效地进行和稳定的操作以商业规模是可能的。 因此，该方法可以有效地生产Ti或由Ca还原Ti合金使用。